• 제목/요약/키워드: physical·chemical properties

검색결과 2,950건 처리시간 0.03초

Doped Sol-gel TiO2 Films for Biological Applications

  • Gartner, M.;Trapalis, C.;Todorova, N.;Giannakopoulou, T.;Dobrescu, G.;Anastasescu, M.;Osiceanu, P.;Ghita, A.;Enache, M.;Dumitru, L.;Stoica, T.;Zaharescu, M.;Bae, J.Y.;Suh, S.H.
    • Bulletin of the Korean Chemical Society
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    • 제29권5호
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    • pp.1038-1042
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    • 2008
  • Mono and multilayer TiO2(Fe, $PEG_{600}$) films were deposited by the dip-coating on $SiO_2$/glass substrate using sol-gel method. In an attempt to improve the antibacterial properties of doped $TiO_2$ films, the influence of the iron oxides and polyethilenglycol ($PEG_{600}$) on the morphological, optical, surface chemical composition and biological properties of nanostructured layers was studied. Complementary measurements were performed including Spectroscopic Ellipsometry (SE), Scanning Electron Microscopy (SEM) coupled with the fractal analysis, X-Ray Photoelectron Spectroscopy (XPS) and antibacterial tests. It was found that different concentrations of Fe and $PEG_{600}$ added to coating solution strongly influence the porosity and morphology at nanometric scale related to fractal behaviour and the elemental and chemical states of the surfaces as well. The thermal treatment under oxidative atmosphere leads to films densification and oxides phase stabilization. The antibacterial activity of coatings against Escherichia Coli bacteria was examined by specific antibacterial tests.

Comparison ofrock weathering propertiesfrom mountain and valley areas of homogeneous bedrock areas (동일 기반암 지역에서 산지와 곡지 암석의 풍화 특성 비교)

  • Lee, Gwang-Ryul
    • Journal of The Geomorphological Association of Korea
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    • 제23권1호
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    • pp.1-16
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    • 2016
  • This study estimates relationships between physical and chemical weathering indices of various rock types and topographical relief. Physical weathering properties such as rock strength and joint and chemical weathering indices such as the $SiO_2/Al2O_3$, CIA and WPI were analyzed from 18 rock outcrops in mountain and valley areas consisting of 9 rock types. The results indicate that the elevation and relief of topography increase physical strength of rock increases. It can be suggested that the total r(rock-mass strength rating) and R(rock rebound strength by Schmidt Hammer) are most useful indices as a quantitative weathering property factor to explain formative causes of topographical relief. The results also suggest that rock types such as sandstone, granite, gneiss and schist are most suitable to explain meaningful difference in topographical relief with the physical and chemical weathering indices.

Improvement of Physical Characteristics of Paper with Micro Pulp (마이크로 펄프를 이용한 종이의 물성 개선)

  • Kim, Hak-Sang;Kim, Bong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • 제40권1호
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    • pp.9-14
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    • 2008
  • Beating and using chemical agents are common methods to improve physical properties. But the beating is high energy consumption process and chemical agent addition may cause deteriorate waste water quality. Therefore, it is necessary to use more environment-friendly methods. In this study, micro pulp was used in the handsheet making to get improving effects of physical properties without beating treatment and chemicals. Stiffness, thickness and air permeability were increased and strength properties of paper were also improved to some extents by only the micro pulp addition.

Utilization of Industrial Waste to Organic Fertilizer for Lawn (산업폐기물의 잔디용 유기질 비료화에 관한 연구)

  • 주영규
    • Asian Journal of Turfgrass Science
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    • 제5권2호
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    • pp.81-86
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    • 1991
  • The sludge, a waste of brewery industries, was examined for potentials as a natural organic fertilizer (or soil conditioner) for lawn. Trial products were measured for changes of physical, chemical properties in laboratory and seed germination and seedling growth in green house were also tested. The results are as the following:1The sludge from distilled liquor brewery contained high quantity of organic matter which had proper physical and chemical properties for lawn fertilizer (natural organic fertilizer, soil conditioner, top-dressing mix) . It showed good characteristics in handling and capabilities to be developed as commercial products for golf courses. 2.Sludge from beer company needs proper treatment to improve physical properties for futher degradiation. It is because aggregation of the sludge particles prevented microbial activities and changing to soluble form. 3.Green carbon can be used as carbon source for organic fertilizer production using brewery sludge, but it should not contain wood extract which inhibit seed germination and seedling growth.

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The Rheological Properties of Poly(acrylonitrile)/Cellulose Acetate Blend Solutions in N,N-Dimethyl Formamide (폴리아크릴로니트릴/셀룰로오스 아세테이트/N,N-디메틸포름아미드 용액의 유연학적 특성)

  • Park, Seung-Han;Song, In-Kyu;Kim, Byoung-Chul
    • Polymer(Korea)
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    • 제33권4호
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    • pp.384-388
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    • 2009
  • The rheological properties of poly (acrylonitrile) (PAN) and cellulose acetate (CA) blend solutions in N,N-dimethyl formamide (DMF) were investigated in terms of temperature and blend composition. The solutions exhibited a very characteristic rheological behavior with variation of temperature. 8 wt% solution showed an increase of viscosity and a decrease of loss tangent as temperature was increased over the temperature range of 20 and $60^{\circ}C$. At $20^{\circ}C$ the physical properties of the solutions exhibited dependence on the blend composition. At 40 and $60^{\circ}C$, however, the effects of blend ratio on the physical properties notably diminished. The longer relaxation time at higher temperature indicated that the formation of physical structures resulting from intermolecular interactions was promoted with increasing temperature. The odd rheological responses were further elucidated by measuring of the physical properties of dilute solutions. The intrinsic viscosity of the solutions suggested that the coiled chain dimension was reduced with increasing temperature.

Comparison of Cell Performance with Physical Properties of Gas Diffusion Layers in PEMFCs (고분자전해질 연료전지에서 다양한 기체확산층의 물리적 특성과 연료전지 성능 비교)

  • Lee, Ji-Jung;Kim, In-Tae;Zhang, Yan;Lee, Hong-Ki;Shim, Joong-Pyo
    • Journal of the Korean Electrochemical Society
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    • 제10권4호
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    • pp.270-278
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    • 2007
  • PEMFC electrodes with various gas diffusion layers (GDL) were characterized to find out the effect of GDL on fuel cell performance. The physical properties of GDL such as electric conductivity, porosity, air permeability, water flux, PTFE content, etc had close relationship each other and affected on the variation of the cell performance. It was observed that the micro-porous layer (MPL) on carbon paper or cloth changed the physical properties of GDL and changed the cell performance. The variation of cell performance as a function of the physical properties of GDL showed different behaviors according to the amount of current density.

Wood Properties of Quercus acuta Thunb. (붉가시나무의 목재성질)

  • Chong, Song-Ho;Park, Byung-Su;Chung, Doo-Jin;Lee, Do-Sick;Cho, Sung-Taek;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • 제18권1호
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    • pp.39-46
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    • 2007
  • This study was carried out to investigate the wood properties for efficient utilization of warm temperate tree species of Quercus acuta Thunb. grown in Korea. Fundamental wood properties in the anatomical, physical, mechanical and chemical characteristics were examined. Quercus acuta Thunb. is a radial-porous, straight grained and fine textured wood. The heartwood is not clearly distinguished from the sapwood. In physical properties, it has a high oven-dry specific gravity of $0.85{\pm}0.02$, and high shrinkage from green to air-dried condition of $7.05{\pm}0.52%$ in radial and $11.13{\pm}0.48%$ in tangential direction. Mechanical properties determined are strong with the MOR of $1,065{\pm}90kgf/cm^2$, and tensile strength parallel to grain of $1,490{\pm}258kgf/cm^2$ and shear strength of $175{\pm}13kgf/cm^2$. Also, this wood has high extractive contents: 11.11% for cold and 13.51% for hot water.

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Physical and Chemical Weathering Indices for Biotite Granite and Granitic Weathered Soil in Gyeongju

  • Ban, Jae-Doo;Moon, Seong-Woo;Lee, Seong-Won;Lee, Joo-Gong;Seo, Yong-Seok
    • The Journal of Engineering Geology
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    • 제27권4호
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    • pp.451-462
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    • 2017
  • Physical weathering caused by external forces and chemical weathering caused by the decomposition or alteration of constituent materials are the two factors that dominate the mechanical properties of rocks. In this study, a field investigation was undertaken to identify the physical and chemical weathering characteristics of the biotite granite and granitic weathered soils in Gyeongju, South Korea. Samples were collected according to their grade of weathering and subjected to modal analysis, XRD analysis, XRF analysis, physical property tests, particle size distribution tests, and slake durability tests. Modal and XRD analysis identified these rocks as biotite granite; secondary alteration minerals were not observed. Physical property tests and particle size distribution analyses indicate an average porosity of 41.28% and a sand content of > 90 wt.%. These values are somewhat higher than those of granites in general. The results of the slake durability test and XRF analyses show that the physical and chemical weathering indices of the samples vary with the degree of weathering.

Influence of Aminized Graphite Nanosheets on the Physical Properties of PMMA-based Nanocomposites

  • Kim, Ki-Seok;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.196-200
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    • 2011
  • In this work, poly(methyl methacrylate) (PMMA) was grafted onto amine treated graphite nanosheets ($NH_2$-GNs) and the surface characteristics and physical properties of the $NH_2$-GNs-g-PMMA films were investigated. The graft reaction of $NH_2$-GNs and PMMA was confirmed from the shift of the $N_{1S}$ peak, including amine oxygen and amide oxygen, by X-ray photoelectron spectroscopy (XPS). The surface characteristics of the $NH_2$-GNs-g-PMMA films were measured as a function of the $NH_2$-GN content using the contact angle method. It was revealed that the specific component of the surface free energy (${\gamma}s$) of the films was slightly increased as the $NH_2$-GN content increased. Also, the thermal and mechanical properties of the $NH_2$-GNs-g-PMMA films were enhanced with the addition of $NH_2$-GNs. This can be attributed to the chemical bonding caused by the graft reaction between the $NH_2$-GNs and the PMMA matrix.

Curing Reaction and Physical Properties of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 경화반응과 도막물성)

  • Park, Hyong-Jin;Kim, Sung-Rae;Jung, Choong-Ho;An, Chong-Il;Park, Hong-Soo;Kim, Tae-Ok
    • Journal of the Korean Applied Science and Technology
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    • 제18권4호
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    • pp.261-272
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    • 2001
  • An ACR/HMMM film was prepared by blending high-solid ACR with curing agent, hexamethoxymethyl melamine (HMMM). An active curing reaction was observed at $170^{\circ}C$. The dynamic viscoelastic $T_{g}$ of the final film increased with the static viscoelastic $T_{g}$ of the film. The log damp value, which means a viscoelastic ratio, decreased with the increase in the curing temperature of the film. Physical properties of the films were within a suitable range for films, and by an accelerated weathering resistance test the films were proved weather resistible ones.