• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.1
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• pp.54-57
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• 2001

We have developed a new multidomain vertical-alignment (MVA) mode using a homeotropic photopolymer that provides a wider viewing angle for nematic liquidcrystal (NLC) with negative dielectric anisotropy. Good voltage-transmittance curves for he new MVA cell using the homeotropic photopolymer were observed. The viewing angle of the new MVA cell using the homeotropic photopolymer was wider than that of the conventional VA cell. The wide viewing angle using the new MVA cell is attributable to 4-domain by the ribs with UV exposure on the photopolymer.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.3
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• pp.171-179
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• 2004

Micro-stereolithography technology has made it possible to fabricate a freeform 3D microslructure. This technology is based on conventional stereolithography, in which a UV laser beam irradiates the open surface of a UV-curable liquid photopolymer, causing it to solidify. In micro-stereolithography, a laser beam of a few $\mu m$ diameter is used to solidify a very small area of the photopolymer. This is one of the key technological elements, and can be achieved by using a focusing lens. Thus, the solidification phenomena of the liquid photopolymer must be carefully investigated. In this study, the photopolymer solidification phenomena in response to variations in the scanning pitch of a focused laser beam was investigated experimentally. The effect of layer thickness on the solidification width and depth was also examined. These studies were conducted under the conditions of relatively lower laser power and relatively higher scanning speed. Moreover, the photopolymer solidification phenomena for the relatively higher laser power and lower scanning speed was investigated, too. In this case, comparing to the case of lower laser power and higher scanning speed, the photopolymer absorbed large amount of irradiation energy of the laser beam. These results were compared with those obtained from a photopolymer solidification model. From these results, a new laser-scanning scheme was proposed according to the shape of the 3D model. Samples by each method were fabricated successfully.

• Journal of the Optical Society of Korea
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• v.12 no.4
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• pp.319-325
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• 2008

We propose a phase contrast filter using photopolymer, for the phase contrast projection display. The photopolymer has high photosensitivity such that its optically induced refractive index change has a linear dependency on the illuminating light intensity. We implemented a phase contrast projection display using photopolymer as a phase contrast filter. By controlling the refractive index change of the photopolymer, we successfully convert an input phase image into a high contrast intensity image. We also investigated the effect of the photopolymer illumination condition on the quality of the displayed intensity image. As a projector, we achieved 82% phase to intensity conversion efficiency, which implies that the proposed method can potentially have much higher light efficiency than conventional projection display.

• Journal of Information Display
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• v.7 no.2
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• pp.6-11
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• 2006

New photopolymers were designed and prepared using the photosensitive polymer binders. Holographic gratings were successfully fabricated in these photopolymer samples by a conventional optical interference method. We also investigated the effect of photocrosslink in the polymer binder on the diffraction behavior of a new photopolymer. The dynamic behavior of the grating formation was monitored by changing exposure intensity in terms of the diffraction efficiency. Particularly, we focused our efforts in observing the variation of diffraction efficiency during a post UV curing process. The surface topographical change of photopolymer layer before and after Vis/UV light exposure was observed by atomic force microscope (AFM). We inscribed the gratings of the glass diffuser on the surface of the photopolymer and investigated their diffusing properties. The diffusers with photopolymer with the main chain polymer binder showed relatively good viewing angle of around ${\pm}30{\circ}$. Two kinds of photopolymer showed similar uniformity of around 47-54%.

• Korean Journal of Optics and Photonics
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• v.20 no.2
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• pp.123-127
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• 2009

In order to improve the diffraction efficiency of the photopolymer, we prepared a $TiO_2$ added photopolymer and investigated the optical properties. Prepared photopolymer films are based on polyvinyl alcohol (PVA) as a polymer binder, acryl amide (AA) as a photo-polymerizable monomer, triethanolamine (TEOA) as an initiator, and eosin Y as a sensitizer at 532 nm. To prepare the photopolymer films with the uniform thickness, the constant amount (2.5 ml) of the photopolymer solution was dropped on the glass and spread using a spin coater. Then films were dried for 72 hrs in a darkroom ($20^{\circ}C$, 40% RH) prior to the optical measurement. Then, the diffraction efficiencies of both the photopolymer films containing $TiO_2$ and non-contained films were measured with the various incident angles ($20{\sim}70^{\circ}$). Therefore, $TiO_2$ added photopolymer showed 5% higher diffraction efficiency than neat photopolymer without $TiO_2$ addition. The addition of $TiO_2$ into the photopolymer showed the high diffraction efficiency (over 70%) at broad range ($20{\sim}70^{\circ}C$) of the incident angle.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.953-956
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• 2002

The electro-optical (EO) performances of a multidomain vertical-alignment (MVA) cell on a homeotropic photopolymer have been investigated. In the absence of an electric field, the MVA cell achieved black state as LC alignment is homeotropic. An electric field created by interdigitated electrodes and rib made after photolithograph using the photopolymer on both substrates causes a director deformation of a multidomain type. Good voltage-transmittance curves for a MVA cell on the homeotropic photopolymer were observed. Also, the stable response time of MVA cell on the homeotropic photopolymer can be achieved.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.7
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• pp.600-605
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• 2001

The electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photo-aligned with polarized UV exposure on various blending photopolymer surfaces were investigated. Excellent LC alignment and voltage-transmittance (V-T) characteristics for TN-LCD photo-aligned with polarized UV exposure of normal incidence on the blending photopolymer (polyimide (PI) +PM4Ch(poly(4-methacryloyloxy chalcone))) surface containing chalcone group can be achieved. The EO performances for the TN-LCD photo-aligned on the blending photopolymer can be improved due to the photosensitivity by long side chain of the photopolymer.

• Journal of the Optical Society of Korea
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• v.14 no.4
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• pp.305-309
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• 2010

Photopolymer films containing fluorescent anthracene polymer, polymethyleneanthracene (PMAn), were prepared with different concentrations of PMAn for holographic recording useful for security documents. The fluorescent photopolymer film showed enhanced fluorescent intensity due to the micro-separation which arose from grating formation and diffusion during photopolymerization. Experimental values of diffraction efficiency were well matched to the simulated values for photopolymers having different PMAn concentrations. Holography patterning was carried out using the fluorescent photopolymer under a photo-mask. A grating was confirmed using microscope techniques in the recorded area under the pattern. Importantly the recorded area showed enhanced fluorescence compared to the unrecorded part, allowing fluorescence patterns at micro scale along with the submicron grating pattern. The fluorescence pattern recorded on the photopolymer film provides additional readability of holographic reading and thus is useful for secure recording and reading of information.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.8
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• pp.670-674
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• 2001

The electro-optical (EO) performance in the vertical-alignment (VA) - 1/4$\pi$ cell photoaligned with polarized UV exposure on a homeotropic photopolymer surfaces was investigated. Excellent voltage-transmittance curve in the VA - 1/4$\pi$ cell photoaligned with polarized UV exposure for 3 min on the photopolymer containing cholesteryl group of 8% can be achieved. The V-T characteristics in the VA-1/4$\pi$ cell photoaligned on the photopolymer surface can be improved by increasing cholesteryl group. For response time measurement, the transmittance characteristics of the VA-1/4$\pi$ cell photopolymer surface was better than that of the VA-1/4$\pi$ cell rubbingaligned on a polyimide(PI) surface.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.3
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• pp.219-223
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• 2003

The electro-optical (EO) performances of a multidomain verticial-alignment (MYA) cell on a homeotropic photopolymer have been investigated. In the absence of an electric field, the WVA cell achieved black state as LC alignment is homeotropic An electric field created by interdigitated electrodes and rib made after photolithograph using the photopolymer on both substrates causes a director deformation of a multidomain type. Good voltage transmittance curves for a MVA cell on the homeotropic photopolymer were observed. Also, the stable response time of MYA cell on the homeotropic photopolymer can be achieved.