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Preparation and Holographic Recording of Fluorescent Photopolymer Films Containing Anthracene Polymer for Security

  • Park, Tea-Hoon (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Kim, Yoon-Jung (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Kim, Jeong-Hun (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Kim, Eun-Kyoung (Department of Chemical and Biomolecular Engineering, Yonsei University)
  • Received : 2010.10.19
  • Accepted : 2010.11.23
  • Published : 2010.12.25

Abstract

Photopolymer films containing fluorescent anthracene polymer, polymethyleneanthracene (PMAn), were prepared with different concentrations of PMAn for holographic recording useful for security documents. The fluorescent photopolymer film showed enhanced fluorescent intensity due to the micro-separation which arose from grating formation and diffusion during photopolymerization. Experimental values of diffraction efficiency were well matched to the simulated values for photopolymers having different PMAn concentrations. Holography patterning was carried out using the fluorescent photopolymer under a photo-mask. A grating was confirmed using microscope techniques in the recorded area under the pattern. Importantly the recorded area showed enhanced fluorescence compared to the unrecorded part, allowing fluorescence patterns at micro scale along with the submicron grating pattern. The fluorescence pattern recorded on the photopolymer film provides additional readability of holographic reading and thus is useful for secure recording and reading of information.

Keywords

References

  1. S. J. Woltman, J. N. Eakin, G. P. Crawford, and S. Žumer, “Holographic diffraction gratings using polymer-dispersed ferroelectric liquid crystals,” Opt. Lett. 31, 3273-3275 (2006). https://doi.org/10.1364/OL.31.003273
  2. J. A. Arns, W. S. Colburn, and S. C. Barden, “Volume phase gratings for spectroscopy, ultrafast laser compressors, and wavelength division multiplexing,” Proc. SPIE 3779, 313-323 (1999). https://doi.org/10.1117/12.368222
  3. C. Wochnowski, Y. Cheng, K. Meteva, K. Sugioka, K. Midorikawa, and S. Metev, “Femtosecond-laser induced formation of grating structures in planar polymer substrates,” J. Opt. A: Pure Appl. Opt. 7, 493-501 (2005). https://doi.org/10.1088/1464-4258/7/9/008
  4. Y. H. Cho, C. W. Shin, N. Kim, B. K. Kim, and Y. Kawakami, “High-performance transmission holographic gratings via different polymerization rates of dipentaerythritol acrylates and siloxane-containing epoxides,” Chem. Mater. 17, 6263-6271 (2005). https://doi.org/10.1021/cm051058l
  5. R. A. Duarte-Quiroga, S. Calixto, and D. J. Lougnot, “Optical characterization and applications of a dual-cure photopolymerizable system,” Appl. Opt. 42, 1417-1425 (2003). https://doi.org/10.1364/AO.42.001417
  6. E. Kim, J. Park, C. Shin, and N. Kim, “Effect of organic side-chains on the diffraction efficiency of an organic-inorganic hybrid nanocomposite film,” Nanotechnology 17, 2899-2906 (2006). https://doi.org/10.1088/0957-4484/17/12/013
  7. H. Lee, B. Sarwade, E. Kim, and S. Lee, “Photopolymers containing triazine monomers for holographic recording,” Proc. SPIE 6335, 63350R1-63350R6 (2006).
  8. J. Joe, J. Lee, S. Yoon, S. Nam, and D. Kim, “Diffraction efficiency change in PVA/AA photopolymer films by $SeO_2$ and $TiO_2$ nano particle addition,” Korean J. Opt. Photon. 21, 82-88 (2010). https://doi.org/10.3807/KJOP.2010.21.2.082
  9. J. S. Yi and Y. H. Lee, “Intermediate holographic data storage system by using sequentially superimposed recording,” J. Opt. Soc. Korea 13, 456-463 (2009). https://doi.org/10.3807/JOSK.2009.13.4.456
  10. M.-S. Kim, G. Baasantseren, N. Kim, and J.-H. Park, “Hologram generation of 3D objects using multiple orthographic view images,” J. Opt. Soc. Korea 12, 269-274 (2008). https://doi.org/10.3807/JOSK.2008.12.4.269
  11. K. Her, H. Jang, and D. Kim, “Diffraction efficiency improvement of PVA/AA/$SeO_2$ photopolymer with various film thickness and eosin Y contents,” Korean J. Opt. Photon. 20, 230-235 (2009). https://doi.org/10.3807/KJOP.2009.20.4.230
  12. K. Her and D. Kim, “Study of diffraction efficiency values for photopolymer films added $TiO_2$ nanoparticles,” Korean J. Opt. Photon. 20, 123-127 (2009). https://doi.org/10.3807/HKH.2009.20.2.123
  13. H. Jung, N. Kim, J. Yoon, and T. Park, “Optical characteristic and image recording of reflection type photopolymer in transmission structure,” Korean J. Opt. Photon. 18, 8-13 (2007). https://doi.org/10.3807/HKH.2007.18.1.008
  14. H.-J. Lee, B. D. Sarwade, J. Park, and E. Kim, “Synthesis of new photopolymeric methacrylate thioester with s-triazine ring for holographic recording,” Opt. Mater. 30, 637-644 (2007). https://doi.org/10.1016/j.optmat.2007.02.046
  15. H. Oh, J. Kim, K. Rameshbabu, J. Do, and E. Kim, “Fluorescent grating patterns of photopolymer film containing ethylene glycol phenyl ether acrylate,” Journal of Nanoscience and Nanotechnology 8, 4616-4620 (2008). https://doi.org/10.1166/jnn.2008.IC36
  16. H. Oh, J. Kim, and E. Kim, “Holographic recording on photopolymers containing pyrene for enhanced fluorescence intensity,” Macromolecules 41, 7160-7165 (2008). https://doi.org/10.1021/ma800691y
  17. J. Kim, H. Oh, and E. Kim, “A dual-functional monomer having epoxy and methacrylate group for holographic recording,” Journal of Materials Chemistry 18, 4762-4768 (2008). https://doi.org/10.1039/b809275c
  18. J. Kim, H. Oh, J. Yoo, K. Rameshbabu, and E. Kim, “Fluorescent photopolymer holographic patterning,” Mol. Cryst. Liq. Cryst. 491, 67-73 (2008). https://doi.org/10.1080/15421400802328956
  19. J. Kim and E. Kim, “Holographic security media prepared from photochromic fluorescent films,” Proc. SPIE 7118, 71180F1-71180F10 (2008).
  20. E. Kim, J. Park, S. Cho, N. Kim, and J. Kim, “Preparation and holographic recording of diarylethene-doped photochromic films,” ETRI Journal 25, 253-257 (2003). https://doi.org/10.4218/etrij.03.0102.0042
  21. K. Rameshbabu, Y. Kim, T. Kwon, J. Yoo, and E. Kim, “Facile one-pot synthesis of a photo patternable anthracene polymer,” Tetrahedron Lett. 48, 4755-4760 (2007). https://doi.org/10.1016/j.tetlet.2007.05.002
  22. H. Lee, H. Oh, E. Kim, D. Dung, and N. Kim, “Diffusion model of monomers in a photopolymer film for holographic recording,” Proc. SPIE 6335, 63350M1-63350M8 (2006).

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