• 한국환경과학회지
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• 제1권1호
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• pp.19-33
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• 1992

The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorolog ital processecs . In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification Process through observation is emphasized.

• Journal of Korean Society for Atmospheric Environment
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• 제15권E호
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• pp.55-64
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• 1999

The CIT(California Institute of Technology) three-dimensional Eulerian photochemical model was applied to the Greater Seoul Area, Korea for July 24, 1994, a day of the 9-day ozone episode to understand the characteristics of photochemical air pollution problems in the area. The modeling domain was 60km$\times$60km with the girl size of 2km$\times$2km. As the base case emissions, air pollutant emission data of the National Institute of Environmental Research, Korea for the year of 1991 were used with modifications based on EKMA(Empirical Kinetic Modeling Approach) resutls. Comparisons between predicted and observed concentrations showed that the model predicted the peak concentration over the domain reasonably. It was found that the location of the peak ozone concentration was mainly decided by metorological conditions. But the model could not resolve the spatial variations of concentration station by station, which was mainly caused by localized variations in emission and meteorology.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제1권1호
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• pp.19-33
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• 1997

The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

• 한국입자에어로졸학회지
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• 제10권1호
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• pp.9-17
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• 2014

Several studies have been carried out on the source contribution of the particulate Polycyclic Aromatic Hydrocarbons (PAHs) over Seoul by using the Chemical Mass Balance Model (CMB)(Lee and Kim, 2007; Kim et al., 2013). To confirm the validity of the modeling results, the modified model employing a photochemical loss rate along with varying residence times and the standard model that considers no loss were compared. It was found that by considering the photochemical loss rate, a better performance was obtained as compared to those obtained from the standard model in the CMB calculation. The modified model estimated higher contributions from coke oven, transportation, and biomass burning by 4 to 8%. However, the order of the relative importance of major sources was not changed, coke oven followed by transportation and biomass burning. Thus, it was concluded that the standard CMB model results are reliable for identifying the relative importance of major sources.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2005년도 추계학술대회 논문집
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• pp.241-242
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• 2005

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2004년도 추계학술대회 논문집
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• pp.197-198
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• 2004

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 추계학술대회 논문집
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• pp.449-450
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• 2003

Performance of photochemical models and their response to emission controls are heavily dependent on the inputs to the model. Two key inputs to these models are accurate meteorological and emissions data. But they can contain significant errors which contribute to uncertainties in photochemical simulation (Kumar and Russell, 1996; Sistla et al., 1996; Pielke and Uliase, 1998; Barna and Lamb, 2000; Nelson L. Seaman, 2000: Hogrefe et al., 2001; Biswas et al., 2001).(omitted)

• 한국정밀공학회지
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• 제22권9호
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• pp.60-68
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• 2005

To investigate the effects of beam focusing in the etching of polymers with short pulse Excimer lasers, a polymer etching model of SSB's is combined with a beam focusing model. Through the numerical simulation, it was found that in the high laser fluence region, SSB model considering both photochemical and thermal contribution is considered to be suitable to predict the etched hole shape than a simple photochemical etching model. The average temperature distribution into the substance obtained by assuming 1-D heat transfer is found to be fairly similar to the fluence distribution on the ablated surface. The experimental etching data fur polymers are used to give material properties for ablation model. The fitted etch depth curve gives a nice agreement with the experimental data.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2005년도 추계학술대회 논문집
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• pp.470-471
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• 2005

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2004년도 춘계학술대회 논문집
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• pp.58-60
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• 2004