• 제목/요약/키워드: photoacoustic

검색결과 95건 처리시간 0.021초

광음향효과에 의한 화합물 반도체의 물성연구 (A Study on the Physical Properties of Compound Semiconducts by Photoacoustic Spectroscopy)

  • 윤화중
    • 한국음향학회:학술대회논문집
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    • 한국음향학회 1984년도 추계학술발표회 논문집
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    • pp.27-32
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    • 1984
  • When chopped light inpinges on some condenced matters such as HgS, HgI2 and GaSe semiconductors, in an enclosed cell, the acoustic signals are produced within the cell. These acoustic signals were detected by using a gas-phase microphone in order to investigate the physical properties of the samples. In order to carry out investigation, PA-cell was first designed and made so as to produce higher sensitivity to acoustic signals. Second, an analysis of the photoacoustic spectrum of the various compounds was carried out to obtain the intensity of the PA-signal in terms of light wavelength and to calculate the energy band gaps occuring according to energy transitions. The agreement between the results obtained by this conventional PAS technique and the results obtained by the optical spectrum method was good. In additional analysis conducted on the basis of the R-G theory and the Sze theory are capable of determining the characteristics of energy transition of semiconductors.

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강유전 고분자 박막을 이용한 유기고분자 태양전지에서의 효율 증대 (Efficiency Enhancement in Organic Polymer Solar Cells with Ferroelectric Films)

  • 박자영;정치섭
    • 한국전기전자재료학회논문지
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    • 제30권2호
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    • pp.126-132
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    • 2017
  • The power conversion efficiency of organic polymer solar cells was enhanced by introducing a ferroelectric polymer layer at the interface between active layer and metal electrode. The power conversion efficiency was increased by 50% through the enhancement of the open circuit voltage. To investigate the role of the ferroelectric layer on the dissociation process of the excitons, non-radiative portion of the exciton decay was directly measured by using photoacoustic technique. The results show that the ferroelectric nature of the buffer layer does not play any roles on the dissociation process of the excitons, which indicates the efficiency enhancement is not due to the ferroelectricity of the buffer layer.

Application of Photoacoustic Rapid Scan FTIR for the Determination of Kappa Number of Pulp

  • Dang Vinh Q.;Bhardwaj Nishi K.;Nguyen Kien L.
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.1
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    • pp.167-172
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    • 2006
  • High-yield Pinus radiate kraft pulps with various Kappa number were produced from flow-through laboratory pulping. The samples were prepared and scanned using a rapid scan photoacoustic Fourier transform infrared (PAS-FTIR) spectrometer. A partial-least-squares (PLS) model was established based on the spectral data collected at different mirror velocities. The model was used to predict the Kappa number of the pulps and its robustness was statistically evaluated. The outcomes indicate that the PLS model can be used to predict the Kappa number of Pinus radiata kraft pulps with a high degree of accuracy provided that the moving mirror velocity is ${\leq}\;0.5cm/s$.

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액체의 상폭발 과정에 의한 펄스 레이저 용발률의 증진 (Enhancement of Pulsed-Laser Ablation by Phase Explosion of Liquid)

  • 김동식;이호
    • 대한기계학회논문집B
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    • 제25권11호
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    • pp.1483-1491
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    • 2001
  • Enhancement of pulsed-laser ablation by an artificially deposited liquid film is presented. Measurements of ablation rate, ablation threshold, and surface topography arc performed. Correlation between material ablation and photoacoustic effect is examined by the optical beam deflection method. The dependence of ablation rate on liquid-film thickness and chemical composition is also examined. The results indicate that photomechanical effect in the phase explosion of liquid is responsible for the enhanced ablation. The low critical temperature of liquid induces explosive vaporization with localized photoacoustic excitation in the superheat limit and increases the ablation efficiency. Experiments were carried out utilizing a Q-swiched Nd:YAG laser at near-threshold laser fluences with negligible plasma effect (up to ∼100 MW/cm$^2$).

강유전 고분자를 첨가한 유기태양전지의 효율 특성 (The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells)

  • 박자영;정치섭
    • 한국전기전자재료학회논문지
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    • 제29권9호
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    • pp.589-594
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    • 2016
  • P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

Photoacoustic Laser Doppler Velocimetrv Using the Self - mixing Effect of RF - excited CO2 Laser

  • Choi, Jong-Woon;You, Moon-Jong;Choi, Sung-Woong;Woo, Sam-Young
    • Journal of the Optical Society of Korea
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    • 제8권4호
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    • pp.188-191
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    • 2004
  • A new laser Doppler velocimeter employing a $CO_2$ laser has been developed by using its photoacoustic effect. A change in the pressure of a discharge, induced by mixing of a returned wave with an originally existing wave inside the cavity, is employed to detect the Doppler frequency shift. We found that a Doppler frequency shift as small as 50 kHz was detected, and also a good linear relationship between the velocity and the Doppler frequency shift was obtained.

Photoacoustic Spectroscopic Study on Cobalt Incorporation onto the Surface of Mesoporous Molecular Sieves

  • 박동호;박성수;최상준
    • Bulletin of the Korean Chemical Society
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    • 제20권6호
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    • pp.715-719
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    • 1999
  • The incorporation of cobalt into mesoporous molecular sieves MCM-41 and MCM-48 was carried out. Co-PO/MCM41 and Co-PO/MCM48 were prepared using Co(II) acetate solution adjusted to pH = 3.0 with phosphoric acid by the incipient wetness method. Photoacoustic spectroscopy (PAS) was used to study the local environments of Co(II) incorporated into mesopores. The band around 500 nm in PAS of as-prepared Co-PO/MCM41 and Co-PO/MCM48 with Co(II) acetate solution was changed to triplet bands around 600 nm. This could be assigned to the 4 A2(F)-> 4T1(P) transition of Co(II) surrounded tetrahedrally by oxygen ions after calcination. It may be attributable to that the octahedral cobalt species containing phosphate ligands in coordination sphere reacting with framework's silanol groups to be dispersed atomically onto the surface of mesoporous molecular sieves as a tetrahedral species. This is unlike that the Co in Co-Cl/MCM41 and direct-synthesized Co-MCM41 transforms to Co oxide phase upon calcination. Co-PO/MCM41 and Co-PO/MCM48 were stable while treated with water.