• Title/Summary/Keyword: photo-polymer

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Charge-carrier Transport Properties of Organic Photoconductor by Photo-isomerization of Liquid Crystal with Azo Group (Azo기를 가지는 액정의 광 이성화에 따른 유기 광전도체의 carrier 수송 특성)

  • Lee, Bong;Sung, Jung-Hee;Moon, Chang-Kwon
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.473-477
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    • 1999
  • Xerographic properties of double-layer photoconductor doped with 4-butyl-4'-methoxyazobenzene (BMAB) as charge-carrier transport material were investigated. BMAB can undergo reversible trans-cis isomerization by light with appropriate wavelength. In the results of measured surface voltage properties for photoconductor doped with BMAB, TNF: BMAB(4-wt%) sample with trans form showed the lowest dark decay, the lowest residual voltage, and the highest sensitivity among cis form. The trans isomer of BMAB has ordering orientation because the molecule possesses a rodlike shape, while the cis isomer has random orientation due to its bent shape. Therefore the molecular arrangement of trans form enhanced charge-carrier transport mobility.

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Fabrication of the Liquid Analyzer us ing Micro-stereolithography Technology (Micro-stereolithography 기술을 이용한 용액분석 소자 제작)

  • 이영태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.12
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    • pp.994-1000
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    • 2001
  • In this paper, using micro-stereolithography technology, I fabricated a liquid analyzer to measure ion concentration of a solution. Micro-stereolithography is a technology to fabricate 3-dimensional structure by applying laser beam on liquid photo-polymer. This technology makes it possible to do preassemble fabrication without any extra assembling step after the process. So, the liquid analyzer could be fabricated at very low cost with very simple process by micro-stereolithography technology. The liquid analyzer consists of a chamber for containing the solution, a pump using piezoelectric effect of PZT disk, a static mixer and a sensor for measuring ion concentration using Pt electrodes.

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Study of Characteristics Variation of Etching according to Gas Flow in Poly-Si Dry Etching using ICP Poly Etcher (ICP Poly Etcher를 이용한 Poly-Si Dry Etch시 Gas Flow에 따른 Etching 특성 변화 연구)

  • Kim, Dong-Il;Han, Seung-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.180-181
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    • 2015
  • 본 논문에서는 ICP Poly Etcher를 이용한 Dry Etch에서 몇가지 공정조건의 변화에 따른 Etching 특성 변화를 연구하였다. 주요 가스유량들이 증가 할 때, Poly-Si 의 Etch rate는 증가 하였으며 Uniformity는 나빠진 것을 확인 할 수 있었고 다른 특성들은 특별한 변화를 보이지 않았다. 주요 Gas인 HBr의 증가는 PR(Photo Resist)와 Uniformity에 영향을 주었다. 이 논문을 통해 HBr의 유량이 Poly-Si Etching에 영향을 주는 결과를 알아 볼 수 있었고 HBr 가스의 유량 증가가 Polymer의 생성에 영향을 줘 Selectivity와 Uniformity를 증가 시킨다는 것도 확인 해 볼 수 있었다.

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Liquid Crystal Alignment on the Films of Polymethacrylate and Polyurethane Bearing an Aminotroazobenzene Chromophore

  • Park, Dong-Hoon;Kim, Jae-Hyung;Cho, Kang-Jin
    • Macromolecular Research
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    • v.8 no.4
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    • pp.172-178
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    • 2000
  • We synthesized polymethacrylate and polyurethane bearing a photosensitive azobenzene chromophore. Photo-induced birefringence of the thin film was observed under a linearly polarized light(λ = 532 nm). Dynamic behaviors of birefringence in two polymers were investigated in terms of the rate constants of growth and decay. An induced dichroism was observed from polarized UV-VIS absorption spectroscopy. Layers of two photosensitive polymers were used for aligning liquid crystal (LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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A New Antistiction Method Using Polymer Suspension for Fabrication with Polysilicon Micromachining (다결정 실리콘 마이크로머시닝 제작 시 폴리머 지지를 이용한 옆 방향 정착방지 방법의 제안)

  • Lim, Hyung-Taek;Yoon, Choong-Hyun;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 1999.07g
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    • pp.3331-3333
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    • 1999
  • A novel antistiction method using photo resist is proposed and verified to improve the yield of polysilicon micromachining process. $7.5{\mu}m-thick$ polysilicon is used as a structural layer. Residual stress and stress gradient originated from polysilicon deposition with LPCVD process is relaxed by doping and thermal treatment. The stress gradient of stress-free polysilicon layer is $-0.755MPa/{\mu}m$.

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Study on characteristics of liquid crystal alignment on photosensitive polyimide having thermal stability (고내열성을 가진 감광성 폴리이미드의 액정배향 특성에 관한 연구)

  • Lee, Sang-Min;Hwan, Jeoung-Yeon;Nam, Ki-Hyung;Seo, Dae-Shik;Suh, Dong-Hack
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.502-505
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    • 2003
  • We synthesized high thermal photoalignment material with hydroxyl aromatic polyimide, and studied the liquid crystal (LC) aligning capabilities on the photopolymer layers. Also, electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photoaligned with linearly polarized UV exposure were investigated. A good LC alignment with UV exposure on the photopolymer surface can be obtained. However, the low pretilt angles were obtained below $1^{\circ}$. The Voltage-transmittance (V-T) curve without backflow bounce in the photoaligned TN cell with UV exposure was observed. The response time of photoaligned TN cell was measured about 24 ms.

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Oil Movement Control of Electrowetting Display with Patterned Electrode (전극 패턴을 이용한 Electrowetting display의 오일 제어)

  • Kim, Tae-Hyun;Kim, Yeon-Sik;Ashanulhaq, Q.;Jeong, Eun;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.47-48
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    • 2006
  • Electrowetting phenomenon is applied in the various field of technology. One of that is electrowetting display as a paper like electronic paper. Fast response and easy to express a color is goodness. In spite of that, the oil movement of the electrowetting display is irregular. So it doesn't look like uniform. Because of the above reason, electrowetting display using patterned electrode is made and the characteristic of oil movement is observed. Electrode and polymer wall is patterned by photo-lithography. We analyze the oil movement according to the variation of size and the position of etched electrode area.

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Oil Movement Control by Charge Density Control in the Electrowetting Display (하전입자의 분포에 따른 Electrowetting display의 오일의 움직임)

  • Kim, Tae-Hyun;Kim, Yeon-Sik;Ashanulhaq, Q.;Jeong, Eun;Hahn, Yoon-Bong;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.495-496
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    • 2006
  • Electrowetting phenomenon is applied in the various field of technology. One of that is electrowetting display as a paper like electronic paper. Fast response and easy to express a color is goodness. In spite of that, the oil movement of the electrowetting display is irregular. So it doesn't look like uniform. Because of above reason, electrowetting display using patterned electrode is made and the characteristic of oil movement is observed. Electrode and polymer wall is patterned by photo-lithography. We analyze the oil movement according to the variation of size and the position of etched electrode area.

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Synthesis and Photocharacteristics of Poly(p-Anol-Formaldehyde) Cinnamate (Poly(p-Anol-Formaldehyde) Cinnamate의 합성과 그 감광특성)

  • Kwon, Soon-Yong;Seo, Kum-Jong;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.1
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    • pp.9-15
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    • 1998
  • Poly(p-anol-formaldehyde) cinnamates(AGEFCs) were synthesized to prepare a photo-sensitive polymer which enabled to be photodimerized via 6-center reaction. The photocharacteristics of the mixture of the AGEFCs and a sensitizer after exposure to light was tested. The yield of the residual film, which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. AGEFC-3 revealed a good photosensitive effect such as about 73% yield of residual film at 128 min. of exposed time.

Synthesis and Characterization of Power Conversion Efficiency of D/A Structure Conjugated Polymer Based on Benzothiadiazole-Benzodithiophene (Benzothiadiazole-benzodithiophene을 기반으로 한 D/A구조의 공액 고분자 합성 및 광전변환 효율 특성 개선 연구)

  • Seong, Ki-Ho;Yun, Dae-Hee;Woo, Je-Wan
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.537-543
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    • 2013
  • In this study, the push-pull structure polymer for organic photo voHaics (OPVs) was synthesized and characterized. The poly{4,8-didodecyloxybenzo[1,2-b;3,4-b]dithiophene-alt-5,6-bis(octyloxy)-4,7-di(thiophen-2-yl)benzo[c][1,2,5]-thiadiazole} (PDBDT-TBTD) was synthesized by Stille coupling reaction using the benzothiadiazole (BTD) derivative as an electron acceptor and benzodithiophene (BDT) derivative as an electron donor. The structure of monomers and polymers was identified by $^1H-NMR$ and GC-MS. The optical, physical and electrochemical properties of the conjugated polymer were identified by GPC, TGA, UV-Vis and cyclic voltammetry. The number average molecular weight ($M_n$) and initial decomposition temperature (5% weight loss temperature, $T_d$) of PDBDT-TBTD were 6200 and $323^{\circ}C$, respectively. The absorption maxima on the film was about 599 nm and the optical band gap was about 1.70 eV. The structure of device was ITO/PEDOT : PSS/PDBDT-TBTD : $PC_{71}BM/BaF_2/Ba/Al$. PDBDT-TBTD and $PC_{71}BM$ were blended with the weight ratio of 1:2 which were then used as an optical active layer. The power conversion efficiency (PCE) of fabricated device was measured by solar simulator and the best PCE was 2.1%.