• Title/Summary/Keyword: photo-polymer

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A study on the preparation of phthalocyanine optoelectric thin films (프탈로시아닌계 광전도성 유기박막의 제조에 관한 연구)

  • 박구범;조기선;이덕출
    • Electrical & Electronic Materials
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    • v.7 no.5
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    • pp.409-416
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    • 1994
  • A double layered photoreceptor using phthalocyanine dye was made by dip-coating method. The under cutting layer(UCL) was coated with A1$\_$2/O$\_$3/ or polyamide, and the charge generation layer(CGL) was formed by .tau.-type metal-free phthalocyanine. The oxadiazole was used as a charge transport layer(CTL) and polycarbonate and poly(vinyl butyral) was employed as a host polymer. The .tau.-H$\_$2/Pc had an absorption peak around 780nm, which coincided with the emitting wavelengths of GaAlAs diode lasers. Maximum charge acceptance of CTL that gives thickness of 12.mu.m was -900V by corona charge of -6.0kV. In photo-induced discharge measurements, residual potential was less than -20V and sufficient for ordinary use, and sample films using of poly(vinyl butyral) was showed good charge retention. In printing test, drum that was employed polycarbonate as a host polymer showed the good print quality.

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Development of Dental Restorative Materials (치과용 고분자 수복재료의 개발)

  • Chung, C.M.;Ahn, K.D.
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.11
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    • pp.140-141
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    • 1996
  • Bis-GMA is an important component in commercial dental restorative composites, but its hydroxy groups are considered to promote water absorption of the cured composite in a mouth. In this work, multifunctional methacrylates were prepared by blocking the hydroxy groups in bis-GMA with methacryloyl groups. Comparing to bis-GMA, new prepolymers having three methacryloyl groups (BPA-3M) and four methacryloyl groups (BPA-4M) showed much lower viscosities. Photopolymerization conversion of BPA-3M was slightly higher than that of bis-GMA. Water absorption of the photo-cured composite containing BPA-3M was measured for one month and found to be much lower than that of bis-GMA.

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Relationship between the pretilt angle generation and the polarization component with oblique polarized UV light irradiation on polyimide surface. (폴링미드표면에 편광된 UV광을 경사조사시의 프리틸트각의 발생과 편광성분의 상호관계)

  • 서대식;박두석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.75-80
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    • 1999
  • In this study, we have investigated the relationship between the generation of pretilt angle and the polarization component in cells with UV light irradiation on polyimide (PI) surface. It was found that the generated pretilt angle is about $1.4^{\circ}$ with S-polarized UV light irradiation of $75^{\circ}$ on PI surface; it may be attributed to the asymmetry triangular of polymer surface with oblique S-polarized UV light irradiation on PI surface. Also, we measured that the generated pretilt angle is about $2.0^{\circ}$ with oblique P polarized UV light irradiation of $75^{\circ}$ on PI surface. Consequently, we suggest that the generated pretilt angle of the NLC is attributed to the interaction between the LC molecules and the polymer surface with oblique polarized UV light irradiation on PI surface.

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Thermal and Optical Properties of Heat-Resistant Core Materials in Plastic Optical Fiber (내열성 플라스틱 광섬유 코어재료의 열적 및 광학적 성질)

  • Lee Gyu-Ho;Cho Won-Keun;Park Min;Lee Hyun-Jung
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.158-161
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    • 2006
  • Recently the application of plastic optical fiber (POF) in automotives and planes demands the heat-resistant and high refractive index con materials. We synthesized polyglutarimides (PGIs) via imidization of PMMA with primary amines under high pressure and high temperature and investigated thermal and optical properties by varying the molar ratio of amines and the type of amines (ethyl amine vs. isopropyl mine). The degree of imidization was calculated based on the peak intensity in $^1H$ NMR and FTIR. We found that the glass transition temperature $(T_g)$ of PGIs increased over $30^{\circ}C$ compared to the traditional core materials in POF, PMMA, and they are stable up to $300\sim400^{\circ}C$. PGIs anthesized with ethyl mine show the better heat resistance than those with isopropyl amines. Additionally, they show the comparable transparency and higher refractive index than PMMA. It implies that they can be utilized as the excellent photo-efficient and heat-resistant core materials in POF.

Determination of photo- and electroluminescence quantum efficiency of semiconducting polymers (전기발광고분자의 양자효율 측정)

  • 이광희;박성흠;김진영;진영읍;서홍석
    • Korean Journal of Optics and Photonics
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    • v.13 no.2
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    • pp.128-133
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    • 2002
  • In a recent effort to develop polymer light-emitting diodes (LEDs) as promising flat panel display components, measurements of reliable absolute photoluminescence (PL) and electroluminescence (EL) efficiency for polymer materials are required. In this work, we performed the measurement of PL and EL efficiency of luminescent polymers using an integrating sphere technique. The external PL efficiency of MEH-PPV was estimated to be 8 ($\pm$2)% together with the value of 0.02 1m/W for the external EL efficiency. This PL efficiency is in good agreement with published values, indicating that our PL efficiency measurements are somewhat legitimate. We believe this study might contribute to the research and development of organic materials for optoelectronic devices.

Width Control in the Photo patterning of PDP Barrier Ribs

  • Kim, Dong-Ju;Kim, Soon-Hak;Hur, Young-June;Kim, Duck-Gon;Lee, Sam-Jong;Jung, Sang-Kwon;Kim, Myeug-Chan;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.910-912
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    • 2006
  • Barrier ribs in plasma display panels (PDPs) function to maintain the discharge space between the glass plates as well as to prevent optical cross-talking. The barrier ribs currently employed are typically $300{\mu}m$ pitch, $110{\sim}120{\mu}m$ in height, with upper and lower widths of $50{\mu}m$ and $80{\mu}m$, respectively. It has been reported that barrier ribs can be fabricated by screen-printing, sand blasting, etching and photolithographic processes. In this study, photosensitive barrier rib pastes were formulated and systematically evaluated in terms of photolithographic process variables such as printing, drying, UV exposure, development and sintering. It was found that the use of UV absorbent, polymerization inhibitor and surfactant were very effective in controlling the width uniformity of barrier ribs in the photolithographic method of barrier rib patterning.

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Incident angle dependence of pretilt angle in a cell with oblique non-polarized UV light irradiation on polymer surface (편광되지 않은 UV광을 폴리이미드막에 경사지게 조사한 경우의 액정셀에서의 조사각도가 프리틸트각에 미치는 영향)

  • Han, Jeong-Min;Park, Doo-Seok;Park, Tae-Kyu;Seo, Dae-Shik;Hwang, Lyul-Yeon
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1258-1260
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    • 1998
  • In this study, we investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surfaces. It was found that the monodomain alignment of the NLC is obtained with an angle of incidence of $70{\sim}85^{\circ}$ on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force due to photo-depolymerization of polymer on PI surfaces. Also, pretilt angle of NLC is generated about $3^{\circ}$ with an angle of incidence of $70{\sim}75^{\circ}$. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the polymer surfaces.

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Fabrication of waveguide using UV Ar-ion laser direct writing (Laser Direct Writing 방법을 이용한 광도파로 제작)

  • Kang H. S.;Suh J.;Lee J. H.;Kim J. O.
    • Laser Solutions
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    • v.8 no.1
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    • pp.9-18
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    • 2005
  • The laser direct writing method using a UV Argon-ion laser is studied for fabrication of waveguide. The laser direct writing system is constructed with a vision camera, a xy-stage, a motion controller and the delivery components of a laser beam. The UV Argon-ion laser has wavelength range of $333.6\~363.8$ nm. A photo-active UV curable polymer for a planar light-wave circuit(PLC) of single mode is used. This polymer is irradiated by Argon-ion laser and developed by a solvent after a post-baking. The optimum laser direct writing condition is obtained experimentally by changing various process parameters such as laser power, writing speed and focal length. The propagation and coupling loss of a optical waveguide was measured as 1dB/cm and 0.6dB/cm, respectively. Also, the minimum width of waveguide of $100{\mu}m$(ZPLW-207) is obtained. Finally, the waveguides of line, bend and branch type are successfully fabricated.

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Synthesis and Photo Luminescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor using Polymer Matrix (폴리머 매트릭스를 전구체로 사용한 SrAl2O4:Eu2+,Dy3+ 축광성 형광체의 합성 및 형광 특성)

  • Kim, Soo-Jong;Kwon, Hyuk-Sil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.671-679
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    • 2007
  • [ $SrAl_2O_4:Eu^{2+},\;Dy^{3+}$ ] phosphor was synthesized using the impregnation method, and its photoluminescence and long-afterglow properties were investigated, A mixture of $Sr(NO_3)_2,\;Al(NO_3)_2\;9H_2O,\;EuCl_3\;6H_2O,\;DyCl_3\;6H_2O,\;NdCl_3\;6H_2O$ salts were dissolved in distilled water and impregnating into the polymer precursor. After drying, the impregnated mixture was heat treated at $900-1400^{\circ}C$ for 2h in a $N_2-H_2$ reduction atmosphere. The microstructure and crystal structure of the $SrAl_2O_4:Eu^{2+},\;Dy^{3+}$ powders were examined by scanning electron microscopy and X-ray diffraction, respectively. The photoluminescence spectra showed an excitation band along over wide wavelength of 250-450nm, and a broaden emission with a maxima peak at 360nm. In addition, the spectra also showed a good long after glow that decayed over a 1000sec period after 10 min excitation illumination.

Electroactive Polymer Actuator for Lens-Drive Unit in Auto-Focus Compact Camera Module

  • Lee, Hyung-Kun;Choi, Nak-Jin;Jung, Sun-Kyung;Park, Kang-Ho;Jung, He-Won;Shim, Jae-Kyu;Ryu, Jae-Wook;Kim, Jong-Dae
    • ETRI Journal
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    • v.31 no.6
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    • pp.695-702
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    • 2009
  • We propose a lens-drive unit composed of an ionic polymer-metal composite (IPMC) for an auto-focus compact camera module in cellular phones to solve the power consumption problem of voice coil motors which are widely used in commercial products. In this research, an IPMC incorporated into a lens-drive unit is designed to implement a large displacement in low-power consumption by using an anisotropic plasma treatment. Experimental results show that a camera module containing IPMCs can control and maintain the position of the lens by using proportional integral derivative control with a photo-reflective position sensor despite the non-linear actuation behavior of IPMCs. We demonstrate that the fabrication and commercialization of a lens actuator that has a large displacement and low power consumption using IPMCs is possible in the near future.