• 제목/요약/키워드: photo-conversion

검색결과 174건 처리시간 0.03초

Realization of flexible polymer solar cell by annealing-free process using 1,8-Diiodooctane as additive

  • Kim, Youn-Su;Ju, Byeong-Kwon;Kim, Kyung-Kon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.383-383
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    • 2011
  • We fabricated thermal annealing-free polymer solar cells (PSC) by processing with additive and applied to flexible substrates. The 1, 8-Diiodooctane of 3 vol% blended with active solution resulted in enhancement of $J_{SC}$ due to increase of light absorption and hole mobility as improving the crystallinity of P3HT. In addition, the $V_{OC}$ of PSCs with additive was improved by inserting $TiO_2$ layer without any treatment. The $TiO_2$ layer prevented the direct contact between active layer and Al electrode and reduced the charge recombination near Active/Al interface. It was confirmed by calculation of J0 and photo-voltage transient measurement. The power conversion efficiencies of annealing-free PSCs using additive for ITO glass and flexible (ITO PEN) substrate were obtained 3.03% and 2.45%, respectively.

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Recent Progress in Flexible Perovskite Solar Cell Development

  • Ren, Xiaodong;Jung, Hyun Suk
    • 한국세라믹학회지
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    • 제55권4호
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    • pp.325-336
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    • 2018
  • Perovskite solar cells (PSCs) are a new class of photovoltaic devices, which have attracted significant attention due to their remarkable optoelectrical properties, including high absorption coefficients, high carrier mobilities, long carrier diffusion lengths, tunable bandgaps, low cost, and facile fabrication. PSCs have reached efficiencies of 22.70% and 18.36% on rigid fluorine-doped tin oxide and poly(ethylene terephthalate) substrates, respectively; these are comparable to those of single-crystal silicon and copper-indium-gallium-selenium solar cells. Over the past eight years, the photo conversion efficiency of PSCs has been significantly improved by device-architecture adjustments, and absorber and electron/hole transport layer optimization. Each layer is important for the performance of PSCs; hence, we discuss achievements in flexible perovskite solar cells (FPSCs), covering electron/hole-transport materials, electrode materials. We give a comprehensive overview of FPSCs and put forward suggestions for their further development.

Observation of Elusive CF2Cl…Cl in Matrix Infrared Spectra and Density Functional Calculations

  • Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3274-3278
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    • 2013
  • $CF_2Cl{\cdots}Cl$, an elusive photo-isomer of $CF_2Cl_2$, has been observed in matrix IR spectra from the precursors exposed to radiation from laser ablation of transition-metals. Other plausible products, $CFCl_2{\cdots}F$ and $FClC{\cdots}F-Cl$ are not detected due to their considerably higher energies. Parallel to its previously reported analogues, the C-X bonds are considerably stronger than those of the reactant, and particularly the Cl atom that is weakly bound to the residual Cl atom forms an unusually strong carbon-halogen bond. NBO analysis reveals that the C-Cl bond is a true double bond, and the weak $Cl{\cdots}Cl$ bond is largely ionic, $F_2C=Cl^{\delta+}{\cdots}Cl^{\delta-}$. IRC computation reproduces smooth inter-conversion between the reactant and product, and the transition state is energetically close to the product, consistent with its prompt disappearance in the early stage of photolysis.

반투명 페로브스카이트 태양전지용 투명전극 소재 (Transparent Electrodes for Semitransparent Perovskite Solar Cells)

  • 이필립;고민재
    • Current Photovoltaic Research
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    • 제6권3호
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    • pp.74-80
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    • 2018
  • Recently, perovskite solar cells have shown tremendous improvement in power conversion efficiencies. Moreover, they have potential in semitransparent solar cell applications due to their high absorption coefficients. In order to fabricate semitransparent perovskite solar cells with good performance, it is essential to consider the suitability of transparent electrode materials in various aspects, such as transparency, conductivity and fabrication process. In this review, candidate materials for transparent electrodes in perovskite solar cells including carbon-based nanomaterials, conductive polymers and metallic nanostructures are discussed.

치과용 고분자 수복재료의 개발 (Development of Dental Restorative Materials)

  • 정찬문;안광덕
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 추계학술대회
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    • pp.140-141
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    • 1996
  • Bis-GMA is an important component in commercial dental restorative composites, but its hydroxy groups are considered to promote water absorption of the cured composite in a mouth. In this work, multifunctional methacrylates were prepared by blocking the hydroxy groups in bis-GMA with methacryloyl groups. Comparing to bis-GMA, new prepolymers having three methacryloyl groups (BPA-3M) and four methacryloyl groups (BPA-4M) showed much lower viscosities. Photopolymerization conversion of BPA-3M was slightly higher than that of bis-GMA. Water absorption of the photo-cured composite containing BPA-3M was measured for one month and found to be much lower than that of bis-GMA.

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계통 연계 모듈형 태양광 전력변환장치 고효율화에 관한 연구 (A Study on High Efficiency for Grid-connected Modular Photovoltaic Power Conversion System)

  • 이우철
    • 조명전기설비학회논문지
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    • 제28권1호
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    • pp.36-44
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    • 2014
  • The conventional central photo voltaic inverters have several problems. First, shadow problem in each solar panel, and high DC voltage problem from each panel because of concentration to one central inverter. Therefore, module integrated inverter is proposed to solve these problems. The inverter should be small and cost effective. The cost and size in the inverter depend on the inductor. So the switching frequency should be increased to reduce the inductor and total size, but there is a problem in efficiency because of the losses in turn-on and turn-off. In the paper, the critical conduction mode(CRM) switching method is adopted to reduce the switching loss and interleaving method is proposed to increase the efficiency in Flyback converter. Finally, the validity of the proposed scheme is investigated with simulated and experimental results for a prototype system rated at 200W.

Measurement of Drifting Mobility and Transit Time of Holes and Electrons in Stabilized a-Se Film

  • Kim, Jae-Hyung;Park, Chang-Hee;Nam, Sang-Hee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.362-363
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    • 2007
  • The transport property of stabilized amorphous selenium typical of the material used in direct conversion x-ray imaging devices was studied using the moving photo-carrier grating (MPG) technique and time-of-flight (TOF) measurements. For MPG measurement, the electron and hole mobility, and recombination lifetime of a-Se films with arsenic (As) additions have been obtained. For TOF measurement, a laser beam with pulse duration of 5ns and wavelength of 350 nm was illuminated on the surface of a-Se with thickness of $400{\mu}m$.

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광에너지를 활용한 선택적 산화그래핀의 환원 (Selective Graphene Oxide Reduction Utilizing Photon Energy)

  • 신재수;최은미
    • 반도체디스플레이기술학회지
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    • 제17권4호
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    • pp.16-20
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    • 2018
  • Graphene is attracting attention due to its outstanding properties as line material for next-generation semiconductor. Graphene pattern technology is essential to apply graphene line. Selective graphene oxide reduction as one of graphene pattern method does not require a substrate thereby a high flexibility device can be applied. Particularly, the method using photon energy has advantages of short process time and environment friendly. In this review, we introduce the photocatalytic method and the photo-thermal energy conversion method using photon energy in the selective reduction process of graphene oxides.

Ag-V/γ-Al2O3 촉매상에서 탄화수소-Selective Catalytic Reduction에 의한 질소산화물 저감 (DeNOx by Hydrocarbon-Selective Catalytic Reduction on Ag-V/γ-Al2O3 Catalyst)

  • 김문찬;이철규
    • 공업화학
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    • 제16권3호
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    • pp.328-336
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    • 2005
  • 본 연구에서는 배출가스 중에 포함된 NO를 비선택적 촉매환원법으로 환원시켜 제거하기 위하여 Ag와 V의 함량을 여러 가지로 달리하여 ${\gamma}-Al_2O_3$에 담지한 촉매를 제조하였고, 제조한 촉매에 대하여 온도, 산소농도, 아황산가스농도의 변화에 따른 $NO_x$의 전환율에 대하여 연구하였다. 또한 제조한 촉매의 물성분석을 통하여 촉매의 상태와 $NO_x$의 전환율과의 관계를 알아보았다. $AgV/{\gamma}-Al_2O_3$ 촉매의 경우에는 고온에서는 $Ag/{\gamma}-Al_2O_3$ 촉매보다 낮은 $NO_x$ 전환율을 나타내는 반면에 저온에서는$Ag/{\gamma}-Al_2O_3$ 촉매보다 높은 $NO_x$ 전환율을 나타내었고, 반응가스 중에 $SO_2$가 함유되어 있어도 $NO_x$의 전환율이 낮아지지 않았다. 반응실험 전 후의 촉매에 대하여 X-ray Diffraction, X-ray Photo electron Spectroscopy, Temperature Programmed Reduction, Ultraviolet-Visible Diffuse Reflectance Spectroscopy 등의 분석결과와 반응실험 결과를 비교하여 볼 때 V가 포함됨으로 인하여 Ag의 산화상태가 잘 유지되지 못하여 고온에서는 $NO_x$ 전환율이 낮아지며, $300^{\circ}C$ 이하의 저온에서는 V의 촉매작용으로 인하여 $NO_x$ 전환율이 높아진 것으로 나타났다.

단일 프레임 기반의 실시간 입체 영상 변환 방법 (A Real-Time Stereoscopic Image Conversion Method Based on A Single Frame)

  • 정재성;조화현;최명렬
    • 전자공학회논문지CI
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    • 제43권1호
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    • pp.45-52
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    • 2006
  • 본 논문에서는 2차원 영상의 단일 프레임을 이용한 실시간 입체 영상 변환 방법을 제안하였다. 2차원 영상의 단일 프레임에서 객체의 수직 위치 정보에 기반하여 깊이 지도를 생성하고, 시차 처리를 통해 입체 영상으로 변환한다. 입체 영상 변환의 실시간 처리와 하드웨어 구현에 따른 복잡도 감소를 위해 영상 샘플링과 표준 휘도화를 통한 객체 분할, 그리고 경계 스캔을 통한 깊이 지도 생성을 수행한다. 제안한 방법은 단일 프레임만을 이용하므로 운동 방향과 속도, 장면 전환에 상관없이 3차원 효과를 제공하며, 동영상뿐만 아니라 정지 영상에도 적용 가능하다. 단일 프레임만을 이용하여 영상 내 객체들의 수직 위치 정보에 의한 차등 깊이감을 제시하기 때문에 본 논문에서 가정한 영상의 구도 조건에 적합한 원거리 촬영 영상이나 풍경, 파노라마 사진과 같은 영상에서 효과적인 입체 영상 변환 효과를 제시한다. 제안한 방법의 성능 평가를 위해 시각적 검증과 APD(Absolute Parallax Difference)를 도입하여 기존의 MTD 방식과의 비교를 수행하였다. 제안한 방법에 의한 입체 변환 영상이 영상의 운동 방향이나 속도에 상관없이 입체 변환 효과를 나타냄을 확인하였다.