• 제목/요약/키워드: photo-conversion

검색결과 173건 처리시간 0.021초

3상 2레벨 계통연계형 태양광 인버터의 강인제어 (Robust Control of a Grid Connected Three-Phase Two-Level Photovoltaic Inverter)

  • 안경필;이영일
    • 전력전자학회논문지
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    • 제19권6호
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    • pp.538-548
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    • 2014
  • This study provides a robust control of a grid-connected three-phase two-level photo voltaic inverter. The introduced control method uses the cascade control strategy to regulate AC-side current and DC-link voltage. A robust controller with integration action is used for the inner-loop AC-side current control, which maximizes the convergence rate using a linear matrix inequality-based optimization design method and eliminates the offset error. The robust controller design method considers the parameter uncertainty set to accommodate parameter mismatch and un-modeled components in the inverter model. An outer-loop proportional-integral controller is used to regulate DC-link voltage with linearization of DC/AC relation. The proposed control strategy is applied to a grid-connected 100 kW photo voltaic inverter.

Construction of a 2D Co(II) Coordination Polymer with (4,4)-Connected Topology: Synthesis, Crystal Structure, and Surface Photo-electric Property

  • Li, Jia-Ming
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1177-1181
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    • 2014
  • A 2D grid-like (4, 4)-connected topology coordination polymer, $[Co(BTA)_2(H_2O)_2]_n$ (1), where HBTA = 2-(1H-benzotriazol-1-yl)acetic acid, has been synthesized by hydrothermal method and characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and surface photovoltage spectroscopy (SPS). X-ray diffraction analyses indicated that 1 displays octahedral metal centers with secondary building units (SBUs) [$Co(BTA)_2(H_2O)_2$] bridged by the $BTA^-$ ligands. In the crystal, the 2D supramolecular architecture is further supported by $O-H{\cdots}O$, $O-H{\cdots}N$, $C-H{\cdots}O$ hydrogen bonds and ${\pi}{\cdots}{\pi}$ stacking interactions. The SPS of polymer 1 indicates that there are positive response bands in the range of 300-600 nm showing photo-electric conversion properties. There are good relationships between SPS and UV-Vis spectra.

Composite Ni-TiO2 nanotube arrays electrode for photo-assisted electrolysis

  • Pozio, Alfonso;Masci, Amedeo;Pasquali, Mauro
    • Advances in Energy Research
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    • 제3권1호
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    • pp.45-57
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    • 2015
  • This article is addressed to define a new composite electrode constituted by porous nickel and an array of highly ordered $TiO_2$ nanotubes obtained by a previous galvanostatic anodization treatment in an ethylene glycol solution. The electrochemical performances of the composite anode were evaluated in a photo-electrolyser, which showed good solar conversion efficiency with respect to the UV irradiance together with a reduction of energy consumption. Such a combination of materials makes our system simple and able to work both in dark and under solar light exposure, thus opening new perspectives for industrial-scale applications.

전하 트랩 및 주입 문제를 해결하기 위한 비정질 셀레늄 필름의 계면 특성 (Interfacial Properties of a-Se Thick Films to Solve Charge Trap and Injection Problems)

  • 조진욱;최장용;박창희;김재형;이형원;남상희;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.497-500
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    • 2001
  • Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e,g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current.

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새로운 광변색성 Spiroxazine색소의 합성과 특성 (Syntheses and Characterisitics of New Photochromic Spiroxazine Dyes)

  • 김성훈
    • 한국인쇄학회지
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    • 제12권1호
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    • pp.159-168
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    • 1994
  • The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

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실리콘 광 촉매 연구동향 (Recent progress in silicon photocatalyst)

  • 이민우;심우영
    • 세라미스트
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    • 제23권2호
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    • pp.178-183
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    • 2020
  • Solar energy conversion is now actively researching because of pollution. Especially silicon photocatalyst has big potential, because of wide absorption range. But low quantum yield of silicon photocatalyst can't be used for commercialization. This paper summarize mechanism of silicon photocatalyst. In addition, properties and current states of photo catalyst using nanomaterials of silicon are also introduced.

단일칩 마이크로컨트롤러를 이용한 차압식 유량제어기의 개발 (Development of Differential Exhaust Flow Controller using One Chip Microcontroller)

  • 박찬원;김현식;주용규
    • 산업기술연구
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    • 제22권A호
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    • pp.89-94
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    • 2002
  • In this paper, a Exhaust Flow Controller (EFC) technology for uniform application of film coater and developer device is introduced that spread and remove photo resister at semiconductor manufacturing process. Because developed EFC device uses differential pressure sensing method as a differential flow meter and embodied smart A/D conversion by using a one chip microprocessor and devised by feedback Servo control, It has shown excellent performance and stability evaluation, as maximum 2000L/min flow, capability of installation to actual semiconductor equipment.

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디지털 X-선 변환물질을 위한 비소(As) 첨가 비정질 셀레늄(a-Se) 박막의 수송현상 (Transport phenomena of a-Se:As thin film for digital X-ray Conversion Material)

  • 박창희;김재형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.282-283
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    • 2006
  • The transport phenomena of arsenic (As) doped amorphous selenium(a-Se:As) thin film for digital X-ray conversion material has been reported. The effect of As addition on the carrier mobility and recombination lifetime in a-Se:As sample has been measured using the moving photo-carrier grating (MPG) technique. An Increase in hole mobility and recombination was observed when 0.3% arsenic, was added into a-Se sample, whereas electron mobility decrease with arsenic addition due to the defect density. The fabricated a-Se:03% As device exhibited the highest X-ray sensitivity.

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결정입계 처리에 따른 다결정 실리콘 태양전지의 효율 향상 (Efficiency Improvement of Polycrystalline Silicon Solar Cells using a Grain boundary treatment)

  • 김상수;김재문;임동건;김광호;원충연;이준신
    • E2M - 전기 전자와 첨단 소재
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    • 제10권10호
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    • pp.1034-1040
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    • 1997
  • A solar cell conversion effiency was degraded by grain boundary effect in polycrystalline silicon. Grain boundaries acted as potential barriers as well as recombination centers for the photo-generated carriers. To reduce these effects of the grain boundaries we investigated various influencing factors such as emitter thickness thermal treatment preferential chemical etching of grain boundaries grid design contact metal and top metallization along boundaries. Pretreatment in $N_2$atmosphere and gettering by POCl$_3$and Al were performed to obtain multicrystalline silicon of the reduced defect density. Structural electrical and optical properties of slar cells were characterized before and after each fabrication process. Improved conversion efficiencies of solar cell were obtained by a combination of pretreatment above 90$0^{\circ}C$ emitter layer of 0.43${\mu}{\textrm}{m}$ Al diffusion in to grain boundaries on rear side fine grid finger top Yb metal and buried contact metallization along grain boundaries.

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마이크로 라만을 사용한 실리콘 아크릴레이트가 광중합 반응에 미치는 영향 관찰 (Observation of the silicon acrylate effect on the photo-polymerization reaction using micro raman spectroscopic technique)

  • 오향림;홍진후;유정아
    • 분석과학
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    • 제17권3호
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    • pp.225-229
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    • 2004
  • UV 경화반응에 의하여 형성된 코팅의 성질을 향상시키기 위하여 첨가제로 사용한 실리콘 아크릴레이트가 광중합 반응에 미치는 영향을 마이크로 라만 분광법을 사용하여 관찰하였다. 광중합 반응의 반응체는 아크릴계 올리고머와 모노머를 사용하였으며 광 개시제로는 Darocur 1173을 사용하였다. 첨가제 실리콘 아크릴레이트는 광 경화 수지에 각각 0-3 wt% 첨가하였으며, UV를 조사하여 중합 반응시킨 후 공기-박막 경계면으로부터 두께에 따른 라만 스펙트럼을 관찰하였다. 광중합 반응의 진행정도는 1410과 $1635cm^{-1}$에 나타나는 중합에 직접 관여하는 아크릴기 ($-C=CH_2$)와 관련된 띠의 세기로부터 구하였다. 관찰된 결과에 따르면 마이크로라만으로부터 얻은 심도 스펙트럼 (depth profile)은 두께에 따른 경화반응의 진행 정도를 관찰할 수 있을 뿐만 아니라 경화 반응에 미치는 여러 요인에 대한 이해를 돕는 좋은 방법이 될 수 있음을 알 수 있다.