• The Transactions of the Korean Institute of Electrical Engineers
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• v.43 no.4
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• pp.569-579
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• 1994

A 5.9kW phosphoric acid fuel cell(PAFC) power generation system that consists of a reformer, a stack, heat exchangers, an automatic data acquisition and control system was designed, fabricated and analyzed. This system which was firstly fabricated in Korea has been operated for 140 hours with an electricity generation of 684kWh. The PAFC generate electricity in the range of 38-52V and 50-160A and has a typical I-V characteristics of a fuel cell. Using the reformed fuel, the system performance is decreased in some degree due to CO content, compared to using the simulated fuel. At steady state operation condition, the total efficency of this system was 45.2%.

• Journal of Energy Engineering
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• v.2 no.2
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• pp.187-193
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• 1993

Porous matrices to contain and support phosphoric acid were prepared with PTFE as binder and SiC whisker or SiC powders of various particle size for phosphoric acid fuel cell(PAFC). Among the matrix characteristics the most important factors in stack performances were thought to be the bubble pressure and electrolyte wettability And then matrix was constructed to have pore size smaller than that of electrode. The bubble pressures and wettabilities of matrices manufactured with various size of SiC and different PTFE contents were investigated and related with the porosities measured by porosimeter, and then the optimum manufacturing condition of matrix for PAFC was determined.

• Korean Journal of Materials Research
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• v.27 no.12
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• pp.664-671
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• 2017

A composite material was prepared for the bipolar plates of phosphoric acid fuel cells(PAFC) by hot pressing a flake type natural graphite powder as a filler material and a fluorine resin as a binder. Average particle sizes of the powders were 610.3, 401.6, 99.5, and $37.7{\mu}m$. The density of the composite increased from 2.25 to $2.72g/cm^3$ as the graphite size increased from 37.7 to $610.3{\mu}m$. The anisotropy ratio of the composite increased from 1.8 to 490.9 as the graphite size increased. The flexural strength of the composite decreased from 15.60 to 8.94MPa as the graphite size increased. The porosity and the resistivity of the composite showed the same tendencies, and decreased as the graphite size increased. The lowest resistivity and porosity of the composite were $1.99{\times}10^{-3}{\Omega}cm$ and 2.02 %, respectively, when the graphite size was $401.6{\mu}m$. The flexural strength of the composite was 10.3MPa when the graphite size was $401.6{\mu}m$. The lowest resistance to electron mobility was well correlated with the composite with lowest porosity. It was possible the flaky large graphite particles survive after the hot pressing process.

• Journal of the Korean Ceramic Society
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• v.34 no.12
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• pp.1205-1212
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• 1997

The matrices which consisted of SiC whisker, PES(polyesterasulfone) as a binder, span 80(sorbitan monooleate) as a surfactant, TPP(triphenyl phosphate) as a plasticizer and dichloromethane as a solvent, have been prepared by the various methods such as tape casting, rolling, tape cast-coating and roll-coating method. The fuel cells of single stack type using these matrices are characterized by ac impedance spectroscopy and cyclic voltammetry technique. A fuel cell using a matrix prepared by the tape cast-coating method shows the best performance of 466.34 mA/$\textrm{cm}^2$ at 0.6V because it has the lowest polarization resistance at the interface between electrodes and a matrix due to the largest three phase contact region of gases, catalyst and electrolyte.

• Korean Journal of Materials Research
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• v.30 no.10
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• pp.522-532
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• 2020

Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

• 제어로봇시스템학회:학술대회논문집
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• 1996.10b
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• pp.1012-1015
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• 1996

This study focuses on the optimal operation and control strategy of the fuel cell process. The control objective of the Phosphoric Acid Fuel Cell (PAFC) is established and dynamic modeling equations of the entire fuel cell process are formulated as discrete-time type. On-line optimal control of the MIMO system employs the direct decomposition-coordination method. The objective function is modified as the tracking form to enhance the response capability to the load change. The weight factor matrices Q,R, which are design parameters, are readjusted. This control system is compared with LQI method and the results show that the suggested method is better than the traditional method in pressure difference control.

• Journal of Energy Engineering
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• v.2 no.1
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• pp.75-82
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• 1993

A 50 ㎾ phosphoric acid fuel cell(PAFC) system using natural gas was simulated for steady state with the commercial software, ASPEN PLUS. The USER block and the FORTRAN block were prepared to simulate the cell. The changes of hydrogen yield according to the variation of several operating conditions were examined and the operating conditions to maximize hydrogen yield were obtained. The simulation results agree with the real data, which can be used to prepare the basic process data and the optimal conditions for the domestic commercial fuel cell system. H$_2$utilization rate over 50% should be maintained to achieve the efficiency of the conventional electricity generation. Energy consumption can be reduced by utilizing the heat released from the reformer and the cell which are operated at high temperatures.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1707-1709
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• 1996

For the improvement of the performance and life time of phosphoric acid fuel cell, the management of electrolyte in the electrocatalyst layer and electrolyte matrix in the cell structure is very important. Porous bipolar pinto structure, that is known as an advanced type, is generally used for the storage of electrolyte in the cell. In this paper, the single cell was made of the electrode by coating directly electrocatalyst layer on porous bipolar plate. The single cell showed $186\;mA/cm^2$ at 0.6V. This performance is similar to the performance of the conventional nonporous plate single cell. The technology of porous plate single cell could be directly used to the fabrication of stack in order to improve the performance and life time of phosphoric acid fuel cell.

• Journal of Energy Engineering
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• v.2 no.2
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• pp.200-207
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• 1993

A methanol reformer was designed and fabricated using a CuO-ZnO low temperature shift catalyst, and its operation characteristics have been studied for the phosphoric acid fuel cell (PAFC) power generation system. The type of reactor was annular Methanol was consumed both for heating and for reforming fuel. Contents of carbon monoxide produced from the reformer increased as the reaction temperatures increased, but decreased as the mole ratios of water to methanol(H$_2$O/CH$_3$OH) increased. At steady state operating conditional, temperature profile of the catalytic reactor of the reformer was well coincide with the model equation, and it took 50 minutes from start to the rated condition of the reformer. When the system was operated at 4/4 and 1/4 of load, thermal efficiencies of the system were 72.3% and 77%, respectively. When the PAFC system was operated with reformed gas in the range of 62 V-37.6 V and 0-147 A, the trend of I-V curve showed a typical fuel tell characteristic. At steady state condition, the flow rates of reforming and combustion methanol were 88.1 mol/h and 50.1 mol/h, respectively.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.05a
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• pp.87-87
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• 1998