• Title/Summary/Keyword: phosphor

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Effect of Dy addition on $Zn_2SiO_4:Tb$ green Phosphor ($Zn_2SiO_4:Tb$ 녹색 형광체의 Dy 첨가 효과)

  • Im, Won-Bin;Kang, Jong-Hyuk;Lee, Dong-Chin;Jeon, Duk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.968-971
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    • 2003
  • Due to a low efficiency of phosphor with large Stoke shift in Vacuum Ultra Violet (VUV) excitation environment, new PDP phosphors which can be excited in UV excitation environment need to be developed. In this study, $Zn_2SiO_4:Tb$ phosphor was synthesized by solid-state reaction method at $1300^{\circ}C$ with varying Tb concentration, and its cross relaxation effect was observed by Photoluminescence (PL) measurement. In order to decrease $^5D_3{\to}7F_j$ transition with blue emission in $Zn_2SiO_4:Tb$ phosphor, Dy, co-activator element, was added to $Zn_2SiO_4:Tb$ phosphor. In 254nm excitation environment, broad-emission peak was observed around 524nm, green emission.

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The Study of Photo-Luminescence on Willemite Phosphor (Willemite 형광체의 Photo-Luminescence 특성에 관한 연구)

  • 장창섭;오근호;이종근
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.245-252
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    • 1984
  • Willemite phosphor is a good one having excellent luminescence efficiency that it;s emission wavelength is in the range of about 525 nm. The energy band gap of this willemite phosphor is about 4.1 eV. When the ratio of ZnO/SiO is 1.8 and Mncl in used as activator source the phosphor has the value of maximum luminescence efficiency. The characteristic of willemite phosphor is tendency of the dependence of temperature. The willemite which was fired with activator after being synthesized at initial firing without activator shows higher value of luminescence efficiency than willemite which was fired with activator in initial stage, When the concentration of activator is 1-1.5mol% it has its most favorite condition and the value of luminescence efficiency decreases according to increasement of activator concentration.

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Improvement of Luminescence Degradation of Phosphor Screen by Surface Modification with $H_{3}PO_{4}$ Solution Treatment (인산 처리 공정에 의한 ZnS:Ag,Cl 형광막의 발광 열화특성의 개선)

  • Park, Zin-Min;Jeon, Duk-Young;Cha, Seung-Nam;Jin, Yong-Wan;Kim, Jong-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04b
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    • pp.49-52
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    • 2002
  • Degradation characteristics of cathodoluminescence (CL) of ZnS:Ag,Cl phosphor were investigated with measurements of CL and photoluminescence (PL). Phosphoric acid treatment was performed to phosphor particles in order to improve CL degradation of phosphor screen that occurred during panel sealing process, and we will discuss mechanisms of degradation and improvement of luminescence mainly with help of AES (auger electron spectroscopy) analysis.

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Morphology and Photoluminescence Characteristics of Halophosphate Phosphor Particles by Spray Pyrolysis and Flame Spray Pyrolysis

  • Sohn, Jong-Rak;Kang, Yun-Chan;Park, Hee-Dong;Yoon, Soon-Gil
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.803-806
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    • 2002
  • Flame spray pyrolysis was applied to improve the photoluminescence characteristics of blue-emitting $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles with high brightness for the application to LED phosphor. $Sr_5(PO_4)_3Cl:Eu^{2+}$ prepared from conventional spray pyrolysis had poor PL intensity than that of commercial products under long-wavelength ultraviolet(UV). $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles prepared by flame spray pyrolysis had PL intensity as same as that of commercial products under long-wavelength UV. Hollow morphology and porous structure of the particles prepared by the flame spray pyrolysis disappeared after posttreatment. Even though the $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles prepared by the flame spray pyrolysis had irregular shape, the particles had dense structure and clear surface property.

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The improvement of discharge characteristics and lifetime of PDP by MgO deposition on the phosphor

  • Ha, Chang-Hoon;Kim, Jae-Sung;Jeong, Dong-Cheol;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.232-235
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    • 2002
  • An alternate application of MgO film for the improvement of discharge characteristics and life time in an ac plasma display panel (PDP) is suggested. In this research, we deposited MgO on the phosphor to get the same address characteristics irrespective of each phosphor. To avoid the luminance and efficiency degradation by MgO deposition on the phosphor, we optimized the MgO thickness through experiments. The results showed that PDP with MgO coated phosphor has a uniform formative delay in address discharge and improved degradation characteristics.

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Effects of metal ions substitution for a potential blue-emitting $RbBaPO_4:Eu^{2+}$ phosphor

  • Kang, Dong-Seok;Yoo, Hyoung-Sun;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1279-1282
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    • 2009
  • The luminescence properties of a potential blue-emitting $RbBaPO_4:Eu^{2+}$ phosphor substituted with various metal ions have been investigated. The main emission wavelength of the phosphor samples was red-shifted by the substitution with K and Sr ions. The maximum peak intensity was obtained from the sample $Rb_{0.25}K_{0.75}Ba_{0.99}Eu_{0.01}PO_4$ which showed 144% relative intensity versus that of BAM:$Eu^{2+}$ phosphor under 254 nm excitation.

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Optical Properties of blue emitting (Ca, Sr)$Mg_2Si_3O_9:Eu^{2+}$ phosphor

  • Lee, Hyun-Ju;Pil, Kyung;Yoo, Jae-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1276-1278
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    • 2009
  • A novel blue emitting $Ca_{1-x}Mg_2Si_3O_9:Eu_x$ phosphor was synthesized by the solid state reaction and its photoluminescence properties were optimized by controlling concentration of the activator contents and substituting concentration of Ca ion by Sr ion. The photoluminescence (PL) showed that this phosphor is efficiently excited by ultraviolet (UV)-visible light in the wavelength range from 200 to 410 nm. Also this phosphor emits intensely blue light with a broad peak at around 450 nm.

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Synthesis and Optical Characteristics of Green-Emitting (Mg,Zn)$Al_2O_4:Mn^{2+}$ Phosphor for 3D- PDP Applications

  • Han, Bo-Yong;Yoo, Jae-Soo;Heo, Eun-Gi;Yoo, Young-Gil
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.272-275
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    • 2009
  • A new green phosphor, ($Mg_{1-x-yZnx)$)$Al_2O_4:Mn^{2+}{_y}$ (0 x 0.6, 0.001 y 0.01), was synthesized by a flux-assisted solid reaction and its vacuum ultraviolet (VUV) excitation and emission characteristics were examined in this study. The chromaticity and peak intensity of the $(Mg_{0.79}Zn_{0.2})Al_2O_4:Mn^{2+}{_{0.01}}$ (x = 0.177, y = 0.745) phosphor were found to be more desirable than that of $Zn_2SiO_4:Mn^{2+}$ (x = 0.216, y = 0.72) phosphor as a green primary color.

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Luminance and Surface Properties of P-ELD Emitted White Light (백색광을 발하는 면발광소자의 휘도 및 표면특성)

  • 박수길;조성렬;손원근;박대희;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.403-406
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    • 1998
  • Electroluminescence(EL) come from the light emission obtained by electrical excitation energy passing through a phosphor layer under applied high electrical field. The preparation and characterizations of light emitting ACPEL(alternating-current powder electroluminescent) cell based on two kinds of phosphor mixed ZnS:Mn, Cu and ZnS:Cu phosphor. Basic structure is ITO/Mixed Phosphor/insulator/Al sheet, each layer was mixed by binder, which concentration 11p for phosphor, 8p for insulator. Dielectric properties was investigated first and emission properties of P-LED based on ZnS:Mn,Cu/ZnS:Cu,Br mixture. Emission spectra exhibits two kinds of main peaks at 100V, 1kHz sinusoidal excitation.

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Effects of Phosphor Layer Morphology on Discharge Characteristics of Red, Green, and Blue Cells in AC-PDP

  • Lee, Jae-Jin;Jang, Sang-Hun;Tae, Heung-Sik;Choi, Kyung-Cheol
    • Journal of Information Display
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    • v.2 no.4
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    • pp.52-56
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    • 2001
  • This paper presents the effects of the phosphor layer morphology related to the discharge volume on the discharge and radiation characteristics of the Red, Green, and Blue cells in an AC-PDP. As the thickness of the phosphor layer increases and the corresponding discharge volume in the cells decreases, the voltage margin decreases due to an increase in the sustain voltage. In contrast, the IR(Infrared) emission, discharge current, and luminance characteristics remain almost unchanged, regardless of any changes in the phosphor layer morphology.

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