The Study of Photo-Luminescence on Willemite Phosphor

Willemite 형광체의 Photo-Luminescence 특성에 관한 연구

  • 장창섭 (한양대학교 무기재료공학과) ;
  • 오근호 (한양대학교 무기재료공학과) ;
  • 이종근 (한양대학교 무기재료공학과)
  • Published : 1984.03.01

Abstract

Willemite phosphor is a good one having excellent luminescence efficiency that it;s emission wavelength is in the range of about 525 nm. The energy band gap of this willemite phosphor is about 4.1 eV. When the ratio of ZnO/SiO is 1.8 and Mncl in used as activator source the phosphor has the value of maximum luminescence efficiency. The characteristic of willemite phosphor is tendency of the dependence of temperature. The willemite which was fired with activator after being synthesized at initial firing without activator shows higher value of luminescence efficiency than willemite which was fired with activator in initial stage, When the concentration of activator is 1-1.5mol% it has its most favorite condition and the value of luminescence efficiency decreases according to increasement of activator concentration.

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References

  1. J. Electrochem. Soc. v.107 no.3 Relation of sime surface chemical properties of zinc silicate phosphor to it's behavior in fluorescent lamp D. E. Harsion
  2. J. Electrochem. Soc. v.99 no.4 The zinc silicate phosphor fluorescing in the bellow and red H. G. Pfeiffer;G. R. Fonda
  3. J. Electrochem. Soc. v.98 no.9 The Thermoluminescence characteristics of Silicate phosphors activated by manganeses and Arsenic C. Bull;G. F. J. Garlick
  4. J. Chem. Phys. v.46 no.6 E.S.R. Study of manganese doped α-ZinC Silicate Crystals Harolyn;King;Perkin;M. T. Sienko
  5. J. Am. Cer. Soc. v.120 Phase diagram for ceramist E. M. Levin;H. F. McMardic;F. P. Hall
  6. Introduction to Luminescence of Solids v.233 Humboldt;W. Leverenz
  7. Crystal structure of Minerals v.178 Lawrence Bragg;G. F. Claringlull
  8. Introduction to Luminescence of Solids v.162 Humboldt. W. Le berenz
  9. Trans. Faraday. Soc. v.8 no.246 R. W. Gurney;W. F. Mott
  10. Phy Rev. v.89 no.5 Introduction of manganese activator ions in Zinc orthosilicate phosphor Simon Larach;John Turkevich