• Title/Summary/Keyword: phosphor

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Effects of Sputtering Conditions on Properties of $CaTiO_3 : Pr$ Phosphor thin Films (Sputtering 조건이 $CaTiO_3 : Pr$ 형광체 박막의 물성에 미치는 영향)

  • 정승묵;김영진;강승구;이기강
    • Korean Journal of Crystallography
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    • v.11 no.3
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    • pp.167-172
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    • 2000
  • CaTiO₃:Pr phosphor thin films were prepared on Si(100), ZnO/glass, Corning glass and ITO/glass by rf magnetron reactive sputtering. The effects of deposition parameters such as oxygen partial pressure, substrate temperature, and annealing conditions on crystallinity and compositional variation of the films were investigated. PL spectra of CaTiO₃:Pr phosphor thin films exhibited red regime peaking at 613 nm and enhanced PL intensity was observed for the film annealed in vacuum atmosphere as compared to the deposit annealed in N₂ environment.

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고출력 LED용 형광체 재료 개발

  • Kim, Seon-Uk;Hwang, Jong-Hui
    • Ceramist
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    • v.21 no.1
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    • pp.80-97
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    • 2018
  • To realize a high luminous efficacy and a high emission color purity for the white-LEDs, the understanding for luminescence properties of the phosphors is significantly important because the performance of white-LEDs is directly affected by the luminescence properties of the phosphors. In this paper, therefore, we reviewed some commercially available $Eu^{2+}$- and $Ce^{3+}$- activated phosphors and discussed for the luminescence properties of these phosphors.

Preparation and Optical Properties of $SrGa_2S_4$:Eu Phosphor

  • Do, Yeong Nak;Bae, Jae U;Kim, Yu Hyeok;Yang, Hong Geun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.3
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    • pp.295-299
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    • 2000
  • The photoluminescence and cathodoluminescence of $SrGa_2S_4:EU$ phosphor were optimized with the process and chemical variables (activators, fluxes and reaction temperature) used in solid state reaction. Firing the powder with flux at $800^{\circ}C$ for 2hr gave the highest photoluminescence efficiency under near-UV excitation and the highest cathodoluminescence efficiency of 20.1 lm/W at 2 kV and 33.3 lm/W at 10 kV. The suitability of $SrGa_2S_4:EU$ for application as a phosphor in LCDs and FEDs is discussed.

Brightness Improvement of ZnS:Cu Powder Electroluminescence by Mixed Layer

  • Lee, Jong-Chan;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.2
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    • pp.64-67
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    • 2004
  • In this paper, to discover the brightness improvement of ZnS:Cu powder electroluminescence (EL), a new structure is proposed in which phosphor and dielectric are mixed between electrodes. Dielectric and phosphor material are BaTiO$_3$ and ZnS:Cu, respectively. The effect of the mixed layer on EL sample is considered the improvement of source efficiency. Although the number of electrons introduced into the phosphor increases only modestly, the high electric field region of phosphor grains increases comparatively in the characteristics of brightness-voltage. Furthermore, the relaxation occurs through leading and trailing edge pairs, which is relatively efficient in characteristics of decay time. With these results, we found that the brightness of newly proposed ZnS:Cu powder electroluminescence was 167.24 cd/$m^2$ at ac voltage of 100V and frequency of 400Hz.

Luminescent Properties of Europium-Doped Lanthanum Silicon Nitride Phosphor

  • Lences, Zoltan;Hrabalova, Monika;Czimerova, Adriana;Sajgalik, Pavol;Zhou, You;Hirao, Kiyoshi
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.325-327
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    • 2012
  • Europium-doped $LaSi_3N_5$ phosphor was synthesized from LaSi/Si/$Si_3N_4/Eu_2O_3$ mixture by nitridation at $1390^{\circ}C$ and additional annealing at $1650^{\circ}C$ for 4 h. The phosphor shows emissions in the green light region with a maximum at 560 nm. With increasing europium content in the general formula $La_{1-z}Eu_zSi_3N_{5-z}O_{1.5z}$ from z = 0.01 to 0.06 there was a maximum emission for z = 0.04 followed by concentration quenching for the highest europium content (z = 0.06).

Synthesis of the sulfide phosphors and white light generation based on InGaN chip

  • Kim, Kyung-Nam;Kim, Jae-Myung;Choi, Kyoung-Jae;Park, Joung-Kyu;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.679-682
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    • 2004
  • $SrGa_2S_4$:Eu green phosphor and SrS:Eu red phosphor have been synthesized by co-precipitation method, respectively. Two sulfide phosphors were influenced by oxygen defect in host materials. Excitation spectra of these phosphors have high efficiency at the long wavelength region. And emission efficiency is increased under the excitation wavelength of 465nm. The combination of thiogallate green phosphor and sulfide red phosphor based on blue light InGaN chip has made it possible to emit white light.

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Application of $Sr_3SiO_5$:Eu yellow phosphor for white light-emitting diodes

  • Park, Joung-Kyu;Kim, Chang-Hae;Park, Hee-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.676-678
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    • 2004
  • In order to develop new yellow phosphor that emit efficiently under the 450 - 470 nm excitation range, we have synthesized a $Eu^{2+}$-activated $Sr_3SiO_5$ yellow phosphor and investigated an attempt to develop white LEDs by combining it with a InGaN blue LED chip (460 nm). Two distinct emission bands from the InGaN-based LED and the $Sr_3SiO_5$:Eu phosphor are clearly observed at 460 nm and at 570 nm, respectively. These two emission bands combine to give a spectrum that appears white to the naked eye. Our results showed that InGaN (460 nm chip)-based $Sr_3SiO_5$:Eu exhibits a better luminous efficiency than that of the industrially available product InGaN (460 nm chip)-based YAG:Ce.

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Enhancement of the Thickness Uniformity of a Phosphor Layer in the Cold Cathode Fluorescent Lamp

  • Kim, Min-Wan;Kim, Hie-Chul;Kim, Suk-Hwan;Lee, Sang-Woo;Choi, Byung-Ho;Kim, Kyung-Hwan;Sohn, Woo-Keun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1068-1071
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    • 2004
  • We report the techniques to obtain the high uniformity of the phosphor film thickness in the cold cathode fluorescent lamps, which are widely used as a back-light for the liquid crystal display. The thickness variation of the phosphor layer was sensitive to blowing conditions. The optimum conditions were obtained at flow rate of 15 sccm for 30 min at 40 $^{\circ}C$. The optimum and uniform thickness of a phosphor layer gives good luminous output.

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The characteristic study of hybrid X-ray detector using ZnS:Ag phosphor (ZnS:Ag phosphor를 이용한 hybrid 형 X-ray detector 특성 연구)

  • Park, Ji-Koon;Gang, Sang-Sik;Lee, Dong-Gil;Cha, Byeong-Yeol;Nam, Sang-Hee;Choi, Heung-Kook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.27-30
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    • 2002
  • Photoconductor for direct detection flat-panel imager present a great materials challenge, since their requirements include high X -ray absorption, ionization and charge collection, low leakage current and large area deposition. Selenium is practical material. But it needs high thickness and high voltage in selenium for high ionization rate. We report comparative studies of detector sensitivity. One is an a-Se with $70{\mu}m$ thickness on glass. The other has hybrid layer of depositting ZnS phosphor with $100{\mu}m$ on a-Se. The leakage current of hybrid is similar to it of a-Se, but photocurrent is lager than a-Se. Both of them have high spatial resolution, but hybrid has higher sensitivity than a-Se at comparable bias voltage.

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Synthesis and luminescent properties of $Sr_2SiO_4:Eu^{2+}$ phosphors ($Sr_2SiO_4:Eu^{2+}$ 형광체의 합성 및 발광특성)

  • Kim, Jong-Min;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.430-431
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    • 2009
  • In this study, europium doped strontium silicate ($Sr_2SiO_4:Eu^{2+}$) phosphor has been synthesized by conventional solid-state method and investigated luminescent characteristic. $SrCO_3$ and $SiO_2$ were mixed together by 2:1 mole ratio. Also $NH_4Cl$ was added as a flux. The mixture were sintered at $800^{\circ}C$, $1000^{\circ}C$ for 3h under the atmosphere (5% $H_2$/95% $N_2$). This phosphor can be applicated to the yellow phosphor for white LED because it has yellow emission band (540nm), which emits efficiently under the 370nm excitaion energy.

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