• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2006년도 춘계학술대회 논문집
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• pp.77-80
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• 2006

Structural phase transformations of silicon during nanoindentation were investigated in detail at the atomic level. The molecular dynamics simulations of nanoindentation on the (100), (110) and (111) surface of single crystalline silicon were simulated, and this supported the theoretical prediction of the anisotropic behavior of structural phase transformations. Simulations showed that microscopic aspects of phase transformation varied according to the crystallographic orientation of the contact surface and were directly linked to the slip system.

• 열처리공학회지
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• 제18권5호
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• pp.281-287
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• 2005

Titanium aluminium nitride((TiAl)N) film is anticipated as an advanced coating film with wear resistance used for drills, bites etc. and with corrosion resistance at a high temperature. In this study, (TiAl)N thin films were deposited both at room temperature and at elevated substrate temperatures of 573 to 773 K by using a two-facing-targets type DC sputtering system in a mixture Ar and $N_2$ gases. Atomic compositions of the binary Ti-Al alloy target is Al-rich (25Ti-75Al (atm%)). Process parameters such as precursor volume %, substrate temperature and Ar/$N_2$ gas ratio were optimized. The crystallization processes and phase transformations of (TiAl)N thin films were investigated by X-ray diffraction, field-emission scanning electron microscopy. The microhardness of (TiAl)N thin films were measured by a dynamic hardness tester. The films obtained with Ar/$N_2$ gas ratio of 1:3 and at 673 K substrate temperature showed the highest microhardness of $H_v$ 810. The crystallized and phase transformations of (TiAl)N thin films were $Ti_2AlN+AlN{\rightarrow}TiN+AlN$ for Ar/$N_2$ gas ratio of 1:3, $Ti_2AlN+AlN{\rightarrow}TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 1:1 and $TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN{\rightarrow}Ti_2AlN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 3:1. The above results are discussed in terms of crystallized phases and microhardness.

• 지질학회지
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• 제54권6호
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• pp.657-675
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• 2018

하부 맨틀의 상부에서 관찰되는 섭입된 해양판의 겉보기 두꺼워짐은 과거 연구를 통해 슬랩 좌굴에 의한 것으로 제안되었다. 그러나, 맨틀의 상전이가 슬랩 좌굴에 미치는 영향을 정량적으로 평가하고 이를 규모 법칙으로 검증한 연구는 거의 이루어지지 못하였다. 이 연구에서는 상전이를 고려한 2차원 컴퓨터 섭입 모델링을 수행하여 상전이가 슬랩 좌굴에 미치는 영향에 대해 정량적으로 평가하고 규모 법칙으로 검증하였다. 실험 결과는 410 km 깊이에서 발생하는 감람석-와드슬레이아이트 상전이가 슬랩 좌굴의 발달에 중요한 영향을 미친다는 것을 보였다. 흡열 상전이는 상부 맨틀에서 섭입 슬랩의 침강을 가속시켜 660 km 깊이에 존재하는 불연속면에 빠르게 도달하게 한다. 그러나 660 km 깊이에 존재하는 링우다이트-페로브스카이트+마그네시오우스타이트 상전이는 슬랩 좌굴의 발달에 상대적으로 작은 영향을 미치는데 그 상전이가 섭입 슬랩의 하부 맨틀 침강을 지연시켜 전이대에 섭입한 슬랩을 누적시키기 때문이다. 그럼에도 불구하고 슬랩 좌굴은 규모 법칙을 20% 이내의 오차에서 잘 만족한다. 이처럼 슬랩 좌굴은 맨틀에서 발생하는 보편적인 현상으로써 자바-순다 및 동북 일본 섭입대에서 관찰되는 하부 맨틀의 상부와 전이대에서의 슬랩 좌굴을 잘 설명한다. 또한 백악기 시기 경상 분지가 겪은 주기적인 압축 및 인장이 슬랩 좌굴에 의한 가능성을 암시한다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.334-336
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• 2009

An elastic-plasticity model during the austenitic decomposition was derived and implemented to incorporate the two important deformation behaviors observed during the phase transformations: the volumetric strain and transformation induced plasticity due to the temperature change and phase transformation. To obtain transformed phase volume fractions during cooling, the fourth order Runge-Kutta method was used to solve the Kirkaldy's phase kinetics model which is function of temperature, austenitic grain size and chemical composition. The volumetric strain was calculated by considering the densities of constituent phases, while the transformation induced plasticity was based on the micro-plasticity due to the volume mismatch between soft austenitic phase and other harder phases. The constitutive equations were implemented into the implicit finite element software and a simple boundary value problem was chosen as a model problem to validate the effect of transformation plasticity on the deformation behavior of steel under cooling from high temperature. It was preliminary concluded that the transformation plasticity plays a critical role in relaxing the developed stress during forming and thus reducing the magnitude of springback.

• Bulletin of the Korean Chemical Society
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• 제14권4호
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• pp.461-465
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• 1993

Reductive transformations of gem-bromonitro compounds and ${\alpha}$-nitro ketones were carried out conveniently with sodium dithionite by using dioctyl viologen as an electron-transfer catalyst in dichloromethane-water two-phase system:the bromine atom in gem-bromonitro compounds and the nitro group in ${\alpha}$-nitro ketones are replaced by hydrogen.

• 한국재료학회지
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• 제23권6호
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• pp.329-333
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• 2013

The structural phase transformations of $0.7Pb(Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) were studied using high resolution x-ray diffraction (HRXRD) as a function of temperature and electric field. A phase transformational sequence of cubic (C)${\rightarrow}$tetragonal (T)${\rightarrow}$rhombohedral (R) phase was observed in zero-field-cooled conditions; and a $C{\rightarrow}T{\rightarrow}$monoclinic $(M_C){\rightarrow}$ monoclinic ($M_A$) phase was observed in the field-cooled conditions. The transformation of T to $M_A$ phase was realized through an intermediate $M_C$ phase. The results also represent conclusive and direct evidence of a $M_C$ to $M_A$ phase transformation in field-cooled conditions. Beginning from the zero-field-cooled condition, a $R{\rightarrow}M_A{\rightarrow}M_C{\rightarrow}T$ phase transformational sequence was found with an increasing electric field at a fixed temperature. Upon removal of the field, the $M_A$ phase was stable at room temperature. With increasing the field, the transformation temperature from T to $M_C$ and from $M_C$ to $M_A$ phase decreased, and the phase stability ranges of both T and $M_C$ phases increased. Upon removal of the field, the phase transformation from R to $M_A$ phase was irreversible, but from $M_A$ to $M_C$ was reversible, which means that $M_A$ is the dominant phase under the electric field. In the M phase region, the results confirmed that lattice parameters and tilt angles were weakly temperature dependent over the range of investigated temperatures.

• 열처리공학회지
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• 제23권5호
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• pp.233-238
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• 2010

The phase transformations and the shape memory effect in In-rich Pb alloys and In rich-Sn alloys have been studied by means of X-ray diffractometry supplemented by metallographic observations. The alloys containing 12~15 at.%Pb transform from the ${\alpha}_2$ (fct) phase to the ${\alpha}_1$ (fct) phase by way of an intermediate phase (m phase) on cooling. The results of X-ray diffraction show that the metastable intermediate phase is observed both on cooling and heating, and has a face-centered orthorhombic (fco) structure. It is concluded that the ${\alpha}_1{\rightleftarrows}{\alpha}_2$ transformation is expressed by the ${\alpha}_1{\rightleftarrows}m{\rightleftarrows}{\alpha}_2$ transformation both on usual cooling and heating with the rate more than $8{\times}10^{-3}$ K/s. The $m{\rightleftarrows}{\alpha}_2$ transformation takes place with a mechanism involving macroscopic shear and are of diffusionless (martensitic) type. The temperature hysteresis in the two transformations is 10~13 K between the heating and cooling transformations. The alloys containing 0~11 at.%Sn are -phase solid solutions with a face centered tetragonal structure (c/a > 1) at room temperature, the axial ratio increasing continuously with tin content. The In-(11~15) at.%Sn alloys are mixtures of ${\alpha}$ and ${\beta}$ phases, the ${\beta}$ phase having a f. c. tetragonal structure (c/a < 1). The alloys containing more than 15 at.%Sn are ${\beta}$-phase solid solutions. The In-(12.9~15.0) at.%Sn alloys show a shape memory effect only when quenched to the temperature of liquid nitrogen, although their effect becomes weak and finally disappears after keeping at room temperature for a long time. The ${\beta}{\rightarrow}{\alpha}^{\prime}$ phase transformation is of the diffusionless (martensitic) type, and takes place between 330 K at 12.9 at.%Sn and 150 K at 14.5 at.%Sn. The hysteresis of transformation temperatures on heating and cooling is considerably large (29~40 K), depending on the composition. Both In-Pb and In-Sn alloys showed distinct the shape memory effects.

• Journal of Advanced Marine Engineering and Technology
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• 제29권7호
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• pp.779-784
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• 2005

This paper presents the theory of similarity transformations applied to the momentum and energy equations for laminar, forced, external boundary layer flow over a horizontal flat plate which leads to a set of non-linear, ordinary differential equations of phase change material slurry(PCM Slurry). The momentum and energy equation set numerically to obtain the non-dimensional velocity and temperature profiles in a laminar boundary layer are solved. The heat transfer characteristics of PCM slurry was numerically investigated with similar method. It is clarified that the similar solution method of Newtonian fluid can be used reasonably this type of PCM slurry which has low concentration. The data of local wall heat flux and convective heat transfer coefficient of PCM slurry are higher than those of water more than 150$\~$200$\%$, approximately.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.161-161
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• 2003

• 열처리공학회지
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• 제16권6호
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• pp.320-328
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• 2003

A specimen of Cu-35%Sn alloy has been subjected to the unidirectional heat treatment in an attempt to examine the evolution of microstructures under varying thermal conditions. The specimen was cast in the form of a cylinder 10 mm in diameter and 200 mm in length, which was then installed in the temperature gradient field established inside a vertical tube furnace. The furnace temperature was adjusted to make the upper part at $750^{\circ}C$ and bottom end part at $300^{\circ}C$ of the specimen. The experiment was terminated by dropping it into water after the 30 minutes holding at given temperature. By the rapid cooling, the high temperature phases, ${\gamma}$ and ${\zeta}$, were retained at ambient temperature with some of ${\gamma}$ phase transformed to ${\varepsilon}$ phase, especially at the grain boundaries of ${\gamma}$ phase. The presence of ${\varepsilon}$ phase was found to determine the nature of phase transformations of the ${\zeta}$ phase undergoes upon cooling. In the close area of the ${\varepsilon}$ phase, ${\varepsilon}$ phase grew separately out of ${\zeta}$, and adds to the preexisting ${\varepsilon}$ whereas in areas away from ${\varepsilon}$, both ${\delta}$ and ${\varepsilon}$ grew simultaneously out of ${\zeta}$, and formed a lamella eutectoid structure. The transformation to ${\delta}$ was found to occur only in slow cooling. The hardness on each phase showed that the retained phases, ${\gamma}$ and ${\zeta}$, could be plastically deformed without brittle fracture while the phases, ${\varepsilon}$ and ${\delta}$, were too brittle to be deformed.