• 제목/요약/키워드: phase transformation behaviors

검색결과 55건 처리시간 0.025초

Angular 스펙트럼을 이용한 3차원 HPO 디지틀 홀로그램의 합성 (Angular-spectrum based 3-D HPO digital hologram synthesis)

  • 양훈기;김은수
    • 전자공학회논문지D
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    • 제34D권5호
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    • pp.67-74
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    • 1997
  • In this paper, we psresent a new scheme to synthetically generate a HPO digital hologram for a three-dimensional image that is modelled as the horizontally stacked two-dimensional images. The proposed method transforms a lightwave field into the angular spectrum of planewaves, which enables this method to use FFT routines, rather than using numerous arithmetic calculations. Hence, this method may be able to not only lead to the dramatically less computation but provide relatively excellent performances due to the phase error-free transformation. We present sampling constraints and implementaton procedure to obtian a hololine for each image and also point out the necessity of interpolation. Simulatioj results are presented to show the comparison with the conventional method in terms of computation time and performances, including the behaviors resulting form the different selection of parameter values to be used in the interpolations.

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Behavioral Current-Voltage Model with Intermediate States for Unipolar Resistive Memories

  • Kim, Young Su;Min, Kyeong-Sik
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제13권6호
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    • pp.539-545
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    • 2013
  • In this paper, a behavioral current-voltage model with intermediate states is proposed for analog applications of unipolar resistive memories, where intermediate resistance values between SET and RESET state are used to store analog data. In this model, SET and RESET behaviors are unified into one equation by the blending function and the percentage volume fraction of each region is modeled by the Johnson-Mehl-Avrami (JMA) equation that can describe the time-dependent phase transformation of unipolar memory. The proposed model is verified by the measured results of $TiO_2$ unipolar memory and tested by the SPECTRE circuit simulation with CMOS read and write circuits for unipolar resistive memories. With the proposed model, we also show that the behavioral model that combines the blending equation and JMA kinetics can universally describe not only unipolar memories but also bipolar ones. This universal behavioral model can be useful in practical applications, where various kinds of both unipolar and bipolar memories are being intensively studied, regardless of polarity of resistive memories.

Diffusion barrier characteristics of molybdenum nitride films for ultra-large-scale-integrated Cu metallization(II); Effect of deposition conditions on diffusion barrier behavior of molybdenum nitride

  • Lee, Jeong-Joub;Lee, You-Kee;Jeon, Seok-Ryong;Kim, dong-Joon
    • Journal of Korean Vacuum Science & Technology
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    • 제1권1호
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    • pp.30-37
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    • 1997
  • Interactions of Cu films with Si substrates separated by thin layers of molybdenum and molybdenum nitride were investigated in the viewpoint of diffusion barrier to copper. the diffusion barrier behavior of the layers was studied as functions of deposition and annealing conditions by cross-sectional transmission electron microscopy and Nomarski microscopy. the layers deposited at $N_2$ gas ratios of 0.4 and 0.5 exhibited good diffusion barrier behaviors up to $700^{\circ}C$, mainly due to the phase transformation of molybdenum to $\gamma$-Mo$_2$N phase. The increase in the N gas ratio in deposition elevates the lower limit of barrier failure temperature. Futhermore, amorphous molybdenum nitride films deposited at 20$0^{\circ}C$ and 30$0^{\circ}C$ did not fail, while the crystalline $\gamma$-Mo$_2$N films deposited at 40$0^{\circ}C$ and 50$0^{\circ}C$ showed signs of interlayer interactions between Cu and Si after annealing at 75$0^{\circ}C$ for 30 minutes. Therefore, the amorphous nature of the molybdenum nitride layer enhanced its ability to reduce Cu diffusion and its stability as a diffusion barrier at elevated temperatures.

Fe 함량에 따른 Ti-5Mo-xFe 준안정 베타 합금의 압축 변형거동 변화 (Change of Compressive Deformation Behaviors of Ti-5Mo-xFe Metastable Beta Alloy According to Fe Contents)

  • 이용재;이재관;이동근
    • 열처리공학회지
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    • 제36권5호
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    • pp.303-310
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    • 2023
  • β titanium alloys are widely used in aerospace industry due to their excellent specific strength and corrosion resistance. In particular, mechanical properties of metastable β titanium can efficiently be controlled by various deformation mechanisms such as slip, twinning, and SIM (Stress-Induced Martensite Transformation), making it an ideal material for many industrial applications. In this study, Ti-5Mo-xFe (x=1, 2, 4 wt%) alloy was designed by adding a relatively inexpensive β element to ensure price competitiveness. Additionally, microstructural analysis was conducted using OM, SEM, and XRD, while mechanical properties were evaluated through hardness and compression tests to consider the deformation mechanisms based on the Fe content. SIMT occurred in all three alloys and was influenced by the presence of βm (metastable beta) and beta stability. As the Fe content decreased, the α'' phase increased due to SIMT occurring within the βm phase, resulting in softening. Conversely, as the Fe content increased, the strength of the alloy increased due to a reduction in α'' formation and the contributions of solid solution strengthening and grain strengthening. Moreover, unlike the other alloys, shear bands were observed only in the fracture of the Ti-5Mo-4Fe alloy, which was attributed to differences in texture and microstructure.

Effect of Increased Oxygen Content due to Intensive Milling on Phase and Microstructural Development of Silicon Nitride

  • Kim, Hai-Doo;Ellen Y. Sun;Paul F. Becher;Kim, Hyo-Jong;Han, Byung-Dong;Park, Dong-Soo
    • 한국세라믹학회지
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    • 제38권5호
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    • pp.405-411
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    • 2001
  • Compacts of a mixture of fine $\alpha$-Si$_3$N$_4$powders, 6% $Y_2$O$_3$and 1% $Al_2$O$_3$were attrition milled time on phase and microstructural development in silicon nitride ceramics. The sintered surface and the interior showed different behaviors in phase and microstructral developments. Increased oxygen content with increased milling time of powder mixture leads to the formation of Si$_2$$N_2$O phase at temperatures as low as 155$0^{\circ}C$. Si$_2$$N_2$O is stable in the interior of the samples but unstable in the surface region of the specimen sintered at higher temperature. This results in a duplex structure where the interior consists of Si$_2$$N_2$O grains dispersed in $\beta$-Si$_3$N$_4$matrix and a surface which contains only $\beta$-Si$_3$N$_4$. The alpha to beta phase transformation and the microstructural development are shown to be influenced by the formation and decomposition of the Si$_2$$N_2$O.

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니켈-타이타늄 호선의 상전이 온도 범위와 상전이 행동 비교 (Comparison of transition temperature range and phase transformation behavior of nickel-titanium wires)

  • 이유현;임범순;이용근;김철위;백승학
    • 대한치과교정학회지
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    • 제40권1호
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    • pp.40-49
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    • 2010
  • 본 연구의 목적은 martensitic (M-NiTi), austenitic (A-NiTi) 및 thermodynamic nickel-titanium wire (T-NiTi)의 물리적 특징과 상전이 정도를 평가하는 것이다. 재료는 $0.016\;{\times}\;0.022$ inch의 M-NiTi (Nitinol Classic, NC), A-NiTi (Optimalloy, OPTI)와 T-NiTi (Neo-Sentalloy, NEO)이었으며, differential scanning calorimetry (DSC), 3점굽힘실험, X-ray diffraction (XRD), 미세구조 분석을 시행하였으며, ANOVA test로 통계처리하였다. DSC분석 결과 OPTI와 NEO는 heating curve에서 2개의 peak, cooling curve에서 1개의 peak를 보였고, NC는 heating과 cooling curve에서 1개의 넓고 약한 peak를 보였다. Austenite finishing ($A_f$) 온도는 OPTI $19.7^{\circ}C$, NEO $24.6^{\circ}C$, NC $52.4^{\circ}C$였다. 3점굽힘실험 결과 NC, OPTI, NEO 모두 residual deflection을 보였으며, NC와 OPTI의 load range가 NEO보다 컸다. XRD와 미세구조 분석결과 OPTI와 NEO는 Martensite finishing ($M_f$)에서 martensite와 austenite가 섞여 있음이 관찰되었다. NEO와 OPTI는 NC보다 개선된 물리적 특징과 상전이 행태를 보였다. NiTi 호선의 물리적, 온도에 따른 행태는 예상되었던 상전이 정도에 의해 완벽하게 설명되지 않았으며, 그 이유는 복잡한 martensite variants의 존재와 열과 stress에 의해 유도된 독립적인 상전이에 기인한다고 생각된다.

연속냉각 중 과냉 된 $Pd_{40}Cu_{30}Ni_{10}P_{20}$ 합금 용탕의 실시간 응고거동 관찰 (In Situ Observation of Solidification Behavior in Undercooled $Pd_{40}Cu_{30}Ni_{10}P_{20}$ Alloy Melts during Linear Cooling)

  • 김지훈
    • 한국주조공학회지
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    • 제23권5호
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    • pp.276-285
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    • 2003
  • In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

2방향 형상기억효과 SMA 띠가 부착된 복합재 보의 거동 (Smart Composite Beams with Shape Memory Alloy Strips Having TWSME)

  • 김정택;김철;윤지원
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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    • pp.51-54
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    • 2005
  • Shape memory alloys (SMAs) find many applications in smart composite structural systems as the active components. Their ability to provide a high force and large displacement makes them an excellent candidate for an actuator for controlling the shape of smart structures. In this paper, using a macroscopic model that captures the thermo-mechanical behaviors and the two-way shape memory effect (TWSME) of SMAs smart morphing polymeric composite shell structures like shape-changeable UAV wings is demonstrated and analyzed numerically and experimentally when subjected to various kinds of pressure loads. The controllable shapes of the morphing shells to that thin SMA strip actuator are attached are investigated depending on various phase transformation temperatures. SMA strips start to transform from the martensitic into the austenitic state upon actuation through resistive heating, simultaneously recover the prestrain, and thus cause the shell structures to deform three dimensionally. The behaviors of composite shells attached with SMA strip actuators are analyzed using the finite element methods and 3-D constitutive equations of SMAs. Several morphing composite shell structures are fabricated and their experimental shape changes depending on temperatures are compared to the numerical results. That two results show good correlations indicates the finite element analysis and 3-D constitutive equations are accurate enough to utilize them for the design of smart composite shell structures for various applications.

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형상기억합금 작동기를 이용한 복합재 보의 능동 형상 제어 (Active Shape Control of Composite Beam Using Shape Memory Alloy Actuators)

  • 양승만;노진호;한재흥;이인
    • Composites Research
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    • 제17권4호
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    • pp.18-24
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    • 2004
  • 본 논문에서는 복합재 구조물에 대하여 형상기억합금 선을 이용한 능동 형상 제어에 관한 연구를 수행하였다. 형상기억합금 선의 열-기계적인 특성을 실험적으로 측정하였으며, 복합재 보 시편의 표면에 볼트를 이용하여 형상기억합금 작동기를 고정하는 방법으로 하이브리드 복합재 구조물을 제작하였다 형상기억합금 작동기는 온도 상승에 의한 상변화에 의해 작동되며, 본 연구에서는 형상기억합금 작동기에 전력을 가하여 내부 저항을 통해 발생하는 열을 이용하여 구동하였다. 보다 빠르고 정확한 형상 및 변형 제어를 위하여 수치적 시뮬레이션을 통한 PID 되먹임 제어기를 설계하였으며, 형상기억합금 작동기에 적용하는 실험을 수행하였다.

산성광산배수에서 광물의 침전에 따른 미량 원소의 거동 (Behaviors of Trace Elements Caused by the Precipitation of Minerals in Acid Mine Drainage)

  • 윤영진;이지은;방상제;백영두;김영규
    • 한국광물학회지
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    • 제31권3호
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    • pp.173-182
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    • 2018
  • 산성광산배수에서 철광물의 침전 및 상전이 과정은 배수 내의 미량원소의 거동에 많은 영향을 미친다. 그러나 자연에서 일어나는 이러한 과정을 정확하게 추적하기는 쉽지 않아 많은 연구들이 산성광산배수에서 일어나는 광물의 침전 및 상전이에 대하여 실내 실험에 의존하는 경우가 많았다. 본 연구에서는 달성광산에서 채취한 배수를 대상으로 실제 산성광산배수에서 서로 다른 pH 값을 갖는 조건에서 시간이 지남에 따라 일어나는 광물의 침전과 이에 따른 배수 내의 미량 원소 변화를 살펴보았다. 침전된 광물의 양이 많지 않아 동정이 어려운 경우도 있었지만 침전된 광물들의 정보를 종합해 보면 대체적으로 비정질의 광물 먼저 형성된 후 아마도 슈베르트마나이트를 거쳐서 추후에 침철석이 침전된 것으로 사료된다. 그러나 시료 중 pH가 높은 경우(10)에는 계속적으로 비정질 상태로 남아있었다. 시간이 지남에 따라 광물의 침전 및 전이에 의하여 배수의 pH는 계속적으로 낮아지는 경향을 보였다. 모든 원소들이 높은 pH (8, 10)에서 낮은 농도를 보였는데 이는 높은 pH에서의 광물의 침전과 표면전하의 영향으로 판단되며 각 원소의 농도는 시간이 지남에 따라 조금씩 증가하였다. 황의 농도는 슈베르트마나이트에서 침철석으로의 전이의 영향으로 배수 내에서 역시 증가하였다.