• Title/Summary/Keyword: phase transformation behaviors

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Angular-spectrum based 3-D HPO digital hologram synthesis (Angular 스펙트럼을 이용한 3차원 HPO 디지틀 홀로그램의 합성)

  • 양훈기;김은수
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.5
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    • pp.67-74
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    • 1997
  • In this paper, we psresent a new scheme to synthetically generate a HPO digital hologram for a three-dimensional image that is modelled as the horizontally stacked two-dimensional images. The proposed method transforms a lightwave field into the angular spectrum of planewaves, which enables this method to use FFT routines, rather than using numerous arithmetic calculations. Hence, this method may be able to not only lead to the dramatically less computation but provide relatively excellent performances due to the phase error-free transformation. We present sampling constraints and implementaton procedure to obtian a hololine for each image and also point out the necessity of interpolation. Simulatioj results are presented to show the comparison with the conventional method in terms of computation time and performances, including the behaviors resulting form the different selection of parameter values to be used in the interpolations.

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Behavioral Current-Voltage Model with Intermediate States for Unipolar Resistive Memories

  • Kim, Young Su;Min, Kyeong-Sik
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.6
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    • pp.539-545
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    • 2013
  • In this paper, a behavioral current-voltage model with intermediate states is proposed for analog applications of unipolar resistive memories, where intermediate resistance values between SET and RESET state are used to store analog data. In this model, SET and RESET behaviors are unified into one equation by the blending function and the percentage volume fraction of each region is modeled by the Johnson-Mehl-Avrami (JMA) equation that can describe the time-dependent phase transformation of unipolar memory. The proposed model is verified by the measured results of $TiO_2$ unipolar memory and tested by the SPECTRE circuit simulation with CMOS read and write circuits for unipolar resistive memories. With the proposed model, we also show that the behavioral model that combines the blending equation and JMA kinetics can universally describe not only unipolar memories but also bipolar ones. This universal behavioral model can be useful in practical applications, where various kinds of both unipolar and bipolar memories are being intensively studied, regardless of polarity of resistive memories.

Diffusion barrier characteristics of molybdenum nitride films for ultra-large-scale-integrated Cu metallization(II); Effect of deposition conditions on diffusion barrier behavior of molybdenum nitride

  • Lee, Jeong-Joub;Lee, You-Kee;Jeon, Seok-Ryong;Kim, dong-Joon
    • Journal of Korean Vacuum Science & Technology
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    • v.1 no.1
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    • pp.30-37
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    • 1997
  • Interactions of Cu films with Si substrates separated by thin layers of molybdenum and molybdenum nitride were investigated in the viewpoint of diffusion barrier to copper. the diffusion barrier behavior of the layers was studied as functions of deposition and annealing conditions by cross-sectional transmission electron microscopy and Nomarski microscopy. the layers deposited at $N_2$ gas ratios of 0.4 and 0.5 exhibited good diffusion barrier behaviors up to $700^{\circ}C$, mainly due to the phase transformation of molybdenum to $\gamma$-Mo$_2$N phase. The increase in the N gas ratio in deposition elevates the lower limit of barrier failure temperature. Futhermore, amorphous molybdenum nitride films deposited at 20$0^{\circ}C$ and 30$0^{\circ}C$ did not fail, while the crystalline $\gamma$-Mo$_2$N films deposited at 40$0^{\circ}C$ and 50$0^{\circ}C$ showed signs of interlayer interactions between Cu and Si after annealing at 75$0^{\circ}C$ for 30 minutes. Therefore, the amorphous nature of the molybdenum nitride layer enhanced its ability to reduce Cu diffusion and its stability as a diffusion barrier at elevated temperatures.

Change of Compressive Deformation Behaviors of Ti-5Mo-xFe Metastable Beta Alloy According to Fe Contents (Fe 함량에 따른 Ti-5Mo-xFe 준안정 베타 합금의 압축 변형거동 변화)

  • Yong-Jae Lee;Jae Gwan Lee;Dong-Geun Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.5
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    • pp.303-310
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    • 2023
  • β titanium alloys are widely used in aerospace industry due to their excellent specific strength and corrosion resistance. In particular, mechanical properties of metastable β titanium can efficiently be controlled by various deformation mechanisms such as slip, twinning, and SIM (Stress-Induced Martensite Transformation), making it an ideal material for many industrial applications. In this study, Ti-5Mo-xFe (x=1, 2, 4 wt%) alloy was designed by adding a relatively inexpensive β element to ensure price competitiveness. Additionally, microstructural analysis was conducted using OM, SEM, and XRD, while mechanical properties were evaluated through hardness and compression tests to consider the deformation mechanisms based on the Fe content. SIMT occurred in all three alloys and was influenced by the presence of βm (metastable beta) and beta stability. As the Fe content decreased, the α'' phase increased due to SIMT occurring within the βm phase, resulting in softening. Conversely, as the Fe content increased, the strength of the alloy increased due to a reduction in α'' formation and the contributions of solid solution strengthening and grain strengthening. Moreover, unlike the other alloys, shear bands were observed only in the fracture of the Ti-5Mo-4Fe alloy, which was attributed to differences in texture and microstructure.

Effect of Increased Oxygen Content due to Intensive Milling on Phase and Microstructural Development of Silicon Nitride

  • Kim, Hai-Doo;Ellen Y. Sun;Paul F. Becher;Kim, Hyo-Jong;Han, Byung-Dong;Park, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.38 no.5
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    • pp.405-411
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    • 2001
  • Compacts of a mixture of fine $\alpha$-Si$_3$N$_4$powders, 6% $Y_2$O$_3$and 1% $Al_2$O$_3$were attrition milled time on phase and microstructural development in silicon nitride ceramics. The sintered surface and the interior showed different behaviors in phase and microstructral developments. Increased oxygen content with increased milling time of powder mixture leads to the formation of Si$_2$$N_2$O phase at temperatures as low as 155$0^{\circ}C$. Si$_2$$N_2$O is stable in the interior of the samples but unstable in the surface region of the specimen sintered at higher temperature. This results in a duplex structure where the interior consists of Si$_2$$N_2$O grains dispersed in $\beta$-Si$_3$N$_4$matrix and a surface which contains only $\beta$-Si$_3$N$_4$. The alpha to beta phase transformation and the microstructural development are shown to be influenced by the formation and decomposition of the Si$_2$$N_2$O.

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Comparison of transition temperature range and phase transformation behavior of nickel-titanium wires (니켈-타이타늄 호선의 상전이 온도 범위와 상전이 행동 비교)

  • Lee, Yu-Hyun;Lim, Bum-Soon;Lee, Yong-Keun;Kim, Cheol-We;Baek, Seung-Hak
    • The korean journal of orthodontics
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    • v.40 no.1
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    • pp.40-49
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    • 2010
  • Objective: The aim of this research was to evaluate the mechanical properties (MP) and degree of the phase transformation (PT) of martensitic (M-NiTi), austenitic (A-NiTi) and thermodynamic nickel-titanium wire (T-NiTi). Methods: The samples consisted of $0.016\;{\times}\;0.022$ inch M-NiTi (Nitinol Classic, NC), A-NiTi (Optimalloy, OPTI) and T-NiTi (Neo-Sentalloy, NEO). Differential scanning calorimetry (DSC), three-point bending test, X-ray diffraction (XRD), and microstructure examination were used. Statistical evaluation was undertaken using ANOVA test. Results: In DSC analysis, OPTI and NEO showed two peaks in the heating curves and one peak in the cooling curves. However, NC revealed one single broad and weak peak in the heating and cooling curves. Austenite finishing ($A_f$) temperatures were $19.7^{\circ}C$ for OPTI, $24.6^{\circ}C$ for NEO and $52.4^{\circ}C$ for NC. In the three-point bending test, residual deflection was observed for NC, OPTI and NEO. The load ranges of NC and OPTI were broader and higher than NEO. XRD and microstructure analyses showed that OPTI and NEO had a mixture of martensite and austenite at temperatures below Martensite finishing ($M_f$). NEO and OPTI showed improved MP and PT behavior than NC. Conclusions: The mechanical and thermal behaviors of NiTi wire cannot be completely explained by the expected degree of PT because of complicated martensite variants and independent PT induced by heat and stress.

In Situ Observation of Solidification Behavior in Undercooled $Pd_{40}Cu_{30}Ni_{10}P_{20}$ Alloy Melts during Linear Cooling (연속냉각 중 과냉 된 $Pd_{40}Cu_{30}Ni_{10}P_{20}$ 합금 용탕의 실시간 응고거동 관찰)

  • Kim, Ji-Hun
    • Journal of Korea Foundry Society
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    • v.23 no.5
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    • pp.276-285
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    • 2003
  • In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

Smart Composite Beams with Shape Memory Alloy Strips Having TWSME (2방향 형상기억효과 SMA 띠가 부착된 복합재 보의 거동)

  • Kim, Jung-Taek;Kim, Cheol;Yoon, Ji-Won
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.51-54
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    • 2005
  • Shape memory alloys (SMAs) find many applications in smart composite structural systems as the active components. Their ability to provide a high force and large displacement makes them an excellent candidate for an actuator for controlling the shape of smart structures. In this paper, using a macroscopic model that captures the thermo-mechanical behaviors and the two-way shape memory effect (TWSME) of SMAs smart morphing polymeric composite shell structures like shape-changeable UAV wings is demonstrated and analyzed numerically and experimentally when subjected to various kinds of pressure loads. The controllable shapes of the morphing shells to that thin SMA strip actuator are attached are investigated depending on various phase transformation temperatures. SMA strips start to transform from the martensitic into the austenitic state upon actuation through resistive heating, simultaneously recover the prestrain, and thus cause the shell structures to deform three dimensionally. The behaviors of composite shells attached with SMA strip actuators are analyzed using the finite element methods and 3-D constitutive equations of SMAs. Several morphing composite shell structures are fabricated and their experimental shape changes depending on temperatures are compared to the numerical results. That two results show good correlations indicates the finite element analysis and 3-D constitutive equations are accurate enough to utilize them for the design of smart composite shell structures for various applications.

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Active Shape Control of Composite Beam Using Shape Memory Alloy Actuators (형상기억합금 작동기를 이용한 복합재 보의 능동 형상 제어)

  • Yang, Seung-Man;Roh, Jin-Ho;Han, Jae-Hung;Lee, In
    • Composites Research
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    • v.17 no.4
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    • pp.18-24
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    • 2004
  • In this paper, active shape control of composite structures actuated by shape memory alloy (SMA) wires is presented. The thermo-mechanical behaviors of SMA wires were experimentally measured. Hybrid composite structures were established by attaching SMA actuators on the surfaces of graphite/epoxy composite beams using bolt-joint connectors. SMA actuators were activated by phase transformation, which induced by temperature rising over austenite finish temperature. In this paper, electrical resistive heating was applied to the hybrid composite structures to activate the SMA actuators. For (aster and more accurate shape/deflection control of the hybrid composite structure, PID feedback controller was designed from numerical simulations and experimentally applied to the SMA actuators.

Behaviors of Trace Elements Caused by the Precipitation of Minerals in Acid Mine Drainage (산성광산배수에서 광물의 침전에 따른 미량 원소의 거동)

  • Yoon, Young Jin;Lee, Ji Eun;Bang, Sang Je;Baek, Young Doo;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.173-182
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    • 2018
  • The precipitation and phase transformation processes of iron minerals in acid mine drainage have a great influence on the behavior of trace elements in drainage. However, it is not easy to accurately trace these processes in natural environments, and therefore, most studies have carried out in the laboratory to obtain the information on the precipitation and transformation of those minerals. In this study, the precipitation of minerals and the changes of trace elements in drainage water were investigated at different pH values in actual acid mine drainage collected from the Dalsung mine. The amount of some precipitated minerals was not enough for the mineral identification. However, from the minerals identified, amorphous minerals were formed first, and then goethite was precipitated probably from schwertmannite. When the pH of the sample was high (10), amorphous phases of minerals were still observed at even high pH (pH 10). With increasing time, the pH values decreased by precipitation and transformation of minerals. All the elements showed low concentrations at high pH (8, 10), which might be due to the precipitation of minerals at high pH and the effect of surface charge, and the concentrations of elements gradually increased with time. In the case of sulfur, it also increased in water due to the transformation of schwertmannite to goethite.