• Title/Summary/Keyword: phase change materials

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Conductivity Characteristics of ${Ge_1}{Se_1}{Te_2}$ Amorphous Chalcogenide Thin Film for the Phase-Change Memory Application (상변화 메모리 응용을 위한 ${Ge_1}{Se_1}{Te_2}$ 비정질 칼코게나이드 박막의 전도 록성)

  • Choi, Hyuk;Kim, Hyun-Gu;Cho, Won-Ju;Chung, Hong-Bay
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.32-33
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    • 2006
  • As next generation nonvolatile memory, chalcogenide-based phase change memory can substitute for a conventional flash memory from its high performance. Also, fast writing speed, low writing voltage, high sensing margin, low power consumption and repetition reliability over $10^{15}$ cycle shows its possibility. At our laboratory, we invented ${Ge_1}{Se_1}{Te_2}$ material to alternate with conventional ${Ge_2}{Sb_2}{Te_5}$ for improve its ability. We respect the ${Ge_1}{Se_1}{Te_2}$ material can be a solution for high power consumption problem and long time at 'set' performance. A conductivity experiment from variable temperature was performed to see reliability of repetition at read and write performance. Compare with conventional ${Ge_2}{Sb_2}{Te_5}$ material, these two materials are used as complex compound to get the finest parameter.

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TMA-Water Clathrate Compound of Cooling Characteristics for Low Temperature Latent Heat Storage (저온잠열축열을 위한 TMA-물계 포접화합물의 냉각특성)

  • Kim, Chang-Oh;Chung, Hyoun-Ho;Chung, Nak-Kyu
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.296-301
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

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Properties of GST Thin Films for PRAM with Composition (PRAM용 GST계 박막의 조성에 따른 특성)

  • Jung, Myung-Hun;Jang, Nak-Won;Kim, Hong-Seung;Ryu, Sang-Ouk;Lee, Nam-Teal;Yoon, Sung-Min;Park, Young-Sam;Lee, Seung-Yun;Yu, Byoung-Gon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.203-204
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    • 2005
  • PRAM (Phase change Random Access Memory) is one of the most promising candidates for next generation Non-volatile Memories. The Phase change material has been researched in the field of optical data storage media. Among the phase change materials $Ge_2Sb_2Te_5$(GST) is very well known for its high optical contrast in the state of amorphous and crystalline. However, the characteristics required in solid state memory are quite different from optical ones. In this study, the structural properties of GST thin films with composition were investigated for PRAM. The 100-nm thick GeTe and $Sb_2Te_3$ films were deposited on $SiO_2$/Si substrates by RF sputtering system. In order to characterize the crystal structure and morphology of these films, we performed x-ray diffraction (XRD) and atomic force microscopy (AFM).

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A promising form-stable phase change material prepared using cost effective Jute stick Biochar as the matrix of stearic acid for thermal energy storage (황마 바이오차를 사용한 에너지 저장용 상변화 물질의 제조 및 성능평가에 관한 연구)

  • Adnin, Raihana Jannat;Mandal, Soumen;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.169-170
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    • 2022
  • Due to the higher use of nonrenewable fossil fuel energy, environment friendly sustainable energy from waste materials is attracting attention of the researchers. Considering that, jute stick (JS) biochar has been considered for this study for ecofriendly and sustainable thermal energy storage application. Waste jute sticks (JS), which are being mainly used as a fuel for cooking purpose, have been pyrolyzed to produce porous biochar and have been used for shape stabilization of stearic acid (SA) as phase change material (PCM). SA at 1:1 ratio has been incorporated into the activated JS biochar to concoct shape-stabilized phase change composite (SAJS). The SAJS has been evaluated by different techniques such as Fourier transform-infrared spectroscope (FT-IR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The obtained composite PCM has shown excellent shape stability with a high latent heat storage, suggesting its suitability for thermal energy storage applications.

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Impact of Ba Substitution on the Magnetocaloric Effect in La1-xBaxMnO3 Manganites

  • Hussain, Imad;Anwar, M.S.;Kim, Eunji;Koo, Bon Heun;Lee, Chan Gyu
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.623-627
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    • 2016
  • $La_{1-x}Ba_xMnO_3$ (x = 0.30, 0.35 and 0.40) samples have been prepared by solid-state reaction method. The X-ray diffraction (XRD) study showed that all the samples crystallized in a rhombohedral structure with an R-3c space group. Variation of the magnetization as a function of the temperature and applied magnetic field was carried out. All the samples revealed ferromagnetic to paramagnetic (FM-PM) phase transition at the Curie temperature $T_C{\sim}342K$. The magnetic entropy change was also studied through examination of the measured magnetic isotherms M(H, T) near $T_C$. The magnetocaloric effect was calculated in terms of the isothermal magnetic entropy change. The maximum entropy change reaches a value of 1.192 J/kgK under a magnetic field change of 2.5T for the $La_{0.6}Ba_{0.4}MnO_3$ composition. The relative cooling power (RCP) is 79.31 J/kg for the same applied magnetic field.

Microstructures and Mechanical Properties of SiC Containing $SiC_{platelet}$ Seeds of Various Size (여러 가지 크기의 $SiC_{platelet}$ Seed를 함유한 SiC 세라믹스의 미세구조 및 기계적 특성)

  • Choi, Myoung-Je;Park, Chan;Park, Dong-Soo;Kim, Hai-Doo
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1094-1101
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    • 1999
  • Liquid phase sintered silicon carbides were obtained by sintering of $\alpha$-SiC and $\beta$-SiC powders as starting materials at 2173K and 2273K respectively. The SiCplatelet seeds of different sizes were obtained by a repeated ball milling and sedimentation. Their mean size (d50) were 2.217 ${\mu}{\textrm}{m}$ 13.67 ${\mu}{\textrm}{m}$, 22.17${\mu}{\textrm}{m}$ respectively 6wt%Al2O3-4 wt% Y2O3 was used as the sintering additives for the liquid phase sintering. The two silicon carbides had a bimodal microstructure consisting of small matrix grains and large platelike grains when the SiCplatelet seeds were added. In the case of the $\beta$-SiC the appreciable phase transformation occurred as sintering temperature increased from 2173K to 2273K and resulted in matrix shape change from equiaxed into platelike grains. In contrast there was no shape change for the $\alpha$-SiC. The size of large grains in the $\alpha$-SiC of large grains in the $\alpha$-SiC was larger than that of the large grains in the $\beta$-SiC These results suggested that the growth of the $\alpha$-SiCplatelet in the $\alpha$-SiC matrix was more favored than that of the $\alpha$-SiCplatelet in the $\beta$-SiC matix. The three point flexural strength decreased as the added seed size increased. Fracture toughness values of samples sintered at 2273K were higher than those of samples sintered at 2173K.

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Feasibility Study of Cold Storage System to Maintaining Cooling Performance for ISG Vehicle (공회전 제한장치 차량에서 냉방 성능 유지를 위한 축냉 시스템 적용에 대한 연구)

  • Lee, Daewoong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.1
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    • pp.7-14
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    • 2016
  • This study explores the feasibility of a cold storage system to provide thermal comfort for idle stop and go (ISG) vehicles. ISG function is the most valuable and environmental friendly technology in the current automobile industry. However, when an ISG vehicle stops, meaning when the engine standstill, the air-conditioning system does not work, because the compressor also stops. Therefore, passenger thermal comfort is not maintained, as cold air is not provided in the cabin. Consequently, many automakers have studied electric air-conditioning systems based on electrically-driven compressors or cold storage systems using phase-change materials. The experiments herein were conducted for the feasibility testing of different types of cold storage heat-exchangers, cold storage mediums, and thermo-expansion valves with current air-conditioners. The auxiliary cold storage system, filled with phase-change materials, was located behind the evaporator and almost stacked on top of it. In the experimental results, the air discharge temperature rate of increase was better than the conventional air-conditioning system when the compressor stopped and thermal comfort was maintained with $1.9{\sim}4.3^{\circ}C$ decreases within 60 seconds. The #1 cold storage heat-exchanger (CSH), #2 thermo-expansion valve (TXV) and #2 phase change material (PCM) were chosen because of the best temperature rise delay. It was concluded that a cold storage system is an effective solution for ISG vehicles to maintain thermal comfort during short engine stops.

Eutectic-based Phase-change Recording Materials for 1-2X and 4X Speed Blu-ray Disc

  • Seo Hun;Lee Seung-Yoon;Lee Kwang- Lyul;Kim Jin-Hong;Bae Byeong-Soo
    • Transactions of the Society of Information Storage Systems
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    • v.1 no.1
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    • pp.34-41
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    • 2005
  • We report some recent results in the rewritable Blu-ray Disc with enhanced overwrite cyclability by using the growth dominant eutectic based Ge(Sb70Te30)+Sb recording layer, GeN interface layer and write strategy optimization. We have developed phase-change optical media with appropriate write strategy for 36(i.e., 1X)-72Mbps(i.e., 2X) dual speed Blu-ray Disc system and fur the future high speed optical data storage. For recording layer, eutectic-based Ge(Sb70Te30)+Sb material was used and Sb/Te ratio and Ge content were optimized to obtain proper erasability and archival stability of recorded amorphous marks. The recording layer is wrapped up in GeN interface layers to obtain overwrite cyclability and higher crystallization speed. In addition, we designed appropriate write strategy so called Time-Shifted Multipulse (TSMP) write strategy where starting position of multipulse parts are shined from reference clock. With this write strategy, the jitter characteristics of the disc was improved and we found that leading edge jitter was improved much more than trailing edge jitter in 1X-2X speed recording. Finally, we investigated the higher speed feasibility of 144Mbps(i.e., 4X) by adopting some elemental doping to the eutectic based Ag-In-Sb-Te recording layer and structural optimization of constitution layers in Blu-ray Disc. In the paper, we report the effect of Sn addition for the feasibility of higher speed recording. The addition of Sn shows increases of the crystallization speed of phase change recording layer.

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Resolution of Tocainide and Its Analogues on a Doubly Tethered N-CH3 Amide Chiral Stationary Phase Based on (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid

  • Lee, Kyu Jung;Tak, Kyung Mi;Hyun, Myung Ho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2978-2982
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    • 2013
  • A doubly tethered $N-CH_3$ amide chiral stationary phase (CSP 4) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid was applied to the resolution of an antiarrythmic agent, tocainide, and its analogues and the chromatographic resolution results were compared with those on a singly tethered N-H amide CSP (CSP 1), a singly tethered $N-CH_3$ amide CSP (CSP 2) and a doubly tethered N-H amide CSP (CSP 3) under an identical aqueous mobile phase condition. CSP 4 was found to be generally better than other CSPs in terms of the separation factors (${\alpha}$) and resolutions (RS). The retention times of analytes denoted by the retention factors ($k_1$) on CSP 4 were quite long compared to those on other CSPs because of the improved lipophilicity of CSP 4. The long retention times of analytes on CSP 4 were successfully controlled by the addition of a small amount of ammonium acetate to aqueous mobile phase without hurting the chiral recognition efficiency. The variation of the content and type of organic and acidic modifier in aqueous mobile phase was found not to change the chiral recognition efficiency significantly.

The Effect of Thermomechanical Treatment on the Transformation Characteristics and Mechanical Properties in a Cu-Al-Ni-Ti-Mn Alloy (Cu-Al-Ni-Ti-Mn 합금의 변태특성 및 기계적 성질에 미치는 가공열처리의 영향)

  • Kim, C.D.;Lee, Y.S.;Yang, G.S.;Jang, W.Y.;Kang, J.W.;Baek, S.N.;Gwak, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.2
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    • pp.145-156
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    • 1999
  • The distribution of the second phase, the change of transformation temperature and mechanical properties with thermomechanical treatment conditions were investigated by metallography, calorimetry, EDS, tensile test and fractography in a Cu-Al-Ni-Ti-Mn alloy. The cast structure revealed Ti-rich precipitates($X_L$ phase) between dendrite arms, which have been identified as $(Cu,Ni)_2TiAl$ intermetallic compounds. By homogenizing above $900^{\circ}C$, the $X_L$ phase was melted in the matrix, while the Xs phase was precipitated in matrix and the volume fraction of it was increased. When hot-rolled specimen was betatized below $750^{\circ}C$, recrystallization could not be observed. However, the specimen betatized above $800^{\circ}C$ was recrystallized and the grain size was about $50{\mu}m$, while Xs phase was precipitated in matrix. With raising betatizing temperature, $M_s$ and $A_s$ temperatures were fallen and transformation hysteresis became larger. The strain of the specimen betatized at $800^{\circ}C$ was 8.2% as maximum value. The maximum shape recovery rate could be obtained in the specimen betatized at $800^{\circ}C$ but it was decreased due to the presence of Xs phase with increasing betatizing temperature.

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