• 한국전기전자재료학회논문지
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• 제28권3호
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• pp.160-164
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• 2015

In this study, $(1-x)Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3+xCeMnO_3$ (x= 0~0.02) ceramics were prepared by Columbite precursor method. The phase structure, ferroelectric and piezoelectric properties were systematically investigated. It was found that PMW-PNN-PZT possessed superior electrical properties due to its composition close to the MPB (morphotropic phase boundary). Coercive electric field of 10.05 [kV/cm] and density of 7.88 [$g/cm^3$] were obtained when the substitution amount of $CeMnO_3$ is x=0.02. In contrast, specimens with x=0.01 showed the mechanical quality factor($Q_m$) of 1,091 and the electromechanical coupling factor($k_p$) of 0.613.

• 설비공학논문집
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• 제16권10호
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• pp.942-951
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• 2004

This paper presents the results of a theoretical study of the effect of radiation during free convective laminar film boiling for methanol/water binary mixtures on an isothermal vertical wall at atmospheric pressure. With the well-known boundary layer theory as a basis, a theoretical model has been formulated into consideration for mass diffusion at liquid phase. The equations are numerically solved by a similarity method to investigate the effects of radiation emissivity on the surface with various parameters such as wall superheat and composition of more volatile component at liquid phase far from the wall. From the results, the distributions of the physical quantifies are investigated in both phases. New correlations are proposed to predict the heat transfer coefficient of binary mixtures. It is shown that the proposed correlations are in good agreement with numerical results and with Bromley's correlation within maximum $11\%$ errors. It is also found that as the wall superheat is increased, radiation effect becomes more important.

• 열처리공학회지
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• 제35권1호
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• pp.1-7
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• 2022

In this study, dissolution and melting phenomenon of the Al₂Cu was studied for the high-strength Al-Si-Cu aluminum alloy in automobile component. The Solution heat treatment was performed at 480℃ and 510℃ for 4hours. Microstructure analysis of the specimen was performed using the optical micrograph and scanning electron microscope for qualitative and quantitative analysis of various phases, the chemical composition of secondary phases was achieved by energy dispersive spectroscopy (EDS) and electron probe micro analysis (EPMA). As a result of the electron probe micro analysis, a plate like Al₂Cu phase was observed, and eutectic Si phase was observed of a coarsen plate shape. At a temperature of 510, necking phenomenon occurs in a specific part of plate like Al₂Cu, and it is segmented and dissolved in the Al matrix. When the temperature of the alloy exceeds the melting point of Al₂Cu, incipient melting occurs at the grain boundary of undissolved Cu particles

• 한국재료학회지
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• 제14권1호
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• pp.35-40
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• 2004

In this study, dissolution characteristics of four types of commercial calcium phosphate ceramics were investigated in distilled water with respect to chemical composition and microstructure. For all samples, no significant damage was observed after 3 days of immersion. Following the 7 days of immersion, surface dissolution of the ceramics containing a crystalline phase susceptible to water such as TCP, even pure hydroxyapatite, was initiated at grain boundaries and the dissolution was extended interior to the material along the grain boundaries. In the considerably dissolved area, there was grain separation followed by the formation of 20 $\mu\textrm{m}$ of cavities. In at least one case, the residual pores on the surface appeared to initiate dissolution. In a dissolved area, a crack during the fracture propagates along the grain boundaries resulting in intergranular fracture, while transgranular fracture occurs in a dense area without significant dissolution.

• 한국세라믹학회지
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• 제24권5호
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• pp.470-476
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• 1987

The system of 0.1Pb(Mg1/3N2/3)O3-yPbTiO3-zPbZrO3 piezoelectric ceramics was made in the radial model disk and ring dot type filter. The resonant frequency(fr) variations were investigated for 100 hours and the temperature range from 20$^{\circ}C$ to 100$^{\circ}C$. As the results, the morphotropic phase boundary was supposed to be the composition of 45 y 50 and 40 z 45. The best characteristic of againg effect, after 10-hours, was composed of y, z=45. The stabilized characteristic of temperature varition, to become 0.1% up to 100$^{\circ}C$, was composed of y=50 and z=40. The bandwidth was broadened with increasing the electromechanical coefficient(kp), and the filter characteristics was approached ideal mode with increasing mechanical quality factor(Qm). Kp and Qm affected combinationally on filter characteristics.

• 한국세라믹학회지
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• 제31권11호
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• pp.1299-1306
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• 1994

Effect of MgO content on microstructural evolution and microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 system was investigated. MgO content was varied from 10 mol% deficiency to 10 mol% excess of stoichiometric composition, respectively. It was found that MgO-deficient specimen showed faster grain growth rate than stoichometric and MgO excess BMT system. Besides, sandwich type precipitates of Ba5Ta4O15 which was formed within the BMT grain, might lead to the anisotropic grain growth of BMT grain. On the contrary, in MgO excess specimen, BMT grain growth rate was retarded by precipitations of MgO phase in grain boundary. Besides, the Q values of MgO-deficient showed lower than MgO-excess due to precipitations of Ba5Ta4O15 within BMT grain.

• 센서학회지
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• 제13권2호
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• pp.152-156
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• 2004

The dielectric and piezoelectric properties of 0.36Pb($Sc_{1/2}Nb_{1/2}$)$O_{3}$-0.25Pb($Ni_{1/3}Nb_{2/3}$)$O_{3}$-0.39Pb$TiO_{3}$ (hereafter PSNNT) at the morphotropic phase boundary (MPB) composition were investigated with $0{\sim}2.5$ mot% $MnO_{2}$ doping. Bulk density, dielectric loss and tetragonality of crystal structure were all improved with increasing $MnO_{2}$ additive content. With increasing $MnO_{2}$ additive content, the electromechanical coupling factor and quality factor were also increased: Electromechanical coupling $k_{p}$ and quality factor $Q_{m}$ at 2.0 mol% $MnO_{2}$ doping with were showed highest values of 55.6 % and 252, respectively.

• 한국세라믹학회지
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• 제23권1호
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• pp.13-20
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• 1986

Zirconia soild electrolytes containing 4~10mol% of yttria were prepared by wet-blending of oxides and rea-ction-sintering, Sinterbility and degree of stabilization were optimized for the development of oxygen sensor. Fracture strength thermal expansion coefficient electrical conductivity and galvanic potential were measured and discussed with respect to the amount of ytria addition phase transformation microstructure and degree of stabilization. It was found that sintering and stabilization occurred when the composition was designed to be near the boundary region of $ZrO_2-Y_2O_3$ binary system. In such away a good zirconia solid electrolyte suitable for oxygen sensor could be developed.

• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.351-356
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• 1996

The quartemary system ceramics 0.5[xPb(Zn$_{1}$3/Nb$_{2}$3/)O$_{3}$-(1-x)Pb(Ni$_{1}$3/Nb$_{2}$3/)O$_{3}$]-0.5[yPbTiO$_{3}$-(1-y) PbZrO$_{3}$ for piezoelectric actuators were prepared bv the were added to the raw materials up to 5 mole. Sintering temperature was varied form 1000.deg. C to 1200.deg. C. Sintering characteristrics, dielectric and piezoelectric properties were then investigated. Piezoelectric properties of sample prepared by the molten salt method were improved compared to those prepared by the conventional method. Addition of PZN shifted morphotropic phase boundary to more Zr-rich composition and decreased the piezoelectric properties.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.812-813
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• 2006

Dimensional change of compact made from (Fe-Cu) prealloyed powder and copper powder compared to that of compact made from iron-copper elemental powder. The compact made from the prealloyed powder with a copper content of 7.18mass% which is nearly equal to its solution limit and copper powder showed only the large contraction in spite of penetration of liquid copper into grain boundary of the prealloyed powder. But the compact made from iron-copper elemental powder showed the large expansion in spite of same chemical composition with former case.