• 제목/요약/키워드: petroleum contamination

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지반 오염도 조사를 위한 전기비저항/정전용량 측정콘의 적용성 평가 (Applicability of Resistivity/Capacitance Measurement on CPT Module for Investigation of Subsurface Contamination)

  • 오명학;김용성;박준범
    • 한국지반공학회논문집
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    • 제22권7호
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    • pp.45-54
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    • 2006
  • 전기비저항콘은 현장에서 지반의 오염대를 조사하는데 상대적으로 경제적인 비용으로 적용될 수 있다. 그러나, 전기비저항 결과만에 의한 해석은 정량적 데이터베이스의 부족과 함수비 등의 다른 지반공학적 영향인자들에 의해 모호한 결과를 나타낼 수 있다. 본 연구에서는 지반오염조사에서의 전기비저항 측정기법을 보완하기 위하여 정전용량 측정기법을 도입하여 중금속과 유류로 오염된 지반에서의 적용성을 평가하고자 하였다. 함수비와 오염물질의 종류에 따른 전기비저항과 정전용량의 변화를 평가하기 위하여 실내모형시험을 수행하였으며, 그 결과 전기비저항과 유전상수를 통시에 측정하여 분석함으로써 오염대의 감지에 신뢰도를 높일 수 있는 것으로 나타났다. 전기비저항과 정전용량 측정기법은 중금속으로 오염된 포화지반과 지하수대 상부에 존재하는 디젤유 오염층을 감지하는 데 적용성이 높은 것으로 나타났다.

오일의 누출이 토양오염, 식생 및 지하수에 주는 영향에 관한 연구 (A Study on the Effect of. Oil Leakage for Soil Contamination, Plants and Groundwater)

  • 진성기;도덕현;최규홍
    • 한국농공학회지
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    • 제36권1호
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    • pp.141-152
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    • 1994
  • Our experiment investigated the degree of soil contaimination caused by oil leakage. Each soil sample was taken by boring 5, 8m below the test areas, located 5 to 30m from storage tanks at oil stations. According to the results from a series of laboratory tests(both soxhiet extract test and gas chromatograph test), Traces of a light oil were found in all samples except in Dj8, rocky soil and gasoline and petroleum were not detected. We concluded that soil contamination was caused by the corrosion of storage tanks or alternatively by oil overflow caused during the flooding of underground water seeping into the tank during heavy rain fall or the spillage caused by carelessness during lubrication. Old stations without a concrete box enclosing their metal tanks run a greater risk of oil leakage. To research the effect of oil leakage on plant growth and underground water, We examined the results of research conducted overseas. According to these results, when oil leakage occurs, plant growth is repressed and agricultural crops experience low productivity levels. Also, the contamination of underground water can be serious when oil spreads to the aquifer layer. As a result of these problems, to prevent oil leakage and minimize its contaminating effects at oil stations, it is necessary to improve facilities of storage tanks and have the monitoring system of oil leakage.

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부지 오염도 평가시 불확실성 정량화 및 저감방안 (Quantification of Uncertainty Associated with Environmental Site Assessments and Its Reduction Approaches)

  • 김건하;백종환;송영우
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권1호
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    • pp.26-33
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    • 2014
  • Uncertainty associated with a sampling method is very high in evaluating the degree of site contamination; therefore, such uncertainty affects the reliability of precise investigation and remediation verification. In particular, in evaluating a site for a small-sized filling station, underground utilities, such as connection pipes and oil storage tanks, make grid-unit sampling impossible and the resulting increase in uncertainty is inevitable. Accordingly, this study quantified the uncertainty related to the evaluation of the degree of contamination by total petroleum hydrocarbon and by benzene, toluene, ethylene, and xylene. When planning a grid aimed at detecting a hot spot, major factors that influence the increase in uncertainty include grid interval and the size and shape of the hot spot. The current guideline for soil sampling prescribes that the grid interval increase in proportion to the area of the evaluated site, but this heightens the possibility that a hot spot will not be detected. In evaluating a site, therefore, it is crucial to estimate the size and shape of the hot spot in advance and to establish a sampling plan considering a diversity of scenarios.

Fluorescence Characteristic Spectra of Domestic Fuel Products through Laser Induced Fluorescence Detection

  • Wu, Ting-Nien;Chang, Shui-Ping;Tsai, Wen-Hsien;Lin, Cian-Yi
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.18-25
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    • 2014
  • Traditional investigation procedures of soil and groundwater contamination are followed by soil gas sampling, soil sampling, groundwater sampling, establishment of monitoring wells, and groundwater monitoring. It often takes several weeks to obtain the analysis reports, and sometimes, it needs supplemental sampling and analysis to delineate the polluted area. Laser induced fluorescence (LIF) system is designed for the detection of free-phase petroleum pollutants, and it is suitable for on-site real-time site investigation when coupling with a direct push testing tool. Petroleum products always contain polycyclic aromatic hydrocarbon (PAH) compounds possessing fluorescence characteristics that make them detectable through LIF detection. In this study, LIF spectroscopy of 5 major fuel products was conducted to establish the databank of LIF fluorescence characteristic spectra, including gasoline, diesel, jet fuel, marine fuel and low-sulfur fuel. Multivariate statistical tools were also applied to distinguish LIF fluorescence characteristic spectra among the mixtures of selected fuel products. This study successfully demonstrated the feasibility of identifying fuel species based on LIF characteristic fluorescence spectra, also LIF seemed to be uncovered its powerful ability of tracing underground petroleum leakages.

유류로 오염된 토양의 생물학적 처리기법에 관한 연구 (A Study on the Biological Remediation Technology for Oil Contaminated Sites)

  • 조재립
    • 한국품질경영학회:학술대회논문집
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    • 한국품질경영학회 2004년도 품질경영모델을 통한 가치 창출
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    • pp.307-312
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    • 2004
  • Contamination of industrial sites has happened by a variety compounds. Petroleum hydrocarbons, which are readily biodegradable, are reported principle contaminats in most industrial sites. Therefore, the use of biological processes will be a promising technology for remediation of industrial sites. This paper addresses the possible use of biological processes in remediation of contaminated industrial sites and discusses the background and main streams of the process. The paper also characterizes representative biological systems developed for application.

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유류오염 토양/지하수 환경복원 조사${\cdot}$설계 사례 (Environmental Remedial Investigation and plan for the soil and groundwater contaminated with petroleum)

  • 김영웅
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2001년도 정기총회 및 제3회 특별지포지움
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    • pp.57-74
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    • 2001
  • 유류오염 토양${\cdot}$지하수의 위해성은 널리 알려져 있다. 따라서 오염부지에 대한 조사 및 복원방법도 많이 개발되어 적용되고 있다. 그러나 유류는 그 종류가 다양하고 지중에 스며들면 그 성분들이 휘발, 흡착, 용해, 생분해 그리고 지하수 유동에 따른 확산 등 다양한 기작에 의해서 거동하게 되므로, 조사와 공법 적용 시에는 이에 대한 충분한 이해가 필요하다. 따라서 부지조사시 조사항목의 선정은 물론이고 오염성분 및 농도조사를 위한 시료 채취과정도 매우 중요하다. 또한 공법 선정과 설계 시에는 오염성분의 종류와 농도 외에도, 지층의 구성과 부지의 입지특성 등을 세밀히 파악하고, 관계법령의 숙지, 그리고 복원공사 실시 후 발생할 수 있는 문제의 검토에 이르기까지 체계적인 관찰이 필요하다. 본 고에서는 부지조사방법과 복원공법 선정과정에 대해서 실제 공사 사례를 인용하여 서술하였다.

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국내 석유계총탄화수소 위해성평가 방법 마련을 위한 국외 지침 비교 및 고찰 (Comparison and Consideration on Foreign Guidances for Establishing Risk Assessment Method of Total Petroleum Hydrocarbons in Korea)

  • 윤성미;노회정;김지인;윤정기;임가희;이홍길;조훈제;김인자;황지애;김현구
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제23권6호
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    • pp.54-72
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    • 2018
  • This study reviewed standard operation procedures for fractionation and analytical methods of total petroleum hydrocarbons (TPH) in north america and european countries to aid proper establishment of risk assessment protocols associated with TPH exposure in Korea. In current, the TPH fraction methods established by Massachusetts Department of Environmental Protection (MassDEP) and Total Petroleum Hydrocarbon Criteria Working Group (TPHCWG) are most frequently employed worldwide. Both methods were developed on the basis of direct exposure of TPH from soil, although the method by TPHCWG also took into account the mobility of TPH. Volatile and extractable fractions of petroleum hydrocarbons were analyzed either separately or together. TPH fractionation methods were evaluated based on conservative toxicity values considering the uncertainty of risk assessment in light of current standard protocol for analyzing soil contaminants in Korea, and it was concluded that the method developed by MassDEP is more appropriate.

분배성 추적자 시험법을 이용한 불균질 지반의 유류 오염도 평가 (The Evaluation of Petroleum Contamination in Heterogeneous Media Using Partitioning Tracer Method)

  • 김은협;이성수;박준범
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 세계 도시지반공학 심포지엄
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    • pp.1372-1377
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    • 2009
  • For the remediation of the subsurface contaminated by nonaqueous phase liquids(NAPLs), it is important to characterize the NAPL zone properly. Conventional characterization methods provide data at discrete points. To overcome the weak points of conventional characterization methods, the partitioning tracer method has been developed and studied. The average saturation of NAPL($S_n$), which is the representative and continuous saturation value within contaminated site, can be calculated by comparing the transport of the partitioning tracers to that of the conservative tracer in the partitioning tracer method. In this study, the application of the partitioning tracer method in heterogeneous media was investigated. To represent the heterogeneous condition of subsurface, a two-dimensional soil box was divided into four layers and each layer contained different sized soils. Soils in the soil box were contaminated by the mixture of kerosene and diesel, and partitioning tracer tests were conducted before and after the contamination using methanol as conservative tracer and 4-methyl-2-pentanol, 2-ethyl-1-butanol, and hexanol as partitioning tracers. The response curves of partitioning tracers from contaminated soils were separated and retarded in comparison with those from non-contaminated soils. The contamination of soils by NAPLs, therefore, can be detected by partitioning tracer method considering these retardations of tracers. From our experiment condition, the average saturation of NAPLs calculated by partitioning tracer method using the methanol as conservative tracer and hexanol as partitioning tracer showed the highest accuracy, though all results were underestimated. Further studies, therefore, were needed for improving the accuracy using the partitioning tracer test in heterogeneous media.

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군기지 오염토양의 정화 방법에 대한 연구 (A Study on Remediation Methods of Contaminated Soils at Former Military Bases)

  • 양혁수;김임순;강선홍;장윤영;박세규;고재욱;김연정;박철환
    • Korean Chemical Engineering Research
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    • 제52권5호
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    • pp.647-651
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    • 2014
  • 대량의 유류 취급과 사격, 폭파훈련으로 인한 피탄지에 중금속 물질의 발생, 많은 인원이 사용 후 발생되는 폐기물, 노후화된 시설물(구조물 포함) 등으로 인해 군부대는 환경오염사고를 야기할 수 있는 가능성을 지니고 있다. 경기도 의정부시에 위치한 5개의 반환미군기지를 대상으로 오염도를 분석하였으며, 그 결과 TPH (Total Petroleum Hydrocarbons), BTEX (Benzene, Toluene, Ethylbenzene, Xylene), 중금속에 의한 토양오염과 지하수 오염을 확인할 수 있었다. 군기지 오염토양의 정화를 위하여 토양증기추출법, 슬러핑공법, 토양경작법 및 토양세척법이 적용되었으며, 적용된 5개의 부지 모두 법적 기준에 적합하도록 정화되었다.