• Title/Summary/Keyword: petrochemical

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A Study on the Real-Time Oil-Spill Monitoring Technology (실시간 기름유출 모니터링 기술에 관한 연구)

  • Yeom, Woo-jung;Hong, Yeon-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.472-477
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    • 2017
  • Oil spills cause a lot of damage to the environment. Oil destroys the water environment and ecosystem in a very short period of time once they are contaminated by it, it takes a lot of time to recover from the contamination and the cleaning process is very difficult. Therefore, oil detectors are greatly needed as they can monitor any oil spills over the sea, rivers, and lakes. There are two kinds of technology available for detecting oil, viz. the contact and non-contact types. The former is based on the use of the conductivity, capacitance and microwaves, while the latter employs infrared, UV, laser, optic and radar technologies. As there are also various hurdles in the measuring of oil on water, such as the presence of waves, refraction of light, temperature and saltiness, it is imperative to select the right oil detector which is appropriate for the specific environment. In this study, a contact type oil detector is developed, which can be used in oil related industries, such as refineries, petrochemical companies, and power generation stations. The detector is made up of the sensor module, which floats on the water, and the controller which processes the signal coming from the sensor module and displays it. It is designed in such a way that the existence of oil is detected through the sensor and the change in the permittivity is observed to determine the volume and type of spilled oil.

Visible Light Communication Based Wide Range Indoor Fine Particulate Matter Monitoring System (가시광통신 기반 광역 실내 초미세먼지 모니터링 시스템)

  • Shakil, Sejan Mohammad Abrar;An, Jinyoung;Han, Daehyun;Chung, Wan-Young
    • Journal of the Institute of Convergence Signal Processing
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    • v.20 no.1
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    • pp.16-23
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    • 2019
  • Fine particulate matter known as PM 2.5 refers to the atmospheric particulate matter that has a diameter less than 2.5 micrometer identified as dangerous element for human health and its concentration can provide us a clear picture about air dust concentration. Humans stay indoor almost 90% of their life time and also there is no official indoor dust concentration data, so our study is focused on measuring the indoor air quality. Indoor dust data monitoring is very important in hospital environments beside that other places can also be considered for monitoring like classrooms, cements factories, computer server rooms, petrochemical storage etc. In this paper, visible light communication system is proposed by Manchester encoding technique for electromagnetic interference (EMI)-free indoor dust monitoring. Important indoor environment information like dust concentration is transferred by visible light channel in wide range. An average voltage-tracking technique is utilized for robust light detection to eliminate ambient light and low-frequency noise. The incoming light is recognized by a photo diode and are simultaneously processed by a receiver micro-controller. We can monitor indoor air quality in real-time and can take necessary action according to the result.

Development Strategy of Seosan-Daesan Port using AHP Analysis (AHP를 이용한 서산 대산항의 발전전략에 관한 연구)

  • Yun, Kyong-Jun;Ahn, Seung-Bum;Lee, Hyang-sook
    • Journal of Korea Port Economic Association
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    • v.34 no.4
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    • pp.39-52
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    • 2018
  • The Seosan-Daesan Port is a representative trade port in Chungnam, and has the sixth largest total cargo throughput and the third largest oil cargo throughput in Korea. However, research on this port's development is lacking relative to that for Busan Port, Incheon Port, and Gwangyang Port, and no study exists that suggests the direction of the development strategy for Seosan-Daesan Port. This study discusses the future role of Seosan-Daesan Port in preparation for a rapidly changing future and the development strategy that should be established. Using the AHP, a development strategy is provided for Seosan-Daesan Port from short/mid-term and long-term viewpoints for three aspects: operation activation, infrastructure construction, and policy support. Operation activation is chosen as the most significant factor from a short/mid-term viewpoint, whereas infrastructure construction is recognized as important from a long-term viewpoint. Specifically, from a short/mid-term viewpoint, sustainable container cargo attraction, multipurpose dock construction, management pier construction, and opening of international passenger ferry lines are important factors while from the long-term viewpoint, hinterland construction, petrochemical industry cluster construction, automobile industry cluster construction, and management improvement system are important. Establishing action plans for each strategy and a cooperative network for sharing goals and strengthening cooperation is necessary.

Petrology of the Cretaceous igneous rocks in Gadeog Island, Busan, Korea (부산 가덕도 지역 백악기 화성암류에 대한 암석학적 연구)

  • 고정선;김은희;윤성효
    • The Journal of the Petrological Society of Korea
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    • v.13 no.2
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    • pp.47-63
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    • 2004
  • This study focuses on the petrography and petrochemical characteristics of the volcanic and plutonic rocks in Gadeog island, Busan, Korea. Based on textural and mineralogical characteristics, intermediate volcanic rocks can be divided into andesitic lava flows (porphyritic and massive andesites) and andesitic pyroclastics. Felsic volcanic rocks are composed of rhyolite, rhyolitic welded tuff, and tuff breccia. Plutonic rocks are intruded rhyolite and andesitic rocks, and composed of hornblende granodiorite which contains lots of mafic magma enclaves. Volcanic rocks are composed of andesite, dacite and rhyolite having a range in SiO$_2$ from 59 to 78wt.%. The volcanic rocks belong to the calc-alkaline rock series. Plutonic rocks have a range in SiO$_2$ from 63 to 69wt.%. This compositional variations correspond to those of Cretaceous volcanic and plutonic rocks in the southeastern Gyeongsang basin. The trace element composition and rare earth element patterns of the volcanics, which are characterized by high LREE/HFSE ratios and enrichment in LREE, suggest that they are typical of calc-alkaline volcanic rocks produced in the subduction environment around continental arc. We concluded that volcanic and plutonic rocks in Gadeog Island were evolved from orogenic andesitic magma which was produced by partial melting of the mantle wedge in the subduction environment.

Residual Life Assessment of mod HP Reformer Tubes Using Surface Replication Methods (표면복제를 사용한 mod HP강 개질로 튜브의 잔여수명 평가에 대한 연구)

  • Ryu, Hyung Ki;Le, Thi Giang;Bang, Hyo Jung;Yoon, Kee Bong
    • Journal of the Korean Institute of Gas
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    • v.25 no.5
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    • pp.30-36
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    • 2021
  • Residual life assessment of reformer tubes of mod HP steel used in the refinery and petrochemical industry were investigated by quantitative metallographic evaluation method. Area fractions of precipitated carbides were measured by using surface replication and its relationship with the remaining life of the tube was investigated. The microstructures of the virgin and other tubes were examined using optical microscopy (OM) for service periods of 1.8, 6.0, 7.2, 8.5, 9.7, and 16.2 years at 950 ℃ and the area fractions of the precipitates were measured by image analysis using ImageJ software. As the area fraction of the precipitates increased, the residual life was decreased accordingly. The results showed that the LMP was the highest in the virgin and the LMP decreased as the service time increased and the residual life decreased. A regressional equation showing the relation between the area fraction of carbides and LMP was experimentally derived. The obtained relationship can be used with the surface replication method for on-site residual life assessment.

A Study on the Improvement for Port Placement of Response Vessel (방제선 배치 항만의 개선 방안)

  • Jang, Duck-Jong;Kim, Dae-Jin;Kim, Woo-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.7
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    • pp.810-819
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    • 2017
  • The purpose of this study is to evaluate port use and the distribution of risk factors in 15 major ports in Korea, delineating the risk of each port after classifying the ports into four risk groups based on estimated risks. The placement of response vessels is then analyzed accordingly. Based on the results, danger was estimated to be especially high in ports where large-scale petrochemical facilities are located, such as Yeosu Gwangyang ports (1.85), Ulsan port (1.33) and Daesan port (1.25). The ports showing the next highest degree of danger were Pusan (0.95) and Incheon (0.83), which have significant vessel traffic, followed by Mokpo (0.71) and Jeju (0.49), which expanded their port facilities recently and saw an increase in large vessel traffic. Next is Masan (0.44), for which many fishing permits in the vicinity. When the relative ratios of each port were graded based on the Yeosu Gwangyang Ports, which showed the highest risk values, and risk groups were classified into four levels, the highest risk groups were Yeosu Gwangyang, Ulsan, Daesan and Pusan, with Incheon, Mokpo, Jeju, and Masan following. Pyeongtaek Dangjin, Pohang, Gunsan, and Donghae Mukho were in the mid-range danger group, and the low risk groups were Samcheonpo, Okgye, and Changsungpo. Among these, all response vessel placement ports specified by current law were above the mid-range risk groups. However, we can see that ports newly included in mid-range risk group, such as Mokpo, Jeju, and Donghae Mukho, were excluded from the pollution response vessel placement system. Therefore, to prepare for marine pollution accidents these three ports should be designated as additional response vessel placement ports.

A Study on the Measurement of Explosion Range by CO2 Addition for the Process Safety Operation of Propylene (프로필렌의 공정안전 운전을 위한 CO2 첨가량에 따른 폭발범위 측정에 관한 연구)

  • Choi, Yu-Jung;Heo, Jong-Man;Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.599-606
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    • 2019
  • Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

Study on Improvements to Domestic Marine HNS Training Curricula through a Case Analysis of Marine Chemical Incidents (해상화학사고 사례 분석을 통한 국내 해상HNS 교육과정 개선에 관한 연구)

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.1
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    • pp.97-112
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    • 2021
  • This study introduces lessons learned from investigation and analysis of major domestic and overseas cases of marine chemical incidents involving hazardous and noxious substances (HNS) during maritime transportation by chemical tankers carrying petrochemical products in bulk. The study then suggests plans to improve domestic marine HNS training curricula based on these lessons. Lessons learned from six incident cases are classified into the following six categories: 1) incident-related information, 2) safety, 3) pollution, 4) response, 5) salvage and 6) others. Based on these six categories, it is suggested that the curriculum provided by the Marine Environment Research & Training Institute for marine pollution prevention managers aboard noxious liquid substance carriers should be changed from the existing two-day training of eight subjects (16 h) to a three-day training of sixteen subjects (24 h). In addition, it is proposed that the marine chemical incident response course of the Korea Coast Guard Academy should be changed from the existing five-day training of fifteen subjects (35 h) to a six-day training of thirty-two subjects (48 h). These results are expected to contribute to sharing experiences and lessons learned about response to marine chemical incidents and to be used as basic data for improving the education and training courses for response personnel in preparedness for marine HNS incidents.

Review on Free-Standing Polymer and Mixed-Matrix Membranes for H2/CO2 Separation (수소/이산화탄소 분리를 위한 프리스탠딩 고분자 및 혼합매질 분리막에 대한 총설)

  • Kang, Miso;Lee, So Youn;Kang, Du Ru;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.4
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    • pp.218-226
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    • 2022
  • Hydrogen, a carrier of large-capacity chemical and clean energy, is an important industrial gas widely used in the petrochemical industry and fuel cells. In particular, hydrogen is mainly produced from fossil fuels through steam reforming and gasification, and carbon dioxide is generated as a by-product. Therefore, in order to obtain high-purity hydrogen, carbon dioxide should be removed. This review focused on free-standing polymeric membranes and mixed-matrix membranes (MMMs) that separate hydrogen from carbon dioxide reported in units of Barrer [1 Barrer = 10-10 cm3 (STP) × cm / (cm2 × s × cmHg)]. By analyzing various recently reported papers, the structure, morphology, interaction, and preparation method of the membranes are discussed, and the structure-property relationship is understood to help find better membrane materials in the future. Robeson's upper bound limits for hydrogen/carbon dioxide separation were presented through reviewing the performance and characteristics of various separation membranes, and various MMMs that improve separation properties using technologies such as crosslinking, blending and heat treatment were discussed.

A Study on the Comparison of Areas Near Gunsan according to the Revision of the National Air Pollutant Emissions (CAPSS) in 2020 (국가대기오염물질 배출량(CAPSS)의 2020년 산정 방법 개정에 따른 군산 인근지역 비교에 관한 연구)

  • Sang-Hun Park;Seong-Cheon Kim
    • Journal of Environmental Health Sciences
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    • v.49 no.4
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    • pp.190-200
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    • 2023
  • Background: Gunsan has been constantly affected by pollutants generated by the Saemangeum development and the construction industry since the completion of the Saemangeum seawall on April 27, 2010. However, there are limitations to its study, such as taking into consideration weather conditions, geographical factors, and foreign inflows. Objectives: In this study, we compared the Existing-CAPSS emissions of Gunsan with Recalculated-CAPSS emissions data to analyze the differences in emissions characteristics by year (2016~2019). Methods: Using Existing data on CAPSS emissions (2016~2019) and Recalculated-CAPSS emissions (2016~2019) for Gunsan, which were Recalculated following the improvement of emissions calculations for 2020, we organized CO, NOX, SOX, PM10, VOCS, and NH3 emissions by substance and investigated the differences and characteristics of the Recalculated emissions by year. Results: For Re-CO and Re-PM10, the emission characteristics of CO were examined as energy industry combustion and PM10 emission characteristics were examined as ship cargo from non-road transportation sources, as ship leisure sources were excluded from non-road transportation source emissions. Conclusions: Comparing the emissions of Existing-CAPSS and Recalculated-CAPSS in Gunsan, the emissions of Recalculated-CAPSS by substance decreased by 39.76% for CO, 9.98% for PM10, 5.53% for VOCS, and 9.24% for NH3, while Re-NOX increased by 2.86% and Re-SOX increased by 1.97%. On the other hand, when comparing the emissions characteristics of Existing-CAPSS and Recalculated-CAPSS in Gunsan, Jeonju, and Iksan, the emission characteristics of Re-NOX, Re-SOX, Re-VOCS and Re-NH3 were similar to those of Ex-NOX, Ex-SOX, Ex-VOCS, and Ex-NH3. As such, Gunsan, Iksan, and Jeonju, showed differences in the comparison of different emission characteristics due to the geographical characteristics of the region (population, area, topography, weather factors) and the characteristics of the industrial complex (metal, petrochemical).