• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1011-1017
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• 1998

$YBa_2Cu_3O_{6+x}(Y123)-Ag$ high-Tc superconducting wires were fabricated by plastic extrusion technique using pyrophoric synthetic and mechanical mixing powder with and without Ag addition(20 wt.%). This method involves powder preparation, plastic paste making, die extrusion, binder burn-out and the sintering process. In order to fabricate a good-quality superconducting body, it is required to use homogeneous and fine-size power as a starting materials. $Y_2O_3-BaCO_3-CuO$ precursor powders with/without Ag addition were prepared both by pyrophoric synthetic(PS) and mechanical mixing(MM) method of raw powders. The formation kinetics of the powder mixtures into Y123 phase was investigated at various temperatures and times in air atmosphere. The powder prepared by PS method was more easily converted into a Y123 phase than the MM powder. The fine size and good chemical homogeneity of the powder prepared by PS method is attributable to the fast formation into a Y123 phase. The critical current density($J_c$) of the Y123-Ag superconducting wires made by plastic extrusion method were in the range of $150A/cm^2{\sim}230A/cm^2$. depending on the charateristics of starting material powders. $J_c$ of the wire prepared by pyrophoric synthetic powder with 20 wt.% Ag addition was $230A/cm^2$.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.438-449
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• 2020

This study is to improve the method of calculating the risk of liability that arise from release and dispersion of chemicals outside the plant in process industries such as chemical and petrochemical plants. To achieve this goal, the correlation factors with the risk of chemical release accident is derived by simulating release and dispersion of substances (14 types) designated by Ministry of Environment as preparation for accident, analyzing the cases of chemical release and effects of plant life damage. The method of calculating chemical liability risk was modified and supplemented based on the results obtained from the study. The correlation coefficient between the probit value of 14 chemical types and the liability risk by EURAM (European Union Risk Ranking Method) was -0.526, while the correlation coefficient with the modified chemical release accident risk was 0.319. Thus, the value from modified method shows that they appear to be correlated. According to modified calculating methodology, the correlation between ERPG-2 value and liability risk of 97 chemical types was -0.494 which is 19 times higher than existing liability risk correlation as absolute value. And the correlation coefficient of corrosion risk was 0.91. The standardized regression coefficients (β) value of correlation factors that affected the increase and decrease of risk were derived in order of Corrosion Index(0.713), ERPG-2 (0.400) and NFPA Health Index (0.0680) by values. It is expected that these findings this study result will also enable the calculation of reasonable chemical release liability risk for existing and new chemical, and will help use them as quantitative liability risk management indicators for chemical plant site.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.356-361
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• 2020

Propylene is widely used in petrochemical manufacturing at over 200 ℃. However, since propylene is a flammable gas with fire and explosion risks, inert nitrogen is injected to prevent them. In this study, experiments were conducted using propylene-nitrogen-oxygen upon pressure changes at 200 ℃. At 21% oxygen, as pressure increased from 0.10 MPa to 0.25 MPa, lower explosion limit (LEL) decreased from 2.2% to 1.9% while upper explosion limit (UEL) increased from 14.8% to 17.6%. In addition, minimum oxygen concentration (MOC) decreased from 10.3% to 10.0%, indicating higher risks with the expanded explosive range as pressure increased. With increase of pressure from 0.10 MPa to 0.25 MPa, explosion pressure increased from 1.84 MPa to 6.04 MPa, and the rate of rise of maximum explosion pressure increased drastically from 90 MPa/s to 298 MPa/s. It is hoped that these results can be used as basic data to prevent accidents in factories using propylene.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.565-572
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• 2020

This study developed a software platform using machine learning of artificial intelligence to optimize the distillation column system. The distillation column is representative and core process in the petrochemical industry. Process stabilization is difficult due to various operating conditions and continuous process characteristics, and differences in process efficiency occur depending on operator skill. The process control based on the theoretical simulation was used to overcome this problem, but it has a limitation which it can't apply to complex processes and real-time systems. This study aims to develop an empirical simulation model based on machine learning and to suggest an optimal process operation method. The development of empirical simulations involves collecting big data from the actual process, feature extraction through data mining, and representative algorithm for the chemical process. Finally, the platform for the distillation column was developed with verification through a developed model and field tests. Through the developed platform, it is possible to predict the operating parameters and provided optimal operating conditions to achieve efficient process control. This study is the basic study applying the artificial intelligence machine learning technique for the chemical process. After application on a wide variety of processes and it can be utilized to the cornerstone of the smart factory of the industry 4.0.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.12
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• pp.446-452
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• 2016

Recently, heat resistant super alloys (which are wear-resistant, corrosion-resistant, and heat-resistant), have been used as the basic structural material in offshore and petrochemical plants. On the other hand, making valves from very expensive, high heat-resistant alloys increases the production cost and decreases its market competitiveness. To solve these problems, the technique of overlaying only those that flow on the fluid has been used as an effective method. Nevertheless, because the former technique of overlaying the ball is performed manually, it takes too much time and perfect welding is difficult to perform. To solve this problem, this study developed a robot automation system that can make uniformly overlay welding of the ball for ball-valves. The system consists of a 6-axis welding robot with a welding torch and additional 2 axes for the rotation of positioner, the controller, and a robot path OLP (Off-Line Programming). The CAD drawing data was entered in the Off-line program to obtain the robot teaching point and drive source. Overlay welding paths were implemented using Matlab. Through an automated overlaying system that implemented the OLP, the productivity rose 2.58 times, as the amount of time required for work decreased from 88 hours to 41 hours.

• Membrane Journal
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• v.25 no.4
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• pp.343-351
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• 2015

In this study, we synthesis polyimide with high gas selectivity using 2,2-bis(3,4-carboxylphenyl) hexafluoropropane, 2,4,6-Trimethyl-1,3-phenylenediamine (DAM) and 4,4-Methylenedianiline (p-MDA), and then the asymmetric membrane was fabricated by non-solvent phase separation method. To confirm the property change of the membrane using different solvent, we measured and compared the viscosity of the polymer solution, cloud point and non-solvent phase separation coefficient. The morphology and gas separation property of membrane prepared by phase separation method was confirmed using Field Emission Scanning Electron Microsope and the single gas permeation measurement apparatus. The single gas ($CH_4$, $N_2$, $O_2$, $CO_2$) permeation property and selectivity value of the membrane prepared with NMP was higher than the membrane prepared with DMAc. We confirmed that the gas selectivity of the membrane increased and the permeation property decreased with increasing of the solvent evaporation time.

• Journal of the Korean Geotechnical Society
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• v.32 no.2
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• pp.53-62
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• 2016

Among several factors controlling soil compaction, temperature is the factor that varies with region and season. Although earthwork is performed in many projects in the cold regions of the earth, studies on quantifying soil compaction associated with temperature are limited. This experimental study investigates the temperature effect on the soil compaction of cohesionless soil. Jumunjin sand was selected for the tests to represent cohesionless clean sand, which is widely used as an engineering fill at petrochemical projects such as northern Alberta of Canada and Russia. The laboratory test program consists of performing a series of standard proctor tests varying temperature of soil samples ranging from $-10^{\circ}C$ to $17^{\circ}C$. Test results indicate that soil specimen volume expansion occurred from bulking and its range was 0% to 6% with zero above temperature. For increasing temperature from $0^{\circ}C$ to $17^{\circ}C$, water content corresponding to maximum volume (minimum dry unit weight) was decreased and water content corresponding to minimum volume (maximum dry unit weight observed after reaching minimum dry unit weight) was slightly increased with increasing temperature. In zero below temperature, dry unit weight gradually decreased with increasing water content. In this case, no bulking effect was found and soil specimen volume increased due to the higher unit volume of ice.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.402-407
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• 2008

Recent popularity in mobile electronics requires higher standard on the mechanical strength of electronic packaging. Thus, the method of soldering between chip and substrate in electronic packaging process is changing from conventional method using intermetallic compound to a new method using organic solderability preservative (OSP) in order to improve the stability and the reliability of final product. Since current organic solder preservatives have several serious problems like thermo-stability during packaging process, however, it is necessary to develop new OSPs having thermo-stability. The main purpose of this study is to investigate the effect of MeOH/IPA (Isopropyl alcohol) ratio on the fluxing of a new OSP, developed in previous research, andto find out an optimum formulation of flux components for the application of the OSP in current packaging process. As a result of this study, it was revealed that higher MeOH/IPA ratio in flux showed better performance of fluxing a new OSP.

• Journal of the Korean earth science society
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• v.26 no.1
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• pp.78-92
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• 2005

Petrographical and petrochemical analyses for late Miocene basalts in Goseong-gun area. Gangwon province, were carried out to interpret the characteristics and the origin of magma. The basaltic rocks occurred as plug-dome in the summit of several small mountain and developed columnar jointing with pyroxene-megacryst bearing porphyritic texture. And the basalt contains xenoliths of biotite granite (basement rocks), gabbro (lower crustal origin) and Iherzolite(upper mantle origin). The basalts belong to the alkaline basalt field in TAS diagram and partly belong to picrobasalt and trachybasalt field. On the tectonomagmatic discrimination diagram f3r basalt in the Goseong-gun area. they fall into the fields for the within plate and oceanic island basalt. The characteristics of trace elements and REEs shows that primary magma for the basalt magma would have been derived from partial melting of garnet-peridotite mantle. This late Miocene basalt volcanism is related to the hot spot within the palte.

• Journal of the Korean earth science society
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• v.18 no.6
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• pp.480-492
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• 1997

In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.