• 한국농공학회논문집
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• 제54권2호
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• pp.157-166
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• 2012

Most of the roads are paved with impermeable materials such as asphalt concrete and cement concrete, and in the event of heavy rainfall, rainwater directly flows into river through a drainage hole on the pavement surface. This large quantity of rainwater directly spilled into the river frequently leads to the flooding of urban streams, damaging lowlands and the lower reaches of a river. In recent years there has been a great deal of ongoing research concerning water permeability and drainage in pavements. Accordingly, in this research, a porous polymer concrete was developed for permeable pavement by using unsaturated polyester resin as a binder, recycled aggregate as coarse aggregate, fly ash and blast furnace slag as filler, and its physical and mechanical properties were investigated. Also, 3 types of permeable polymer block by optimum mix design were developed and rainfall runoff reduction effects by permeability pavement using permeable polymer block were analyzed based on hydraulic experimental model. The infiltration volume, infiltration ratio, runoff initial time and runoff volume in permeability pavement with permeable polymer block of $300{\times}300{\times}80$ mm were evaluated for 50, 100 and 200mm/hr rainfall intensity.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.29-30
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• 2018

Recent impervious pavements on roads and sidewalks cause rainwater to not penetrate into the ground, deplete groundwater, or flood the rivers, causing urban flood damage. In order to solve these problems, the amount of installed pitcher block is increasing, but the existing pitcher block is made with cement base and causes many problems. In the cement permeable block, the efflorescene phenomenon occurs due to the acid component, and the pore of the permeable block is clogged and the permeability is lost. As a result, the service life of the pitcher block is shortened and the replacement period is shortened. The purpose of this study is to analyze the basic properties of polymer concrete by replacing cement with polymer in order to solve the problem of cement - based concrete permeable block.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.356-361
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• 1998

Permeable polymer cement concrete in this study is one of the invironment conscious concretes that can be applied at roads, side walks, parking lots, interlocking block and river embankment, etc. In this study, permeable polymer cement concretes using polymer dispersion(St/Ac) with water-cement ratios of 25, 30, 35 and 40%, polymer-cement ratios of 0, 5, 10, 15 and 20%, and a ratio of cement to aggregate (by weight), 1 : 3.5(about 415kg/㎥), 1 : 4.0(about 375 kg/㎥), and 1 : 4.5(about 345kg/㎥) are prepared, and tested for compressive, flexural and tensile strength, and permeability. From the test results, increase in the strengths of permeable polymer cement concrete are clearly observed with increasing polymer-cement ratio, we can obtain the maximum strengths at water-cement ratio of 35%. The optimum permeable polymer cement concrete according to application and location of work can be selected in various mix proportions.

• 한국건축시공학회지
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• 제18권5호
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• pp.447-453
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• 2018

인공투수관을 혼입한 폴리머 투수블록은 폴리머를 치환할 경우 강도, 공극률, 투수계수 등의 'KS F 4419'(보차도용 콘크리트 인터록킹 블록)의 기준보다 높은 결과 값이 측정되었으며, 제품의 경량화가 가능할 것으로 판단된다. 폴리머 재료의 단가 문제로 인해 경제성을 고려하여 시멘트와의 치환율을 14%로 선정하는 것이 효과적이라고 판단된다. 또한, 인공투수관의 혼입율의 3가지 수준 중 2.0%가 가장 적당하다고 판단되며, 3가지 수준에 대한 측정 값이 큰 차이를 보이지 않는 것으로 나타났다. 공극률과 투수계수의 경우 2%에서 개선된 값이 측정되었기 때문에 인공투수관 혼입율 2%의가 효과적일 것으로 판단된다. 투수블록 제품화를 하기 위해선 경제성을 고려해야 하며, 본 연구에서 사용된 폴리머 VAE 경제성이 떨어지기 때문에 다른 폴리머의 재료와 비교 실험을 진행하여 문제점을 개선 한다면 투수블록 제품화가 가능할 것이라 판단된다. 본 연구의 결과는 추후 폴리머 및 인공투수관을 활용한 연구의 기초적인 자료로 사용 가능 할 경우 효율적인 데이터로 활용이 가능할 것으로 판단된다.

• Macromolecular Research
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• 제10권2호
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• pp.67-74
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• 2002

New immunoprotecting membranes were prepared by spin coating the amphiphilic random multiblock copolymers of poly(ethylene glycol) (PEG) and poly(tetramethylene ether glycol) (PTMEG) or poly(dimethyl siloxane) (PDMS) on porous Durapore(R) membrane. The copolymer coating was intended to make a biocompatible, immunoprotecting diffusional barrier and the supporting porous substrate was for mechanical stability and processability. By filling Durapore(R) membrane pores with water, the penetration of coating solution into the pores was minimized during the spin coating process. A single coating process produced a completely covered thin surface layer (~1 ${\mu}{\textrm}{m}$ in thickness) on the porous substrate membrane. The permselectivity of the coated layer was influenced by PEG block length, polymer composition, and thickness of the coating layer. A composite membrane with the coating layer prepared with PEG 2 K/PTMEG 2 K block copolymer showed that its molecular weight cut-of fat any 40 based on dextran was close to the molecular size of IgG (Mw = 150 kDa). However, IgG permeation was detected from protein permeation test, while glucose oxidase (Mw = 186 kDa) was not permeable through the coated membrane.

• 한국막학회:학술대회논문집
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• 한국막학회 1997년도 추계 총회 및 학술발표회
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• pp.69-70
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• 1997

Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.