• 마이크로전자및패키징학회지
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• 제26권4호
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• pp.15-22
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• 2019

Metallic nanowires (MNWs) have recently been considered as one of the most promising candidates for flexible electrodes of advanced electronics including wearable devices, electronic skins, and soft robotics, since they have high aspect ratio in physical shape, low percolation threshold, high ductility and optical transparency. Herein, we review the latest findings related to the MNWs and discuss the properties and potentials of this material that can be used in implementation of various advanced electronic devices.

• 폴리머
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• 제37권4호
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• pp.526-532
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• 2013

라텍스 기법으로 제조한 폴리스티렌(PS)/탄소나노튜브(CNT) 나노복합재료의 CNT 분산 방법에 따른 유변물성과 전기 전도도를 비교하였다. PS/CNT 나노복합재료는 PS 입자와 CNT를 분산시킨 후 동결건조하여 제조하였다. 본 연구에서는 화학적 개질시 나타나는 CNT의 고유 물성 저하를 방지하기 위하여 sodium dodecylsulfate(SDS)를 첨가하는 방법과 polyvinyl pyrrolidone(PVP)으로 CNT를 감싸는 방법의 물리적 분산법을 적용하였다. 라텍스 기법에 적용한 물리적 분산 방법은 CNT의 분산에 매우 효과적이었다. SDS를 첨가한 경우는 PVP로 감싼 CNT를 사용하여 제조한 경우에 비해 나노복합재료의 유변물성의 증가폭이 낮은데 이는 저분자량인 SDS를 첨가로 인해 매트릭스의 물성이 감소하기 때문이다. CNT를 SDS로 분산시킨 나노복합재료와 PVP로 감싼 CNT를 사용한 나노복합재료의 전기적 임계점은 각각 0.23과 0.90 wt%로 나타났다. PVP로 CNT를 감싼 경우가 전기 전도도 향상 효과가 낮은데 이는 감싸고 있는 절연성의 PVP가 CNT간의 전기적 연결을 억제하기 때문이다.

• 한국구조물진단유지관리공학회 논문집
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• 제26권3호
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• pp.72-83
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• 2022

본 논문에서는 전도성 재료인 탄소섬유(carbon fiber, CF)와 강섬유(steel fiber, SF)를 함유한 시멘트 모르타르의 미세구조 및 전기적 특성, 압축강도에 미치는 영향을 연구하였다. 전도성 섬유보강 시멘트 모르타르(fiber-reinforced cement mortar, FRCM)의 비저항은 4-probe 방법을 이용하여 측정하였고, 압축강도는 압축시험을 기반으로 측정하였다. 이들의 성능은 플레인 모르타르(plain mortar, PM)와 비교, 검토하였다. 게다가 전도성 FRCM 파단면의 표면형상과 구성성분은 주사전자현미경(scanning electron microscope, SEM)과 에너지 분산형 X-ray 분광분석기(energy disperse X-ray spectrometer, EDS)를 이용하여 분석하였다. 그 결과 모든 시편에서 양생재령이 경과됨에 따라 비저항이 점차 증가하는 반면, 섬유혼입률이 증가할수록 비저항은 상당히 감소하였다. 강섬유를 1.25%까지 추가하여도 시멘트 모르타르의 비저항에는 크게 영향을 미치지 않았다. 대조적으로, 탄소섬유는 낮은 함량(즉, 0.1~0.3%)에서도 비저항이 다소 감소하였고, 그 이후에는 현저히 저하되었다. 본 실험에 사용된 CF가 함유된 전도성 CFRCM의 침투 임계점은 0.4%이었고, 압축강도 성능을 유지하면서 전도성 효과를 극대화하는 최적의 탄소섬유 혼입량이라고 판단된다. 전도성 FRCM의 표면형상 및 구성성분 분석을 위해 SEM/EDS를 통해 파단면을 관찰하였다. 이러한 결과는 시멘트 모르타르 내에서 보강섬유의 미세구조 메커니즘을 확립하는 데 매우 유용할 것으로 사료된다.

• Fibers and Polymers
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• 제1권1호
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• pp.32-36
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• 2000

An alternative strategy to .educe the percolation threshold of carbon black (CB) in polymer blends was investigated using random copolymer ternary blends of polystyrene (PS), poly(methyl methacrylate)(PMMA), and a styrene-methyl methacrylate random copolymer (SMMA). The target morphology was to selectively locate CB particles in the encapsulating layer of SMMA during melt mixing. The CB used in this study is BP-2000 from Cabot and has a strong selective affinity to PS. Even when the CB was premixed with SMMA, it moves to the PS phase during the melt mixing. However, we also observed the CB particles located at the interface between SMMA and PS phases. Through this study it is found that the interaction between polymers and CB particles is critical for selectively localizing CB particles in multi-component polymer blends. Although appropriate processing condition may retard the movement of CB particles to the polymer phase with affinity, it cannot prevent it completely and locate them to the SMMA phase, which is not thermodynamically favored. To locate CB particles in an encapsulating layer of ternary polymer blends, first of all, polymers forming it should have selective affinity to CB.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.42-45
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• 2003

Nondestructive damage sensing and mechanical properties for acid-treated carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites were investigated using electro-micromechanical technique and acoustic emission (AE). Carbon black (CB) was used to compare to CNT and CNF. The results were compared to the untreated case. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity under double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. For surface treatment case, the damage sensitivity and reinforcing effect were higher than those of the untreated case. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

• 공업화학
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• 제10권2호
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• pp.287-292
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• 1999

Polycarbonate (PC)를 matrix로 사용하여 전도성 고분자인 polyaniline (PANI)과의 복합체를 블렌딩 방법에 의하여 제조하였다. 용매로는 chloroform을 사용하였으며 PANI는 전하수송을 가능하게 하고 유기용매에 잘 용해될 수 있도록 camphorsulfonic acid (CSA) 혹은 dodecylbenzenesulfonic acid (DBSA)와 같은 알킬 벤젠 술폰산으로 양성화시켰다. 또한, 전도성 복합체의 전기전도성은 압축성형이 아닌 solution casting법에 의하여 향상시켰다. 아울러 양성화제 유무, PANI의 함량 또는 온도에 따라 전기전도도, 몰포로지 및 인장강도 등을 측정 분석하였다. PANI 착체의 함량이 많을수록 전기전도도는 증가하였으며 알킬사슬이 긴 DBSA로 양성화된 25 wt % PANI 착체의 전도성 복합체의 전기전도도는 3.18 S/cm까지 향상되었다.

• 공업화학
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• 제10권2호
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• pp.281-286
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• 1999

Nylon6,6를 matrix로 사용하여 전도성 고분자인 polypyrrole (PPy)과의 전도성 복합체를 블렌딩 방법에 의하여 제조하였다. PPy를 화학적으로 중합시키는데 있어서 $FeCl_3$를 산화제로 사용하였으며, dopant로서 camphorsulfonic acid (CSA)와 dodecylbenzenesulfonic acid (DBSA)와 같은 알킬 벤젠 술폰산을 사용하였다. 제조된 전도성 복합체에 대하여 dopant의 종류에 따라 또는 PPy의 함량에 따라 전기전도도 및 몰포로지 그리고 기계적 물성 등을 측정 분석하였다. PPy 착체의 함량이 증가할수록 전기전도도는 증가하였으며, 알킬사슬의 길이가 긴 DBSA로 도핑된 25 wt % PPy 착체와 nylon6,6 복합체의 전기전도도는 0.64 S/cm까지 향상되었다.

• Carbon letters
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• 제11권4호
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• pp.285-292
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• 2010

Novel unsaturated polyester composites with PAN-based nanofiber, stabilized PAN nanofiber, and carbonized nanofiber webs have been fabricated, respectively, and the effects of the nanofiber web content on their electrical resistivity, the thermal stability, dynamic storage modulus, and fracture surfaces were studied. The result demonstrated that the introduction of just one single layer (which is corresponding to 2 wt.%) of the carbonized nanofiber web to unsaturated polyester resin (UPE) could contribute to reducing markedly the electrical resistivity of the resin reflecting the percolation threshold, to improving the storage modulus, and to increasing the thermal stability above $350^{\circ}C$. The effect on decreasing the resistivity and increasing the modulus was the greatest at the carbonized PAN nanofiber web content of 8 wt.%, particularly showing that the storage modulus was increased about 257~283% in the measuring temperature range of $-25^{\circ}C$ to $50^{\circ}C$. The result also exhibited that the carbonized PAN nanofibers were distributed uniformly and compactly in the unsaturated polyester, connecting the matrix three-dimensionally through the thickness direction of each specimen. It seemed that such the fiber distribution played a role in reducing the electrical resistivity as well as in improving the dynamic storage modulus.

• 한국수소및신에너지학회논문집
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• 제22권6호
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• pp.827-834
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• 2011

Epoxy/graphite/expanded graphite composites have been prepared in various weight ratios and thermal degradation and electrical properties were estimated in order to use for the bipolar plate materials in PEMFC. Thermogravimetric analysis (TGA) showed that the epoxy/graphite system cured by a curing agent GX-533 was most proper because its weight loss until $80^{\circ}C$ at which PEMFC would be operated was 0.3 wt%, and differential scanning calorimetry (DSC) analysis showed its cure temperature would be sufficient at $80^{\circ}C$. The activation energy for the cure reaction was 132.0 kJ/mol and the pre-exponential factor was $1.76{\times}10^{17}min^{-1}$. Electrical conductivity on the surface of the bipolar plate prepared under a pressure of 200 $kgf/cm^2$ was increased from 4 to 25 $S/cm^2$ by increasing expanded graphite (EG) content from 50 phr to 90 phr. The percolation threshold was initiated around 75 phr and the corrosion rate at 80 phr was 1.903 $uA/cm^2$.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.99-106
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• 2013

Polyaniline-yttrium trioxide (PAni-$Y_2O_3$) composites were synthesized by the in-situ polymerization of aniline in the presence of $Y_2O_3$ The composite formation and structural changes in these composites were investigated by X-ray diffraction (XRD), Fourier transform infra red spectroscopy (FTIR), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The direct current (DC) electrical conductivity of the order of $0.51{\times}10^{-2}\;S\;cm^{-1}-0.283\;S\;cm^{-1}$ in the temperature range 300 K-473 K indicates semiconducting behavior of the composites. Room temperature AC conductivity and dielectric response of the composites were studied in the frequency range of 10 Hz to 1 MHz. The variation of AC conductivity with frequency obeyed the power law, which decreased with increasing weight percentage (wt %) of $Y_2O_3$. Studies on dielectric properties shows the relaxation contribution coupled by electrode polarization effect. The dielectric constant and dielectric loss in these composites depend on the content of $Y_2O_3$ with a percolation threshold at 20 wt % of $Y_2O_3$ in PAni. Electromagnetic interference shielding effectiveness (EMI SE) of the composites in the frequency range 100 Hz to 2 GHz was in the practically useful range of -12.2 dB to -17.2 dB. The observed electrical and shielding properties were attributed to the interaction of $Y_2O_3$ particles with the PAni molecular chains.