• 제목/요약/키워드: percolation

검색결과 361건 처리시간 0.024초

MAGNETOREFRACTIVE EFFECT AND CUBIC NONLINEAR MAGNETOOPTICS IN MAGNETIC GRANULAR ALLOYS

  • Granovsky, A.;Inoue, M.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2002년도 동계연구발표회 논문개요집
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    • pp.16-16
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    • 2002
  • Granular metal-insulator alloys, consisting of nano-scale magnetic particles in an insulating matrix are of unique consideration for the technological application and fundamental physics. They display a wide variety of unusual both linear and nonlinear electric-transport, optical and magnetooptical properties, especially for compositions close to the percolation threshold. (omitted)

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전기적 응용을 위한 바나듐옥사이드 나노선/폴리비닐 알코올 복합체 제작 (Fabrication of $V_2O_5$ Nanowire/PVA (Polyvinyl Alcohol) Composites for the Electric Applications)

  • 이재우;이강호;김규태
    • 전기전자학회논문지
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    • 제13권2호
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    • pp.216-219
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    • 2009
  • $V_2O_5$ 나노선/폴리비닐 알코올(PVA) 고분자 복합체를 나일론 제조법을 응용하여 제작하였고 전기적 특성을 연구하였다. PVA가 아세톤, 에탄올, 메탄올 등의 벤젠기와 반응하여 얇은 막을 형성하는 것을 이용하여 나일론 섬유 제작방법과 유사하게 실타래를 감아올려 나노선 섬유가 섞인 폴리머 섬유를 만들었다. 폴리머-나노선 복합체는 내부에서 전도성이 있는 $V_2O_5$나노선 다발이 네트워크를 형성하기 때문에 전자기장을 차폐할 수 있는 고분자 섬유 등에 적용할 수 있다.

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단일 채널 DPF의 PM 포집 모델링 및 모델 파라미터의 민감도 해석 (Rigorous Modeling of Single Channel DPF Filtration and Sensitivity Analysis of Important Model Parameters)

  • 정승채;박종선;윤웅섭
    • 한국자동차공학회논문집
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    • 제14권6호
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    • pp.127-136
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    • 2006
  • Prediction of diesel particulate filtration is typically made by virtue of modeling of particulate matter(PM) collection. The model is closed with filtration parameters reflecting all small scale phenomena associated with PM trapping, and these parameters are to be traced back by inversely analyzing large-scale empirical data-the pressure drop histories. Included are soot cake permeability, soot cake density, soot density in the porous filter wall, and percolation constant. In the present study, a series of single channel DPF experiment is conducted, pressure histories are inversely analyzed, and the essential filtration parameters are deducted by DPF filtration model formulated with non-linear description of soot cake regression. Sensitivity analyses of model parameters are also made. Results showed that filtration transients are significantly altered by the extent of percolation constant, and the soot density in the porous filter wall is controlling the filtration qualities in deep-bed filtration regime. In addition, effect of soot particle size on filtration quality is distinct in a period of soot cake regime.

연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구 (Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells)

  • 신승호;김아름;정혜미;엄석기
    • 한국정밀공학회지
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    • 제31권10호
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    • pp.955-965
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    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

써레질 용수량과 지배요인에 관한 시험연구 (Experimental Study on the Harrow Water Reguirement and the Factors Influenced on It in the Paddy Field)

  • 권영현;윤정목;김철기;한찬택
    • 한국농공학회지
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    • 제31권4호
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    • pp.90-95
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    • 1989
  • The purpose of this study is to seek out the harrow water requirement applicable for the irrigation plan of paddy field and to find out the factors influenced on a variation in the requirement. The plots of experiment were arranged with randomized block design which was compo- sed of three kinds of soil texture (sandy loam, loam and silty loam) and ploughing depth (12cm, 17cm, and 22cm). The results obtained from this experimental study are summarized as follows. 1. Harrow water reguirement is not only changed by soil texture, but influenced by soil water content just before irrigating 2. Magnitude of total harrow water reguirement appli(able for the irrigation plan, when surface water depth and the water content just before irrigating is fixed on the basis of 30 mm and a shrinkage limit respectively, generally becomes to be 177.5mm, 116.3mm and 113. 8mm in the sandy loam, loam amd silty loam block, respectively. 3. The more a percolation of soil layer occurs, the more the harrow water requirement increases, but it is not much influenced by the increase in ploughing depth. 4. The larger a porosity of soil layer is, the more a net harrow requirement increases 5. The factors that influence on a variation in the harrow water requirement are appea- red to be percolation of soil layer, soil water content just before irrigating, porosity of soil layer, ploughing depth and designed surface water depth etc.

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열전도도 및 전기전도도가 향상된 에폭시/보론나이트라이드/은나노입자 복합체의 제조 (Improvement of Thermal and Electrical Conductivity of Epoxy/boron Nitride/silver Nanoparticle Composite)

  • 김승용;임순호
    • Korean Chemical Engineering Research
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    • 제55권3호
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    • pp.426-429
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    • 2017
  • 본 연구에서는 은나노입자 및 보론나이트라이드의 혼합이 열전도도 및 전기전도도에 미치는 효과에 대해 고찰하였다. 에폭시/보론나이트라이드 복합체의 경우 열전도도가 보론나이트라이드의 함량에 비례하여 증가하였으며 에폭시/은나노입자의 경우는 열전도도가 크게 변화 없었으며 전기전도도는 20 vol%에서 퍼콜레이션 현상을 보여주었다. 퍼콜레이션 함량 이하에서 은나노입자를 고정시키고 보론나이트라이드를 첨가하여 조사한 결과 전기전도도 및 열전도도가 크게 향상됨을 알 수 있었다.

Effects of Morphology on the Electrical and Mechanical Properties of the Polycarbonate/Multi-Walled Carbon Nanotube Composites

  • Kum Chong-Ku;Sung Yu-Taek;Han Mi-Sun;Lee Heon-Sang;Lee Sun-Jeong;Joo Jin-Soo;Kim Woo-Nyon
    • Macromolecular Research
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    • 제14권4호
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    • pp.456-460
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    • 2006
  • The electrical, morphological, and mechanical properties of poly carbonate (PC)/multi-walled carbon nan-otube (MWNT) composites were studied by electrical conductivity, electromagnetic interference shielding efficiency (EMI SE), scanning electron microscopy, and tensile strength measurements. In the electrical property analysis of the PC/MWNT composites, the percolation threshold of the PC/MWNT composites was observed between 1.5 and 2.5 wt% MWNT content. From the electrical conductivity and EMI SE studies, the theoretical values of the EMI SE were in good agreement with the experimental values of the EMI SE. From the morphology of the PC/MWNT composites, it was observed that MWNT is dispersed homogenously in the PC matrix. From the electrical conductivity and morphological studies, it was suggested that the percolation threshold of the PC/MWNT composites is related with the morphological results in that MWNT is apparently interconnected to form an electrical pathway. The mechanical properties of the PC/MWNT composites peaked at the MWNT content of 2.5 wt%.

Effect of Carbon Nanotube Pre-treatment on Dispersion and Electrical Properties of Melt Mixed Multi-Walled Carbon Nanotubes / Poly(methyl methacrylate) Composites

  • Park Won Ki;Kim Jung Uyun;Lee Sang-Soo;Kim Junkyung;Lee Geon-Woong;Park Min
    • Macromolecular Research
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    • 제13권3호
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    • pp.206-211
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    • 2005
  • Multi-walled carbon nanotubes (MWNTs) pre-treated by concentrated mixed acid or oxidized at high temperature were melt mixed with poly(methyl methacrylate) (PMMA) using a twin screw extruder. The morphologies and electrical properties of the MWNT/PMMA composites were investigated. The thermally treated MWNTs (t-MWNTs) were well dispersed, whereas the acid treated MWNTs (a-MWNTs) were highly entangled, forming large-sized clusters. The resulting electrical properties of the composites were analyzed in terms of the carbon nanotube (CNT) dispersion. The experimental percolation threshold was estimated to be $3 wt\%$ of t-MWNTs, but no percolation occurred at similar concentrations in the a-MWNT composites, due to the poor dispersion in the matrix.

블렌딩을 이용한 폴리우레탄 그라프트 다중벽 탄소나노튜브/폴리우레탄 복합체의 전기 전도성 및 분산 특성 (Dispersity and Electro-Conductivity of PU Grafted MWCNT/PU Composite via Simple Blending Method)

  • 윤성진;임현구;김주헌
    • 공업화학
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    • 제21권5호
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    • pp.500-504
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    • 2010
  • 다중벽 탄소 나노튜브(Carbon nanotube, MWNTs)의 우수한 전기적 기계적 특성과 폴리우레탄의 우수한 기계적 물성을 이용하여 우수한 전기 전도성 복합체를 제조하기 위하여 말단기가 polyurethane로 기능화 된 탄소 나노튜브(PU-g-MWNTs)를 제조하였다. 말단기에 형성된 폴리우레탄과 고분자 메트릭스 간의 상용성으로 인한 계면 접합력으로 인해 기능화된 CNT 복합체 기능화 되지 않은 CNT에 비해 우수한 분산성을 나타내었다. PU-g-MWNT/PU 복합체의 전기 전도성을 PU-g-MWNT의 농도에 따라 측정하였으며 percolation threshold 이론에 의해 해석하였다. 그 결과 PU-g-MWNT/PU 복합체의 전기전도성은 임계농도 0.78 wt%과 임계지수 0.945를 가짐을 확인하였다.