• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.1954-1961
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• 2022

Lead-based fast reactor (LFR) has become one of the most promising reactors for Generation IV nuclear systems. A developing trend of LFR is high efficiency, along with operation temperatures up to 800 ℃ or even higher. One of key issues in the high-efficiency LFR is corrosion of cladding materials with lead at high temperatures. In this study, corrosion behavior of some refractory metals (Nb, Nb521, and Mo-0.5La) was investigated in static lead at 1000 ℃ for 1000 h. The results showed that Nb and Nb521 exhibited an intense dissolution corrosion with obvious lead penetration after corrosion, and lead penetration extended along the grain boundaries of the specimens. Furthermore, Nb521 showed a better corrosion resistance than that of Nb as a result of the elements of W and Mo included in Nb521. Mo-0.5La showed much better corrosion resistance than that of Nb and Nb521, and no lead penetration could be observed. However, an etched morphology appeared on the surface of Mo-0.5La, indicating the occurrence of corrosion to a certain degree. The results indicate that Mo-0.5La is compatible with lead up to 1000 ℃. While Nb and Nb alloys might be not compatible with lead for high-efficiency LFR at such high temperatures.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.7
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• pp.113-119
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• 2019

Concrete structures built on reclaimed land are combined with chemical erosion such as chlorine and sulfate ions from seawater. Chloride attack deteriorates the performance of the structure by corroding reinforcing bars. In addition, the waste water treatment structure has a problem that the concrete is deteriorated by the sulfate generated inside. Therefore, in this study, the characteristics and chemical resistance of low heat cement concrete used in wastewater treatment structures constructed on reclaimed land were evaluated. As a result of the experiment, the target slump and air content were satisfied under all the mixing conditions. The slump of low heat cement (LHC) concrete was higher than that of ordinary portland cement (OPC) concrete, while the air content of LHC concrete was smaller than that of OPC concrete with the same mix proportion. As a result of compressive strength test, OPC concrete showed higher strength at younger age compared to 28 days. In contrast, LHC concrete exhibited higher strength than OPC concrete at the age of 56 days. As a result of chlorine ion penetration tests, LHC-B concrete showed chlorine ion penetration resistance performance of the "very low" level at the age of 56 days. As a result of chemical resistance evaluation, when the LHC concrete is applied without epoxy treatment, chemical resistance is improved by about 18% compared to OPC concrete. In testing chemical resistance, the epoxy coated concrete exhibited less than 5% strength reduction when compared to sound concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.86-94
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• 2020

When the Superabsorbent Polymer (SAP) is added into concrete, the slump decreases rapidly, deteriorating the workability, the internal curing effect can be obtained through the water absorption and discharge process, and the internal voids of the concrete are increased. In this study, the effects of internal curing and voids were evaluated by evaluating the compressive strength, freeze-thaw resistance, and chloride penetration resistance of SAP-adding concrete that secured workability using a water reducing agent. Also, the internal curing effect of SAP was evaluated by dividing the curing conditions of concrete into water curing and sealed curing. From the result, as the SAP adding ratio increased, the amount of water reducing agent increased, and as for the compressive strength, the SAP adding ratio of 1.5% showed the greatest compressive strength. In particular, in the case of sealed curing showed higher compressive strength than the water curing. It is considered that the compressive strength increased due to the reduction of the effective water-cement ratio and the internal curing effect. Adding 1.0~1.5% of SAP improved the freeze-thaw resistance similar to the case of adding the AE agent, and the addition of more than 1.0% of SAP improved the chloride penetration resistance. The optimal adding ratio of SAP is 1.5%, and the adding ratio of 2.0% or more adversely affects the compressive strength and freeze-thaw resistance.

• Korean Journal of Materials Research
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• v.22 no.12
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• pp.643-649
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• 2012

Coatings composited with alumina and Perfluoro alkoxyalkane (PFA) resin were deposited on stainless steel plate (SUS304) to further improve corrosion resistance. Plate (ca. $10{\mu}m$) and/or nanosize (27~43 nm) alumina used as inorganic additives were mixed in PFA resin to make alumina-fluoro composite coatings. These coatings were deposited on SUS304 plate with wet spray coating and then the film was cured thermally. According to the amount and ratio of the two kinds of alumina having plate morphology and nano size, corrosion resistance of the film was evaluated under strong acids (HF, HCl) and a strong base (NaOH). The film prepared with the addition of 5~10 wt% alumina powders in PFA resin showed corrosion resistance superior to that of pure PFA resin film. However, for the film prepared with alumina content above 10 wt%, the corrosion resistance did not improve with the physical properties, such as surface hardness and adhesion. The film prepared with plate/nanosize (weight ratio = 1/2) alumina especially enhanced the surface hardness and corrosion resistance. This can be explained as showing that the plate and the nanosize alumina dispersed in PFA resin effectively suppressed the penetration of cations and anions due to the long penetration length and fewer defects that accompany the improved surface hardness under a serious environment of 10% HF solution for over 120 hrs.

• Journal of information and communication convergence engineering
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• v.5 no.2
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• pp.109-111
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• 2007

In this paper, MOS devices with ultrathin gate dielectrics (5.5 nm) are characterized and compared with those with conventional oxides particularly for nanoscale CMOS applications. Nitrogen concentrations and profiles in the nitride gate dielectrics were obtained that will play an important role in improving both hot-carrier lifetime and resistance to boron penetration. This approach seems very useful for future nanoscale CMOS device applications.

• Journal of The Korean Society of Agricultural Engineers
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• v.51 no.6
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• pp.77-81
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• 2009

This study was performed to evaluate applicability of patching materials for underwater dam concrete structure. Two kinds of patching materials was investigated. Laboratory experimentals were conducted by workability, compressive strength, bond strength, chloride ion penetration, abrasion resistance. Test results showed that the most performances are relatively good except chloride ion penetration.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.1
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• pp.79-85
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• 2006

CFRP(Carbon Fiber Reinforced Plastics) of the advanced composite materials as structural materials for vehicle, has a wide application in light-weigh structural materials of airplanes, ships and automobiles because of high strength and stiffness, However, there is a design variable to be considered in practical application of the laminate composite materials, these materials are vulnerable to transverse impact. This paper is to study the effects of stacking sequence and curvature on the penetration characteristics of composite laminate shell. They are stacked to $[0_3/90_3]S,\;[90_3/0_3]s\;and\;[0_2/90_3/0]s,\;[90_2/0_3/90]s$ and their interlaminar number two and four. They are manufactured to various curvature radius (R=100, 150, 200mm and $\infty$), When the specimen is subjected to transverse impact by a steel ball, the velocity of the steel ball was measured both before and after impact by determing the time for it to pass two ballistics-screen sensors located a known distance apart. The critical penetration energy of specimen A and B with less interfaces were a little higher than those of C and D. As the curvature increases, the critical penetration energy increases linearly because the resistance to the in-plane deformation as well as bending deformation increases, which need higher critical penetration energy. The specimen A and C have higher critical penetration energy than B and D because of different stacking sequences. We examined crack length through a penetration test. For the specimen A with 2interfaces, the longest circumferential direction crack length were observed on the first interface from the impact point. For the specimen B 4-interface, the longest circumferential direction crack length were observed on the second interface from the impact point.

• Geomechanics and Engineering
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• v.34 no.2
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• pp.209-220
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• 2023

In this study, a series of three-dimensional numerical analyses were carried out to investigate the penetration performance of a dynamically installed Hall anchor. The advanced coupled Eulerian-Lagrangian (CEL) technique was adopted to accurately simulate the large soil deformation during the vertical penetration of a Hall anchor. In total, 52 numerical analyses were conducted to investigate the relationship between anchor penetration depth and the initial kinematic energy. Moreover, a sensitivity analysis was performed to investigate the effects of soil shear strength and soil type on the penetration mechanism of a drop anchor under self-weight. There is a monotonic increase in the penetration depth with an increasing anchor weight when the topsoil of the riverbed is not subjected to erosion. On the other hand, all the computed depths significantly increase when soil erosion is taken into consideration. This is mainly due to an enhanced initial kinematic energy from an increased dropping depth. Both depths increase exponentially with the initial kinematic energy. An enhanced shear strength can potentially increase the side resistance and end-bearing pressure around a drop anchor, thus significantly reducing the downward penetration of a hall anchor. Design charts are developed to directly estimate penetration depth and associated plastic zone due to dynamically installed anchor at arbitrary soil shear strength and anchor kinematic energy.

• Journal of the Korea Institute of Building Construction
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• v.11 no.1
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• pp.83-90
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• 2011

The purpose of this research is to investigate the effect of AFm formation on the stiffening process of cement paste. High and low alkali sulfate clinkers were used for the experiments. The flow and stiffening behavior of cement paste was investigated using modified ASTM C403 penetration resistance test and oscillatory shear rheology. X-ray powder diffraction (XRD) was used for phase identification associated with stiffening of the paste. It was found from the results that low alkali clinker mixture produced very strong premature stiffening whereas high alkali clinker mixture did not cause premature stiffening. This is because of the large amount of alkali sulfate present in the clinker. Addition of calcium and sodium chloride to the high alkali clinker mixture caused faster stiffening and set.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2277-2280
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• 2014

The contact properties between gold and poly(3-hexylthiophene) (P3HT) films having either of two distinct molecular orientations and orderings were investigated. Thermal treatment increased the molecular ordering of P3HT and remarkably reduced the contact resistance at the electrode/semiconductor interface, which enhanced the electrical performance. This phenomenon was understood in terms of a small degree of metal penetration into the P3HT film as a result of the thermal treatment, which formed a sharp interface at the contact interface between the gold electrode and the organic semiconductor.