• Title/Summary/Keyword: penetration ratio

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Preparation of Anion-exchange Membrane for Selective Separation of Urea and Ion (요소(Urea) 및 이온의 선택적 분리를 위한 음이온교환막의 제조)

  • Kim, Byoung-Sik;Kim, Min;Heo, Kwang-Beom;Hong, Joo-Hee;Na, Won-Jae;Kim, Jae-Hun
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.303-309
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    • 2006
  • In this study, functional anion-exchange membranes have been prepared and characterized to improve the permeation fluxes of the anion and urea for peritoneum dialysis. They were prepared by UV and radiation graft polymerization methods. The separation-membrane prepared by UV graft polymerization showed the highest grafting degree when HEMA and VBTAC were mixed by 1:2 ratio. However, the grafting degree decreased slightly at compositions above the 1:2 ratio because of the disruption of UV penetration caused by build-up of homopolymer. In the case of photo-initiator, the grafting degree increased up to 0.2 wt%, above which it decreased to a small extent. For the two membranes prepared by radiation graft polymerization, the VBTAC/HEMA membrane showed 96% grafting degree for 6 h reaction time and the GMA membrane showed over 100% grafting degree for 2 h reaction time. Anion-exchange membranes were prepared with 113% grafting degree and with DEA and TEA exchange groups. The DEA membrane showed the conversion degree of 70% in 4 h reaction time while the TEA membrane showed 30% in 2 h reaction time. The prepared anion-exchange membranes were permeable to only anions and urea, but not cations.

THE INFLUENCE OF IRM TEMPORARY RESTORATIONS ON MARGINAL MICROLEAKAGE OF DENTIN ADHESIVES (IRM 임시수복이 상아질 접착제의 변연 미세누출에 미치는 영향)

  • Cho, Young-Gon;Kim, Hyun-Kyung;Lee, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.28 no.1
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    • pp.1-10
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    • 2003
  • This study investigated the influence of IRM on marginal microleakage of 5th generation adhesives. Class V cavities with gingival margins in dentin were prepared on both buccal and lingual surfaces of 60 extract-ed human molar teeth. Prepared teeth were randomly divided into six groups. Group 1 and 4 received no temporary restoration with IRM. Group 2 and 5 were covered with IRM mixed at P/L ratio(10g/1g). Group 3 and 6 were covered with IRM mixed at P/L ratio(10g/2g). The temporary restorations were removed mechanically with an ultrasonic scaler after one-week storage in distilled water. The cavities were restored using one of two adhesives and composites ; Single Bond/Filtek Z 250(Croup 1, 2 and 3), UniFil Bond/UniFil F(Group 4, 5 and 6). Following one day storage in distilled water, the restored teeth were thermocycled for 500 cycles(between $5^{\circ}C{\;}and{\;}55^{\circ}C$) and immersed in 2 % methylene blue for dye penetration testing. The results were analysed using Kruskal-Wallis Test, Mann-Whitney and Wilcoxon signed ranked test at a significance level of 0.05. The results of this study were as follows 1. Ranking of mean microleakage scores at the enamel margins was Group 10.05) 4. At the dentin margins, the microleakage of the group not pretreated with IRM was lower than that of the group pretreated with IRM. And the microleakage of UniFil Bond was lower than that of Single Bond. 5. Compared with microleakages between the enamel and dentin margins of each groups, Group 1, 2, 3, 4, 5 and 6 at dentin margin were higher microleakage than those at enamel margin. There were significant difference between enamel and dentin microleakage of Group 2 and 3(p<0.05).

A Study on the Applicability of Arias Intensity Liquefaction Assessment (Arias Intensity 액상화 평가기법의 적용성에 관한 연구)

  • Hwang, Jungtae;Lee, Jongkeun;Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.6
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    • pp.13-19
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    • 2013
  • In this study, the target ground was selected for the assessment of liquefaction, for which energy-based Arias intensity liquefaction assessment method was applied, The results of evaluation by simplified method using conventional in-situ test were compared. The result of the assessment of liquefaction revealed that the safety factor of the Arias Intensity using the actual records of the Hachinohe and Ofunato earthquake showed generally similar trends with the simplified method, However, the Arias Intensity factor of safety for the artificial earthquake created from the design response spectrum showed some difference from the factors of safety of the simplified method. The shear stress ratio and the occurrence strength of the Arias Intensity are differently calculated between stress and energy, but the resistance stress ratio of the simplified method and the resistance strength of the Arias Intensity use the empirical chart of the results of the standard penetration test for the actual liquefaction areas by the earthquake, which seems the reason for the similar results between Arias Intensity assessment and stress concept simplified method for Hachinohe and Ofunato earthquakes. Therefore, it was found that the energy-based Arias Intensity liquefaction assessment could represent the dynamic changes of the ground caused by seismic characteristics such as acceleration, magnitude, duration and amplitude.

Effects of the Rheological Properties of UV Cured Acrylic Pressure Sensitive Adhesive with Nano-particles on the Silk Screen Printing and Adhesion (실크 스크린 인쇄 및 점착력에 나노 입자가 포함된 UV 경화형 아크릴계 감압 점착제의 유변학적 특성)

  • Cho, Min-Jeong;Kang, Ho-Jong;Kim, Dong-Bok
    • Journal of Adhesion and Interface
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    • v.18 no.1
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    • pp.25-32
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    • 2017
  • For application to display module junction process, the silk screen printing based on UV curable acrylic pressure sensitive adhesive(PSA) with silica nano-particles and the rheological properties were studied to investigate the effect on printability and adhesion. The monomers for PSA were based on 2-ethylhexyl acrylate(2-EHA) and acrylic acid(AA) 93:7, butyl acylate(BA), 2-hydroxyethyl acrylate(2-HEA) and tetrahydrofurfuryl acrylate(THFA) were added. Additionally, hydrophobic and hydrophilic nano-particles AEROSIL R974 and AEROSIL 200 were added, respectively. When the ratio of nano-particle was used above 4 or 7 phr, G' and ${\eta}^*$ were increased significantly. When the ratio of AEROSIL 200 was used above 7 phr, the penetration property was decreased during the silk screen printing. We found that the adhesion was decreased with increasing the nano-particle content, and it was decreased in the case of the hydrophilic nano-particle AEROSIL 200.

Durability Performance Evaluations on Resistance to Chloride Attack for Concrete Using LCD Waste Glass Powder (LCD 폐유리 미분말을 사용한 콘크리트의 염해내구성 평가)

  • Kim, Seong-Kyum;Lee, Kwang-Woon;Song, Jae-Ho;Jang, Il-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.289-296
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    • 2018
  • In this study, we evaluated the feasibility and performance of LCD waste glass as a replacement for cement by using LCD waste glass powder which is generated from manufacturing process due to development of LCD industry. Experiments were carried out by replacing 10% and 20% cement of LCD waste glass with particle size of $12{\mu}m$ of LCD waste glass with OPC and particle size of $5{\mu}m$, respectively. Through experiments, basic properties, mechanical properties and durability of concrete were evaluated. Experimental results show that the compressive strength is high at 10% replacement ratio compared to 20%. The lower the particle size, the higher the strength. The durability test evaluated the chloride penetration performance through the chloride ion diffusion coefficient. The higher the substitution rate and the smaller the particle size, the lower the chloride ion diffusion coefficient and the better the OPC than the all substitution rate. As a result, LCD waste glass concrete with low granularity and proper replacement ratio is considered to be advantageous for durability under salt environment.

Evaluation of Permeability Characteristics of Yangsan Clay using Piezocone Penetration Tests and Laboratory Tests (피에조 콘 시험과 실내시험을 이용한 양산점토의 투수특성 평가)

  • Gu, Namsil;Kim, Youngmin;Park, Jaehwhan
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.12
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    • pp.47-54
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    • 2011
  • Consolidation behavior of soft clay is generally to be affected by its compressibility and deformation characteristics. Especially, soil permeability depends on soil characteristics including its type of anisotropy. Coefficient of permeability of soft clay is mostly estimated by using laboratory(Oedometer test) and in-stiu piezocone test. The permeability characteristics of soft clay is estimated by excess pore pressure dissipation test results. In this study, the tests were performed to find out the validity of the existing theoretical formula in clay by pore pressure dissipation test and laboratory test results. After grasping of variation the coefficient of permeability ratio(${k_{h}/k_{v}}$) in different clay soils, it was found out adequate solution of in-stiu permeability ratio(${k_{h}/k_{v}}$). Piezocone tests and laboratory tests were performed at the site of pilot project of ground improvement at Yangsan-Mulgeum, Gyeongsangnam-do. Comparisons of the estimated values of ${k_{h}/k_{v}}$ using piezocone tests results and those from laboratory consolidation tests were carried out. Test results show that values of ${k_{h}/k_{v}}$ by piezocone test result(5.85) is similar of it's laboratory test(5.28).

Skin Barrier Function Enhancement Effect about Ceramide Liquid Crystal Emulsion: Similar Ratio of Skin Lipid Composition (피부 지질 조성 모사 Ceramide 액정 에멀젼의 피부 장벽 강화 효과 확인에 관한 연구)

  • Han, Ji Hye;Lee, Ju Yeon;Lee, Kwan Hyoung;Kim, Hee Sun;Park, Chang Yeol;Maeng, Ji Hye;So, Ji Min;Nam, Gae Won;Kim, Sang Chul
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.1
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    • pp.49-56
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    • 2021
  • In this study, a liquid crystal emulsion with a composition ratio similar to the skin lipid composition was manufactured using ceramide, glycolipids, cholesterol, and fatty acids, and a polarized microscope was used to identify liquid crystal particles in the formulation, and a cryso-SEM was used to confirm the formation of a multilayer structure. The above samples were stored at room temperature for one month and the liquid crystal structure was continuously maintained through microscopic observation. In addition, a cream composition containing liquid crystal emulsion was manufactured, and the efficiency of ceramide skin penetration was confirmed using three-dimensional artificial skin. Clinical trials were conducted using the cream composition and the results of clinical trials on skin barrier improvement were confirmed by measuring skin moisture retention (skin hydration) and transepidermal water loss (T EWL) of subjects compared to general emulsion.

Characteristics of Chloride Diffusion and Compressive Strength in the Mortar containing C12A7 based Binder and Anhydrite (C12A7계 바인더와 무수석고를 혼입한 모르타르의 염화물 확산 및 압축강도 특성)

  • Byeong-Cheol, Lho;Yong-Sik, Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.450-456
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    • 2022
  • In this study, as the preliminary research on the development of heating concrete members, compressive strength and accelerated chloride diffusion behavior in the mortar specimens containing C12A7 based binder and anhydrite was evaluated. Also, the effect of the mixing ratio of the citric acid based retarder was quantitatively evaluated by considering 4 levels of mixing cases. The compressive strength tests of the mortar specimen were performed referred to KS L ISO 679, and the accelerated chloride diffusion tests were performed according to NT BUILD 492 and ASTM C 1202. In the mortar with 0.3 % of retarder, the highest compressive strength was evaluated, which showed the strength development ratio of 127.6 % compared to the control case. It was considered that engineering performance was improved by effectively securing setting and curing time with 0.3 % of citric acid based retarder. As the result of the evaluation of the passed charge and the accelerated chloride diffusion coefficient, the evaluation results had similar behavior with the results of compressive strength. According to the previous study, the strength behavior and the chloride diffusion behavior had a linear relationship. The mixture showing the highest strength performance had the highest durability performance for chloride ingress, and the heating concrete development from this study will be performed in the future.

Mechanism of Dilatory Dissipation during Piezocone Tests in Lightly Overconsolidated Cohesive Soil (약간 과압밀된 점성토에서 발생하는 피에조콘 지연소산 메커니즘)

  • Ha, Tae-Gyun;Jung, Jong-Hong;Kim, Hong-Jong;Park, Lae-Seon;Chung, Choong-Ki
    • Journal of the Korean Geotechnical Society
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    • v.23 no.10
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    • pp.73-84
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    • 2007
  • For standard piezocones with shoulder filter elements immediately behind the cone tip, general dissipation curves show monotonically decreasing pore pressure from the initial value. However, dilatory dissipation behavior, showing a temporary increase in pore pressure followed by a decrease in the hydrostatic pressure, has been observed in lightly overconsolidated cohesive soils $(1. This unusual dissipation behavior was reported mostly in heavily overconsolidated ground and previous researches were limited to such cases. In this study, the mechanism of dilatory dissipation in lightly overconsolidated cohesive soils was investigated. The relativities of the ground properties evaluated from the CPTu data to the dilatory dissipation were analyzed. And, finite difference analyses on dissipation after cone penetration were performed. It was found that dilatory dissipation occurs in lightly overconsolidated soils since the higher excess pore pressure at the cone face propagates upward to the shoulder filter. Also, it was shown that the ratio of initial excess pore pressure at the cone face to that of the shoulder filter $({\Delta}u_{1i}/{\Delta}u_{2i})$, which is related to overconsolidation ratio (OCR) and hydrostatic pressure $(u_0)$, affects the dilatory dissipation.

A Study on Friction Anisotropy between Sand and Surface Asperities of Plate Using Modified Direct Shear Test (수정된 직접 전단 시험기를 이용한 모래와 표면 돌출부를 갖는 플레이트 사이의 마찰 이방성에 대한 연구)

  • Lee, Seung-Hun;Chong, Song-Hun
    • Journal of the Korean Geotechnical Society
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    • v.38 no.2
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    • pp.29-38
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    • 2022
  • The friction anisotropy of shear resistance can be selectively used in geo-structures. For example, larger axially loaded deep foundation, soil nails, and tiebacks increase load carrying capacity due to induced large shear resistance while pile penetration and soil sampling produce minimal shear resistance. Previous studies confirmed direction-dependent shear resistance induced by interface between soil and surface asperity of plate inspired by geometrical shape of snake scale. The aim of this paper is to quantitatively evaluate interface friction angle with different surface asperities. Using the modified direct shear test, a total of 51 cases, which sand are prepared at the relative density of 40%, are conduced including 9 plates, two shear direction (shearing direction against the height of surface asperity is increased or decreased during shearing test), and three initial vertical stress (100 kPa, 200 kPa, 300 kPa). Experimental results show that shear stress is increased with higher height of surface asperity, shorter length of surface asperity, and the shearing direction that the height of surface asperity increases. Also, interface friction angle is decreased with larger surface asperity ratio, and shearing direction with increasing height of surface asperity produces larger interface friction angle regardless of the surface asperity ratio.