• 제목/요약/키워드: peak concentration

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산화법에 의한 YAG:Ce 형광체의 발광 특성 (Luminescence characteristics of YAG:Ce phosphor by combustion method)

  • 최형욱;이승규;차재혁;박용서
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.322-323
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    • 2006
  • The nano-sized Ce-doped YAG(Yttrium Aluminum Garnet, $Y_3Al_5O_{12}$) phosphor powders were prepared by combustion method from a mixed aqueous solution of metal nitrates, using citric acid as a fuel. The luminescence formation process and structure of phosphor powders were investigated by means of XRD, SEM and PL. The XRD patterns show that YAG phase can form at all of the $Ce^{3+}$ concentration. However, when $Ce^{3+}$ concentration is over 2.0mol%, XRD patterns show $CeO_2$ peak between (321) peak and (400) peak. The pure crystalline YAG:Ce with uniform size of 30nm was obtained at 0.6mol% of the $Ce^{3+}$ concentration. The crystalline YAG:Ce powders showed broad emission peaks in the range 475~630nm and had maximum intensity at 526nm.

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EFDC를 이용한 대청댐내 보존성 오염물질 확산 모델링에 관한 연구 (Modelling the Dispersion Behavior of Conservative Pollutants within Daechung Dam using EFDC-Hydro)

  • 박노석;김성수;정선아;김종오;김도환;강문선
    • 상하수도학회지
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    • 제26권5호
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    • pp.705-712
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    • 2012
  • Selecting Daechung Dam as a sample study site, this study simulates virtual water quality incident which can be occurred using EFDC maintained by USEPA. In order to predict the behavior and diffusion of leaked conservative pollutant within dam under the worst condition, the hydrological data and information from 2008 were used. EFDC was successfully calibrated for observed water level obtained from the above sources. From the results of simulations, even though the concentrations (500 ppm, 1,000 ppm and 10,000 ppm) of leaked pollutant were different with each other at the same sources, the travel time of each peak concentration appeared similar. Also, changing the leak source point from dam gate(0 km) to 7 km, it was found that as leak source point was nearer to the dam gate, the travel time of each peak concentration showed up sooner. It was simulated to take 1 day to 15 days for initial appearance of the leaked pollutant according to the leaked points, and 3 days to 25 days for the reach of the peak concentration, respectively.

튜브 전기로를 이용한 TiO2 나노입자의 합성 및 특성 분석 (Synthesis and Analysis of Nanosized TiO2 Particles Using a Tube Furnace)

  • 배귀남;현정은;이태규;정종수
    • 한국대기환경학회지
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    • 제20권3호
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    • pp.411-419
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    • 2004
  • Titania particles are widely used as a photocatalyst to treat various contaminants in air and water. Titania particles were formed by vapor-phase oxidation of titanium tetraisopropoxide (TTIP) in a tube furnace between 773 and 1,273 K. The effect of process variables such as furnace temperature, flow rate of carrier air, and flow rate of sheath air on powder size and phase characteristics was investigated using a scanning mobility particle sizer (SMPS), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The size distribution of synthesized titania particles was characterized with mode diameter and peak concentration. The mode diameter ranging from 20 to 80 nm decreased with increasing flow rates of sheath air and carrier air, and increased with increasing furnace temperature. The peak concentration increased with increasing flow rates of sheath air and carrier air The best synthetic condition for high production rate can be derived from the experimental data set represented by mode diameter and peak concentration. The crystal structure of synthesized titania particles was found to be anatase phase, ensuring high photocatalytic potential.

THE RELATIONSHIP BETWEEN BUFFER INDEX CURVE AND FERMENTATION QUALITY OF SILAGE

  • Kim, K.H;Uchida, S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제4권1호
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    • pp.67-71
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    • 1991
  • The purpose of this study was to investigate the possibility of using the buffer index curve as a criterion of silage quality evaluation. The buffer index (or buffer capacity, $\beta$) value is the amount of 0.1N NaOH consumed in titrating from the beginning to the end of the chosen pH step. This value equals the slope of the titration curve at the chosen pH range (${\beta}={\Delta}NaOH/{\Delta}pH$). There were two patterns of buffer index curve. Poorly preserved silages had a peak at pH 5.0, whereas with well preserved silages the peaks tended to rise to the pH 3.75 or 4.00. Well preserved, wilted silages with high pH also appeared to have peak values at pH 3.75 or 4.00. There was a high positive correlationship between the concentration of lactic acid and peak value of good quality silage (r = 0.994, p < 0.01). Also a high positive correlationship (r = 0.899, p < 0.001) was found between the sums of concentration of acetic and butyric acids and the peak values of poor quality silages. The results of these experiments verified the value of the buffer index method as a criterion of silage quality evaluation.

Relative Bioavailability Studies on Two Tablet Preparations of Ofloxacin

  • Shakya, Ashok-K.;Talwar, Naresh;Karajgi, Jayant;Singhai, Akhlesh
    • Archives of Pharmacal Research
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    • 제15권3호
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    • pp.208-210
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    • 1992
  • Comparative bioavailability of two tablet dosage forms of ofloxacin (either as Hoechst (India) or Ranbaxy preparation ) was investigated. In a randomized cross-over study, eitht healthy human volunteers received single 200 mg dose of film coated ofloxacin in fasting state. The concentration of ofloxacin in the collected saliva and serum samples were measured by high performance liquid chromatography. No significant difference in bioavailability of both preparations was judged from various serum and seliva pharmacokinetic parameters such as peak concentration, time to peak concentration and are under the curves. Intersubject variation was also found to be insignificant.

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갈수기(渴水期) 하천(河川)에서의 오염물질(汚染物質)의 확산(擴散) 및 이동(移動) (Low Flow Pollutant Transport in Natural Rivers)

  • 서일원
    • 상하수도학회지
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    • 제7권1호
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    • pp.29-36
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    • 1993
  • The complex nature of low flow mixing in natural channels has been investigated using both laboratory experiments and the numerical solution of a proposed mathematical model that is based on a set of mass balance equations describing the mixing and mass exchange mechanisms. Laboratory experiments, which involved collection of channel geometry, hydraulic, and dye dispersion test data, were conducted in a model of four pool and riffle sequences in a 49-m long tilting flume. The experimental results show that flow over the model pool-riffle sequences is highly non-uniform. Concentration-time curves are significantly skewed with long tails. Comparison between measured and predicted concentration-time curves shows good agreement in the general shape, peak concentration and time to peak. The proposed model shows significant improvement over the conventional one-dimensional dispersion model in predicting natural mixing processes in open channels under low flow conditions through pools and riffles.

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압연기용 Roll의 동견부(Chamfer=Barrel Edge)에서의 음력집중의 완화 대책 (Analysis on contact stress concentration at the end of strip mill rolls)

  • 소야신시
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 제7회 압연 심포지엄
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    • pp.13-16
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    • 2009
  • In order to investigate the effects of geometry factors such as a roil diameter ratio and backup roll crown of the stress concentration factor on the edge of backup roil end, 3-dimensional FEM analyses of stress at the contact of backup roll and work roll assembled in a 4-high strip mill were carried out, It was made clear that the peak stress at the edge is about 2 to 3 times of that at the longitudinal center of the roll barrel and the peak stress proportionally increase with decreasing the ratio of backup roll diameter to work roll diameter Furthermore a crowning on the backup roll is effective to decrease the maximum edge stress.

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Synthesis of Polyacrylonitrile as Precursor for High-Performance Ultrafine Fibrids

  • Kim, Subong;Kuk, Yun-Su;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.407-414
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    • 2014
  • Polyacrylonitrile (PAN) copolymers with different methyl acrylate (MA) contents were synthesized via solution polymerization and used as precursors for high-performance PAN ultrafine fibrids. The chemical structures of the copolymers were characterized using Fourier-transform infrared spectroscopy and $^{13}C$ nuclear magnetic resonance spectroscopy. Their particle sizes and aspect ratios increased with increasing viscosity, and the degree of crystallinity increased with decreasing concentration of copolymer solution. In contrast, their peak temperature and heat of exotherm increased with decreasing concentration of the copolymer solution. The aromatization indices (AIs) of the fibrids increased with increasing heat-treatment time; however, the AIs decreased when the heat-treatment temperature was higher than the onset temperature of the copolymers. On the other hand, the crystal sizes of the fibrids decreased with increasing concentration of the copolymer solution when the MA content was held constant.

오존최대농도지표를 이용한 오존단기예측모형 개발 (Development of a Short-term Model for Ozone Using OPI)

  • 전의찬;김정욱
    • 한국대기환경학회지
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    • 제15권5호
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    • pp.545-554
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    • 1999
  • We would like to develop a short-term model to predict the time-related concentration of ozone whose reaction mechanism is complex. The paper targets Seoul where an ozone alert system has recently been employed. In order to develop a short-term prediction model for ozone, we suggested the Ozone Peak Indicator(OPI), an equivalent of the potential daily maximum ozone concentration, with precursors being the only limiting factor, and we calculated the Ozone Peak Indicarot as OPI={$ rac{(O_3)_{max}cdot(H_{eH})_{max}(Rad)_{max}$ to preclude the influence of mixing height and solar radiation on the daily maximum ozone concentration. The OPI on the day of the prediction is to be calcultated by using the relation between OPI and the initial value of precursors. The basic prediction formula for time-related ozone concentration was established as $O_3(1)={(OPI)cdot Rad(t-2)H_{eH}}$, using the OPI, solar radiation two hours before prediction and mixing height. We developed, along with the basic formula for predicting photochemical oxidants, "SEOM"(Seoul Empirical Oxidants Model), a Fortran program that helps predict solar radiation and mixing height needed in the prediction of ozone pollution. When this model was applied to Seoul and an analysis of the correlation between the observed and the predicted ozone concentrations was made through SEOM, there appeared a very high correlation, with a coefficient of 0.815. SEOM can be described as a short-term prediction model for ozone concentration in large cities that takes into account the initial values of precursors, and changes in solar radiation and mixing height. SEOM can reflect the local characteristics of a particular and region can yield relatively good prediction results by a simple data input process.t process.

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강우 및 유입 하천수가 팔당호 수질에 미치는 영향분석 (A Study on the Water Quality Affected by the Rainfall and Influent Rivers in Paldang Reservoir, Korea)

  • 김종민;노혜란;허성남;양희정;박준대
    • 한국물환경학회지
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    • 제21권3호
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    • pp.277-283
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    • 2005
  • This paper aimed to compare the daily water quality as well as the hydrological data gathered for the past two years (2000 to 2001) between the two influent rivers of Paldang reservoir. The analysis also has been carried out to draw out the factors that affect the water quality at the dam site, where the main drinking water drawing point is located. The relationship between total amount of monthly rainfall and monthly inflow showed $r^2=0.74$ (p<0.05). The highest peak of inflow of influent rivers recorded in August and September (in the year of 2000) and July and August (2001). Average inflows of influent rivers in 2000 and 2001 are calculated at 209.0, 161.5 CMS (Bughangang), 268.6, 148.2 CMS(Namhangang), and 7.8, 5.0 CMS (Gyeongancheon). The formula which was driven from the relationship between inflow and COD load of influent rivers, explained that COD concentration in general increased with the inflow. But during the rainy seasons (July, August, and September), COD concentration decreased according to the increase of inflow. The daily rainfall and COD concentration(or load) during the rainy season (August and September in the year of 2000, July and August in 2001) indicated that the peak of COD load correspond with the rainfall, which decreased sharply after 3 or 4 days. The reason was thought that the high COD load was diluted rapidly by the rain flow. Water temperature, pH and conductivity measured at dam site decreased obviously when the inflow sharply increased. Peak period of total phosphorus concentration coincided with that of inflow. In rainy season, chlorophyll-a concentration decreased obviously as the inflow increased. The reason can be ascribed to the flushing effect caused by the operation of floodgate.