• 한국산업융합학회 논문집
• /
• 제2권2호
• /
• pp.73-81
• /
• 1999

Shake mixing has been widely used in cell culture. The mixing performance for shake mixing, however, has not been reported quantitatively. The critical circulating frequency and the power consumption for complete suspension of particles, based on the definition of Zwietering, were measured in a shaking vessel containing a solid-liquid system. The critical suspension frequency was correlated by the equation from Baldi's particle suspension model modified with the physical properties of the particles. Critical suspension frequency was correlated as following ; $$N_{JS}={\frac{0.58\;d{_p}^{0.06}(g{\Delta}{\rho}/{\rho}_L)^{0.004}X^{0.03}}{D^{0.35}d^{0.17}{\upsilon}^{0.04}}}$$ The power consumption at the critical suspension condition in the shaking vessel was less than that in an agitated vessel with impeller.

• Korea-Australia Rheology Journal
• /
• 제15권4호
• /
• pp.179-185
• /
• 2003

Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

• 약학회지
• /
• 제35권4호
• /
• pp.277-282
• /
• 1991

Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

• 한국세라믹학회:학술대회논문집
• /
• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
• /
• pp.33.2-33
• /
• 2003

• 물과 미래
• /
• 제27권3호
• /
• pp.115-121
• /
• 1994

하구수리계에 있어서 점착성류사의 운동은 응결과 응집(aggregation) 현상에 의해 크게 좌우되며, 이들 현상에 의하여 의결된 입자들의 크기, 모양, 강도는 그 퇴적율과 그리고 부유류사와 오염물질의 변동과정에 영향을 미친다. 본 연구에서는 Brownian 운동에 의해 지배되는 이동성 부유영역과 중력에 의해 지배되는 정체성 부유영역으로 분리하여 점착성입자들의 응집과 응결과정을 모의하였다. 이동성 부유영역에 있어서는 Smoluchowski 모형중 입자들의 무작위 회전을 이용한 최대연쇄 모형으로 응집물질의 사영들을 도출하였으며, 그 회전반경에 의해 사영들의 쪽거리 차원을 구하였다. 저에성 부유영역에서의 응집물질(Brownian 영역을 벗어나 침강하는 응집물질)는 비구형 입자들의 침강으로 간주되어진다. 최종 침강속도 차이로 이들 응집물들은 재차 충돌, 결합하여 보다 큰 응집 입자들을 형성하며, 이들 최종 응집입자들의 사영이 모의되어진다. 최대 Feret's 직경과 Minkowski's sausage logic 개념들을 이용하여 모의되어진 사영들의 둘레 길이에 대하여 쪽거리 차원들을 구하였다.

• Korea-Australia Rheology Journal
• /
• 제14권4호
• /
• pp.203-207
• /
• 2002

Particle-particle interaction is of great importance in the study of suspension rheology. In this research we have investigated the hydrodynamic interaction between two identical cylinders in viscoelastic fluids numerically as a model problem for the study of viscoelastic suspension. We confine two neutrally buoyant cylinders between two parallel plates and impose a shear flow. We determine the migration velocity of two cylinders. The result shows that cylinders move toward or away from each other depending upon the initial distance between them and that there is an equilibrium distance between two cylinders in viscoelastic fluids regardless of the initial distance. In the case of Newtonian fluid, there is no relative movement as expected. The results partly explain the chaining phenomena of spherical particles in shear flows of viscoelastic fluids.

• Korean Chemical Engineering Research
• /
• 제60권2호
• /
• pp.260-266
• /
• 2022

Average aggregate size in particulate suspensions is estimated with scaling theories based on fractal concept and elasticity of colloidal gel. The scaling theories are used to determine structure parameters of the aggregates, i.e., fractal dimension and power-law exponent for aggregate size reduction with shear stress using scaling behavior of elastic modulus and shear yield stress as a function of particle concentration. The structure parameters are utilized to predict aggregate size which varies with shear stress through rheological modeling. Experimentally rheological measurement is conducted for aqueous suspension of zinc oxide particles with average diameter of 110 nm. The predicted aggregate size is about 1135 nm at 1 s^-1 and 739 nm at 1000 s^-1 on the average over the particle concentrations. It has been found that the predicted aggregate size near 0.1 s^-1 agrees with that the measured one by a dynamic light scattering analyzer operated un-sheared.

• 한국재료학회지
• /
• 제21권3호
• /
• pp.156-160
• /
• 2011

FePt nanoparticles suspension was synthesized by reduction of platinum acetylacetonate and decomposition of iron pentacarbonyl in the presence of oleic acid and oleyl amine. FePt nanoparticles were coated on a substrate by convective assembly from the suspension. To prevent the coalescence during the annealing of FePt nanoparticles double convective coatings were tried. First convective coating was for silica particle assembly on a silicon substrate and second one was for FePt nanoparticles on the previously coated silica layers. It was observed by scanning electron microscopy (SEM) that FePt nanoparticles were dispersed on the silica particle surface. After annealing at $700^{\circ}C$ for 30 minutes under nitrogen atmosphere, FePt nanoparticles on silica particles were maintained in a dispersed state with slight increase of particle size. On the contrary, FePt nanoparticles that were directly coated on silicon substrate showed severe particle growth after annealing due to the close-packing of nanoparticles during assembly. The size variation during annealing was also verified by X-ray diffractometer (XRD). It was suggested that pre-coating, which offered solvent flux oppose to the capillary force between FePt nanoparticles, was an effective method to prevent coalescence of nano-sized particles under high temperature annealing.

• Korea-Australia Rheology Journal
• /
• 제18권4호
• /
• pp.171-181
• /
• 2006

We present a short review for authors' previous work on direct numerical simulations for inertialess hard particle suspensions formulated either with a Newtonian fluid or with viscoelastic polymeric fluids to understand the microstructural evolution and the bulk material behavior. We employ two well-defined bi-periodic domain concepts such that a single cell problem with a small number of particles may represent a large number of repeated structures: one is the sliding bi-periodic frame for simple shear flow and the other is the extensional bi-periodic frame for planar elongational flow. For implicit treatment of hydrodynamic interaction between particle and fluid, we use the finite-element/fictitious-domain method similar to the distributed Lagrangian multiplier (DLM) method together with the rigid ring description. The bi-periodic boundary conditions can be effectively incorportated as constraint equations and implemented by Lagrangian multipliers. The bulk stress can be evaluated by simple boundary integrals of stresslets on the particle boundary in such formulations. Some 2-D example results are presented to show effects of the solid fraction and the particle configuration on the shear and elongational viscosity along with the micro-structural evolution for both particles and fluid. Effects of the fluid elasticity has been also presented.

• 한국의류학회지
• /
• 제28권6호
• /
• pp.854-861
• /
• 2004

To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 ％ surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.