• 대한환경공학회지
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• 제32권12호
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• pp.1147-1153
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• 2010

본 연구에서는 Compound parabolic concentrator reactor system을 이용하여 초기농도 10 mg/L의 클로로포름을 광촉매 반응으로 처리하였다. 1000 W의 메탈할라이드 방전램프를 인공태양광원으로 사용하였으며 약 99%의 클로로포름이 광촉매반응에 의하여 90분 안에 제거되어 먹는물 수질기준인 0.08 mg/L을 만족하였다(pH 5.24, $TiO_2$ 농도 0.2 g/L). 또한 초기 pH와 $TiO_2$ 농도가 클로로포름의 분해에 미치는 영향 을 알아보기 위해 pH 4, 5, 6, 7과 $TiO_2$ 농도 0.1, 0.2, 0.4의 조건에서 실험을 수행하였으며, 각 pH 에서의 $TiO_2$ 입자크기(particle size)와 비표면적(specific surface area)을 측정하여 클로로포름 분해율과 비교하여 비표면적과 광촉매반응 활성 사이의 상관관계를 규명하고자 하였다. 그 결과 pH와$TiO_2$ 농도에 따른 클로로포름 분해율은 큰 차이를 보이지 않았다. 하지만 pH에 따라 $TiO_2$의 입자크기분포(particle distribution)와 비표면적이 변했고 pH 7은 다른 pH 영역보다 비표면적이 약 2배 정도 작은 결과를 보였다. 본 연구의 결과를 바탕으로 클로로포름의 광촉매반응은 $TiO_2$의 비표면적과 상관관계가 없는 TCE-type인 것을 유추할 수 있었다.

• 한국재료학회지
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• 제22권1호
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• pp.54-60
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• 2012

The particle size of MgO was examined as a function of the Na content in $Mg(OH)_2$ powders and the calcination temperature. $Mg(OH)_2$ suspension was obtained by dropwise precipitation of $Mg(NO_3)_2{\cdot}6H_2O$ and NaOH solutions. The suspension was diluted by varying the dilution volume ratio of distilled water to $Mg(OH)_2$ suspension to change the Na salt concentration in the suspension. $Mg(OH)_2$ slurry was filtered and dried at $60^{\circ}C$ under vacuum, and then its $Mg(OH)_2$ powder was calcined to produce MgO with different amount of Na content at $500\sim900^{\circ}C$ under air. Investigation of the physical and chemical properties of the various MgO powders with dilution ratio and calcination temperature variation was done by X-ray diffraction, transmission electron microscopy, BET specific surface area and thermal gravimetric analysis. It was observed that MgO particle size could depend on the condition of calcination temperature and dilution ratio of the $Mg(OH)_2$ suspension. The particle size of the MgO depends on the Na content remaining in the $Mg(OH)_2$ powder, which powder was prepared by changing the dilution ratio of the $Mg(OH)_2$ suspension. This change increased as the calcination temperature increased and decreased as the dilution ratio increased. The growth of MgO particle size according to the increase of temperature was more effective when there was a relatively high content of Na. The increase of Na content lowered the temperature at which decomposition of $Mg(OH)_2$ to MgO took place, thereby promoting the crystal growth of MgO.

• 한국식품과학회지
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• 제18권1호
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• pp.48-54
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• 1986

본 연구는 유동층 조립기로 조립시킨 보리 미숫가루 입자들의 인스탄트 성질에 영향을 주는 인자들을 조사하였다. 조립에 사용된 바인더는 맥아당, 포도당, 젤라틴의 수용액과 물 이었으며 조립입자의 인스탄트 효과는 입자의 습윤성, 침강성, 분산성 및 용해성을 측정하여 결정하였다. 바인더의 종류별로 조립된 시료의 인스탄트 성질의 개선에 대한 기여도는 낮은 바인더 수용액에서 5%젤라틴수용액>5%맥아당수용액>5%포도당수용액의 순으로 나타났으며 물은 가장 낮은 인스탄트효과를 보였다. 바인더 용액의 농도증가에 따른 조립입자의 인스탄트성질은 포도당, 맥아당과 같은 당류의 경우 증가되었으나 젤라틴의 경우에는 이와 반대경향을 나타내었다. 조립입자의 크기가 인스탄트성질에 미치는 영향은 현저하였으며 입자의 크기가 $0.1{\sim}0.3mm$일 때, 시료의 인스탄트효과가 가장 좋았다. 조립입자의 건조온도($60^{\circ}C,\;70^{\circ}C,\;80^{\circ}C$)는 입자의 인스탄트효과에 거의 영향을 미치지 않았다. 바인더용액을 사용하여 조립한 미숫가루입자의 흡습속도는 각각의 상대습도(42%, 67%, 92%)에서 5%젤라틴수용액>5%맥아당수용액>5%포도당수용액의 순으로 빠르게 나타났으며 이러한 결과는 바인더 종류가 인스탄트 성질에 미치는 효과와 동일한 순서로 일치함을 보여주었다.

• 대한기계학회논문집
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• 제11권3호
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• pp.501-508
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• 1987

본 연구에서는 입자발생 장치를 유동층(fluidized bed)을 이용하여 만들었고 이것에 의해서 고온의 연소가스속으로 입자가 공급되므로, 종래의 초음파입자 발생기 나 오리피스진동입자 발생기등에서 일어나는 호학반응 및 입자상호간의 응집(coagul- ation)현상등을 되도록 없게 하여 순수한 구형입자에 대한 입자부착 효과를 볼 수 있 게 함으로써, 부착기구의 이해와 해석등을 한층 유리하게 한다. 그리고 공급되는 입 자의 크기의 범위를 직경 0.2$\mu\textrm{m}$~30$\mu\textrm{m}$ 정도로 광범위하게 다루어 비교적 간단하고 잘 정의된 층류 유동에서, (1) 미세입자의 경우 실시간(real time) 레이져 광반사법에 의 한 입자부착률의 온도구배 및 농도에 대한 효과를 실험하고, (2) 입자의 Counting/Si- zing 법에 의하여 입자크기에 따른 열확산 효과 및 관성충돌 효과 등을 볼 수 있게 한 다.

• Advances in concrete construction
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• 제2권1호
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• pp.13-27
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• 2014

The principal objective of this study is to deepen the characterization studies already led on sand concretes in previous works. Indeed, it consists in studying the effect of the sand type on the main properties of sand concrete: fracture and mechanical properties. We particularly insist on the determination of the fracture characteristics of this material which apparently have not been studied. To carry out this study, four different types of sand have been used: dune sand (DS), river sand (RS), crushed sand (CS) and river-dune sand (RDS). These sands differ in mineralogical nature, grain shape, angularity, particle size, proportion of fine elements, etc. The obtained results show that the particle size distribution of sand has marked its influence in all the studied properties of sand concrete since the sand having the highest diameter and the best particle size distribution has given the best fracture and mechanical properties. The grain shape, the angularity and the nature of sand have also marked their influence: thanks to its angularity and its limestone nature, crushed sand yielded good results compared to river and dune sands which are characterized by rounded shape and siliceous nature. Finally, it should further be noted that the sand concrete presents values of fracture and mechanical properties slightly lower than those of ordinary concrete. Compared to mortar, although the mechanical strength is lower, the fracture parameters are almost comparable. In all cases, the sand grains are debonded from the paste cement during the fracture which means that the crack goes through the paste-aggregate interface.

• 대한토목학회논문집
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• 제14권4호
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• pp.941-951
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• 1994

본 연구에서는 국내에서 사용되고 있는 보조기층재료에 대해 변형측정정치의 위치 및 포화도에 따른 $M_R$값의 변화양상을 파악하고, 시료내의 입자크기(particle size)에 따른 치수효과(size effect)를 파악하여 적절한 $M_R$ 관계식을 제시하였다. 외부변형측정장치를 사용한 경우의 $M_R$값은 회복변형율을 과대평가 하기 때문에 내부변형측정장치를 사용한 경우보다 작았고, 포화도에 따른 $M_R$값은 wet 상태($S_r$=70%)가 damp 상태 ($S_r$=40%)보다 10% 정도 작게 나타났으며 시편을 구성하는 입자의 치수효과는 과대 입자(oversize particle)를 제거함에 따른 간극비의 변화와 직접적인 관계가 있음을 알 수 있었다. 이와같은 결과를 종합하여 보조기층의 $M_R$ 관계식은 damp 상태의 포화도에서, $M_R=3960{\cdot}{\theta}^{0.60}$ psi.로 제안할 수 있다.

• 한국항공우주학회지
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• 제44권12호
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• pp.1027-1034
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• 2016

본 논문에서는 실험적 연구를 통해 고체 입자의 크기가 입자 침식에 미치는 영향에 대해 논하였다. 고밀도 폴리에틸렌 입자를 최고 속도 마하 3으로 이단 가스건을 이용해 발사하였다. 발사된 입자를 Al1050, Al6061 T6 알루미늄 합금과 ZnS, 사파이어 적외선창 시편과 충돌시켜 입자침식을 일으켰다. 알루미늄 합금의 표면에는 크레이터가 생성되었다. 크레이터의 크기를 통해, 알루미늄 합금의 입자침식 저항성을 살펴보았다. 적외선창은 시편 표면에 크랙이 생성될 때까지 반복해서 시험하였다. 이를 통해 적외선창의 입자침식 저항 특성을 나타내는 충돌 임계 곡선을 정의할 수 있었다. 다양한 크기의 고체 입자를 이용한 입자침식 시험을 통해, 고체 입자의 크기가 재료의 입자침식 저항성에 선형적으로 영향을 끼친다는 것을 확인할 수 있었다.

• 한국재료학회지
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• 제28권10호
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• pp.539-543
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• 2018

We report the structural, morphological and magnetic properties of the $Ni_{70}Mn_{30}$ alloy prepared by Planetary Ball Mill method. Keeping the milling time constant for 30 h, the effect of different ball milling speeds on the synthesis and magnetic properties of the samples was thoroughly investigated. A remarkable variation in the morphology and average particle size was observed with the increase in milling speed. For the samples ball milled at 200 and 300 rpm, the average particle size and hence magnetization were decreased due to the increased lattice strain, distortion and surface effects which became prominent due to the increase in the thickness of the outer magnetically dead layer. For the samples ball milled at 400, 500 and 600 rpm however, the average particle size and hence magnetization were increased. This increased magnetization was attributed to the reduced surface area to volume ratio that ultimately led to the enhanced ferromagnetic interactions. The maximum saturation magnetization (75 emu/g at 1 T applied field) observed for the sample ball milled at 600 rpm and the low value of coercivity makes this material useful as soft magnetic material.

• 한국도로학회논문집
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• 제18권5호
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• pp.39-47
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• 2016

PURPOSES : Road subsidence occurs owing to road cavities, which cause many social and environmental problems, especially in cities. Recently, road cavities were detected by various ground radars and repair works were carried out against the detected cavities. The condition assessments related to the road cavities are necessary to understand the potential risk of the cavities. Therefore, in this study, a numerical study was performed to assess the various conditions of road cavities. METHODS : The numerical method adopted in this study is the discrete element approach, and it is suitable for analyzing the condition because it can consider the movement of the soil particles in the surrounded cavity areas. In addition, the triaxial test was modeled and performed under various cavity conditions inside the specimens. RESULTS : The conditions of different cavity locations and shapes were analyzed to identify the effect of cavity state. Three general cases of particle size distributions were formulated to identify the effect of surrounding ground conditions. As a result, the degree of decrement and volumetric strain were varied depending on the locations and shapes of the cavity. Only minor changes were observed when the particle size distributions were altered. CONCLUSIONS : The strength reduction was higher when the cavity formed was larger and located in the upper zone. Similar to the cavity shape, strength reduction and volume deformation are more influenced by the width than the length of the cavities. There is an influence from ground conditions such as the particle size distribution, especially on the wide cavity.

• 펄프종이기술
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• 제48권2호
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• pp.61-67
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• 2016

This study was carried out in order to investigate the effect of pigment properties in a pre-coating layer on the characteristics of a top-coating layer and the print mottle of the coated paper. Five different pigments were applied for this study as raw materials for the pre-coating layer. The properties and print mottle of the coated paper samples were evaluated according to the coating color formulation. Type of pigments appliied in a pre-coating layer was one of the most important factor to control the properties of pre and top coating layer. Surface properties of pre and top coated paper were improved by blending GCC which had smaller particle size, with clay. Properties of a top-coating layer was affected by the pigment properties used in the pre-coating layer. It was found that print mottle of coated paper can be improved by replacing part of GCC with smaller particle size GCC or clay in pre-coating layer.