• Title/Summary/Keyword: particle size control

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Assessment of Particle Size Distribution and Pollution Impact of Heavy metalsin Road-deposited Sediments(RDS) from Shihwa Industrial Complex (시화산업단지 도로축적퇴적물의 입도분포 및 중금속 오염영향 평가)

  • Lee, Jihyun;Jeong, Hyeryeong;Ra, Kongtae;Choi, Jin Young
    • Journal of Environmental Impact Assessment
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    • v.29 no.1
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    • pp.8-25
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    • 2020
  • Industrialization has increased the production of road-deposited sediments (RDS) and the level of heavy metals in those RDS, which can have a significant impact on the surrounding aquatic environments through non-point pollution. Although the relationship between contamination characteristics and particle size of RDS is important for pollution control, there is very little information on this. In this study, we investigated the characteristics of grain size distribution and heavy metal concentrations in the road-deposited sediments (RDS) collected from 25 stations in Shihwa Industrial Complex. The environmental impact of RDS with particle size is also studied. Igeo, the contamination assessment index of each metal concentration, represents the RDS from Shihwa Industrial Complex are very highly polluted with Cu, Zn, Pb and Sb, and the levels of those metals were 633~3605, 130~1483, 120~1997, 5.5~50 mg/kg, respectively. The concentrations of heavy metals in RDS increased with the decrease in particle size. The particle size fraction below 250 ㎛ was very dominant with mass and contamination loads, 78.6 and 70.4%, respectively. Particles less than 125 ㎛ of RDS were highly contaminated and toxic to benthic organisms in rivers. RDS particles larger than 250 ㎛ and smaller than 250 ㎛ were contaminated by the surrounding industrial facility and vehicle activities, respectively. As a result of this study, the clean-up of fine particles of RDS, smaller than 125-250 ㎛, is very important for the control and reduction of non-point pollution to nearby water in Shihwa Industrial Complex.

Quality characteristics of Tteokbokki (Rice Cake) depending on cultivars and particle sizes of dry-milling rice flour

  • Song, Eun-Ju;Choi, So-Ra;Song, Young-Eun;Lee, In-Sok;Lee, Ki-Kwon
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.276-276
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    • 2017
  • This study was examined to establish a conditions for producing Tteokbokki using dry-milling rice flour which can save manpower and labor time. Since the cost of producing rice flour milled in a wet condition is 500 to 700 won/kg, which is more than twice as much as that of 300 won wheat flour, it is necessary to directly make rice flour from raw rice. The dry-milling rice flour used in the experiment was produced by Air mill (Nara machinary co. ltd., Tokyo, Japan) from 5 rice cultivars (Samkwang, Dasan-1, Boramchan, Seolgaeng, Hanareum-2), which were cultivated in A-san in 2015 year. Their particle sizes were 50, 100 and $150{\mu}m$ for each cultivar, respectively. A control was a wet-milled rice flour milled with a roll mill after the rice was soaked in water for 4 hours. The moisture content of dry-milling rice flour based on cultivars was 11 ~ 12%, and added water up to 50~55% of dry-milling rice flour weight. The RVA characteristic of peak viscosity was the highest in Dasan-1 and Hanareum-2, the lowest in Seolgaeng. The setback value used as an indicator of aging was the highest in Dasan-1, therefore Dasan-1 was expected to be quick solidification, resulting in the low tendency of sensory evaluation. The damaged starch was high in Dasan-1 and Boramchan (p<0.05) compared to others. The Hunter color L were no significant among cultivars and b value increased in all cultivars of dry-milling rice flour compared with control. The hardness of dry-milling rice flour was higher than that of the control, especially Dasan-1 and Hanareum-2 were the highest. Based on the sensory evaluation, the best cultivars were Boramchan, Hanareum-2 and Samkwang. The overall preference of dry-milling rice flour was good in particle size of 50~100um.

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Antibacterial activity of enrofloxacin loaded gelatin-sodium alginate composite nanogels against intracellular Staphylococcus aureus small colony variants

  • Luo, Wanhe;Liu, Jinhuan;Algharib, Samah Attia;Chen, Wei
    • Journal of Veterinary Science
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    • v.23 no.3
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    • pp.48.1-48.12
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    • 2022
  • Background: The poor intracellular concentration of enrofloxacin might lead to treatment failure of cow mastitis caused by Staphylococcus aureus small colony variants (SASCVs). Objectives: In this study, enrofloxacin composite nanogels were developed to increase the intracellular therapeutic drug concentrations and enhance the efficacy of enrofloxacin against cow mastitis caused by intracellular SASCVs. Methods: Enrofloxacin composite nanogels were formulated by an electrostatic interaction between gelatin (positive charge) and sodium alginate (SA; negative charge) with the help of CaCl2 (ionic crosslinkers) and optimized by a single factor test using the particle diameter, zeta potential (ZP), polydispersity index (PDI), loading capacity (LC), and encapsulation efficiency (EE) as indexes. The formation mechanism, structural characteristics, bioadhesion ability, cellular uptake, and the antibacterial activity of the enrofloxacin composite nanogels against intracellular SASCVs strain were studied systematically. Results: The optimized formulation was comprised of 10 mg/mL (gelatin), 5 mg/mL (SA), and 0.25 mg/mL (CaCl2). The size, LC, EE, PDI, and ZP of the optimized enrofloxacin composite nanogels were 323.2 ± 4.3 nm, 15.4% ± 0.2%, 69.6% ± 1.3%, 0.11 ± 0.02, and -34.4 ± 0.8 mV, respectively. Transmission electron microscopy showed that the enrofloxacin composite nanogels were spherical with a smooth surface and good particle size distributions. In addition, the enrofloxacin composite nanogels could enhance the bioadhesion capacity of enrofloxacin for the SASCVs strain by adhesive studies. The minimum inhibitory concentration, minimum bactericidal concentration, minimum biofilm inhibitory concentration, and minimum biofilm eradication concentration were 2, 4, 4, and 8 ㎍/mL, respectively. The killing rate curve had a concentration-dependent bactericidal effect as increasing drug concentrations induced swifter and more radical killing effects. Conclusions: This study provides a good tendency for developing enrofloxacin composite nanogels for treating cow mastitis caused by intracellular SASCVs and other intracellular bacterial infections.

Evaluation on Light Scattering Behavior of a Pulverized Coal Suspension (슬러리내 석탄입자의 광산란 특성 평가)

  • Hwang, Munkyeong;Nam, Hyunsoo;Kim, Kyubo;Song, Juhun
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.5
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    • pp.451-460
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    • 2013
  • In a direct coal fuel cell (DCFC) system, it is essential to identify volume fraction of coal suspended in electrolyte melt in order to control its dispersion and fluidity. This requirement is compelling especially at anode channel where hot slurry is likely to flow at low velocity. In this study, light scattering techniques were employed to measure the volume fraction for a pulverized coal suspension with relatively high absorption coefficient. The particle size, scattering angle, and volume fraction were varied to evaluate their effects on the scattering behavior as well as scattering regime. The larger coal size and smaller forward scattering angle could provide a shift to more favorable scattering regime, i.e., independent scattering, where interferences of light scattering from one particle with others are suppressed.

Control of morphology and interfacial tension of PC/SAN blends with compatibilizer

  • Kim, J.H.;Kim, M.J.;Kim, C.K.;Lee, J.W.
    • Korea-Australia Rheology Journal
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    • v.13 no.3
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    • pp.125-130
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    • 2001
  • Block copolymers of PC-b-PMMA (polycarbonate-b-polymethylmethacrylate) and PC -b-SAN (polycarbonate-b-(styrene-c-acrylonitrile)), were examined as compatibilizers for blonds of PC with SAN copolymer. The average diameter of the dispersed particles was measured with an image analyser, and the interfacial properties of the blonds were analysed with an imbedded fiber retraction (IFR) technique. The average diameter of dispersed particles and interfacial tension of the PC/SAN blends reached a minimum value when the SAN copolymer contained about 24 wt% AN. Interfacial tension and particle size were further reduced by adding compatibilizer to the PC/SAN blends. PC-b-PMMA was more effective than PC-b-SAN as a compatibilizer in reducing the average diameter of the dispersed particles and interfacial tension of PC/SAN blend. A direct proportionality between the particle diameter and interfacial tension was also observed. The interfacial properties of the PC/SAN blends were optimized by adding a block copolymer and using an SAN copolymer that had minimum interaction energy with PC.

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Synthesis and Nucleation Behavior of MoO3 Nano Particles with Concentration of Precursors (전구체 농도에 따른 MoO3 나노 분말 합성 및 핵생성 거동)

  • Lee, Seyoung;Kwon, Namhun;Roh, Jaeseok;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.27 no.5
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    • pp.394-400
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    • 2020
  • Molybdenum trioxide (MoO3) is used in various applications including sensors, photocatalysts, and batteries owing to its excellent ionic conductivity and thermal properties. It can also be used as a precursor in the hydrogen reduction process to obtain molybdenum metals. Control of the parameters governing the MoO3 synthesis process is extremely important because the size and shape of MoO3 in the reduction process affect the shape, size, and crystallization of Mo metal. In this study, we fabricated MoO3 nanoparticles using a solution combustion synthesis (SCS) method that utilizes an organic additive, thereby controlling their morphology. The nucleation behavior and particle morphology were confirmed using ultraviolet-visible spectroscopy (UV-vis) and field emission scanning electron microscopy (FE-SEM). The concentration of the precursor (ammonium heptamolybdate tetrahydrate) was adjusted to be 0.1, 0.2, and 0.4 M. Depending on this concentration, different nucleation rates were obtained, thereby resulting in different particle morphologies.

Novel Convenient Method to Determine Wettability and Dispersibility of Dairy Powders

  • Lee, Jeae;Chai, Changhoon;Park, Dong June;Lim, Kwangsei;Imm, Jee-Young
    • Food Science of Animal Resources
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    • v.34 no.6
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    • pp.852-857
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    • 2014
  • This study was carried out to develop a simple, convenient, and reproducible testing device to determine wettability and dispersibility of dairy powders. The testing device consists of a sieve ($150{\mu}m$) attached to a sample chamber, sensors mounted on a supporting body and a main control unit containing a display panel. The sensors detect the difference in electrical resistance between air and water. A timer is automatically triggered by the sensor when the bottom of sample-loaded chamber contacts water in the petri dish. Wettability and dispersibility of commercial skim milk powders (SMPs) produced at different heating strengths (low-, medium-, and high-heat SMP) are compared using the new testing device. Wettability of the SMPs were correlated with particle size and are found to increase in the order of medium-, low-, and high-heat SMP regardless of the amount of sample tested. Dispersibility of SMPs showed the same trend and high heat-SMP which has the smallest particle size resulted in the lowest dispersibility. Unlike existing methods, the new testing device can determine both wettability and dispersibility of powders and successfully detected differences among the samples.

Improved Clay Process for Builder-grade Zeolite Synthesis by Acidic Benification (광산 용출에 의한 Builder급 Zeolite점토 합성법)

  • 서정권;정필조
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.685-693
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    • 1988
  • From leaching of Korean native halloysite with hot sulfuric acid, active species of siliceous aluminosilicate are obtained as residue, which gives the mole ratio of SiO2/Al2O3 10 and substantially removes most acid-soluble impurities. By dissolving the residue in sodium hydroxide at an ambient temperature sodium silicate solution is prepared, this is used for zeolite synthesis as one of starting materials. In order to prepare zeolite Type 4A thereform, addition of a proper aluminum source is made so that the composition of the reactant materials may be of the following mole ratios : Na2O/SiO2=1.2-1.5, SiO2/Al2O3=1.8-2.0 and H2O/Na2O=34-45 By careful control of ageing time and temperature, subsequent crystal growth is induced into microfine zeolite 4A, which gives optimum particle size distributjion being suitable for detergent builder. The zeolite products thus obtained and highly competitive with those from the use of the refined clay in comparison of their calcium exchange capacity, whiteness and particle size distribution. The present method shows a marginal advantage over the existing procedures requiring neitherseparate purification nor calcinating otherwise necessary for the raw clay ores in use.

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Comparison of Bioleaching Kinetics of Spent Catalyst by Adapted and Unadapted Iron & Sulfur Oxidizing Bacteria - Effect of Pulp Density; Particle Size; Temperature

  • Pradhan, Debabrata;Kim, Dong-Jin;Ahn, Jong-Gwan;Gahan, Chandra Sekhar;Chung, Hun-Saeng;Lee, Seoung-Won
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.956-966
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    • 2011
  • Bioleaching studies of metals from a spent catalyst were conducted using both adapted and unadapted bacterial cultures. The bacterium used in this experiment was Acidithiobacillus ferrooxidans. A comparison of the kinetics of leaching was made between the two cultures by varying the leaching parameters, including the pulp density, particle size and temperature. Both cultures showed similar effects with respect to the above parameters, but the leaching rates of all metals were higher with the adapted compared to the unadapted bacterial cultures. The leaching reactions were continued for 240 h in the case of the unadapted bacterial culture, but only for 40 h in the case of the adapted bacterial culture. The leaching reactions followed first order kinetics. In addition, the kinetics of leaching was concluded to be a diffusion control model; therefore, the product layers were impervious.

Synthesis and Control of Ultrafine Particles by Ion-Injection in Furnace (반응로내 이온주입에 의한 초미세입자의 합성 및 응집제어)

  • Yoon, J.U.;Kim, Y.W.;Ahn, K.H.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.91-96
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    • 2001
  • Ultrafine particles have been widely used in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size $SiO_{2}$ particles are synthesized by the injection of TEOS vapor, ions and reaction gas in furnace. Ions were generated by Corona discharge electrode and these ions charge $SiO_{2}$ particles. As a result, spherical, nonagglomerated and ultrafine particles are generated in various conditions, it's morphology, charging portion and size distribution are examined by using TEM, ESP and SMPS. As the applied voltage of electrode changes from 0 kV to 5.0 kV, it is observed that the mean diameter of $SiO_{2}$ particle decreases from 94 nm to 42 nm.

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