• 대한원격탐사학회지
• /
• 제29권4호
• /
• pp.415-421
• /
• 2013

본 연구에서는 다파장 라만 라이다 시스템을 이용하여 대기 중의 비구형 순수 황사입자와 구형 오염 입자가 혼합된 황사 입자의 단산란 알베도를 산출할 수 있는 방법론을 제시하고, 실제 대기 관측 사례 분석 자료로부터 정확도를 검증하고자 하였다. 편광소멸도는 황사와 비황사와의 혼합정도에 반비례함을 응용하여 편광소멸도 값으로부터 황사비를 산출하고 이를 이용하여 황사와 비황사로 황사층을 구분하였다. 산출된 비황사의 두 파장(355, 532 nm)의 소산계수와 세 파장(355, 532, 1064 nm)의 후방산란계수를 이용하여 역행렬 분석을 수행하여 비황사의 고도별 단산란알베도를 도출하였다. 황사와 비황사의 가중치를 소산계수값으로부터 산출하고 각 가중치를 황사와 비황사에 적용하여 황사 층 전체의 고도별 단산란알베도를 산출하였다. 단, 황사의 단산란알베도는 순수황사로 가정하여 발원지에서 측정된 순수황사가 나타내는 0.96의 값을 적용하였다. 본 연구로부터 개발된 분석방법은 기존의 원격탐사 기술의 한계점을 극복하여 황사의 이동시 타 오염입자와의 혼합에 따른 광학적 특성의 변화에 대한 정밀한 자료를 제공할 수 있을 것으로 기대된다.

• 지구물리와물리탐사
• /
• 제25권4호
• /
• pp.214-216
• /
• 2022

분포형 음향 센싱(distributed acoustic sensing, DAS)은 광섬유 케이블을 수신기로 활용하는 탐사기술로서, 석유탐사 및 지진분야에서 모니터링 목적으로 활발히 적용되고 있다. 최근에는 지하매질의 물성정보를 도출하기 위해 분포형 음향 센싱 자료를 활용한 전파형역산 연구가 수행되고 있다. 분포형 음향 센싱은 광섬유 케이블 상의 두 점 간의 위상 차이에 의한 변형률을 측정하기 때문에, 기존 전파형역산 알고리즘에 직접 활용하기 어렵다. 분포형 음향 센싱 자료를 전파형역산에 활용하기 위해, 본 연구에서는 평면파 가정에서의 변형률과 수평입자속도의 관계식을 이용한 평면파 전파형역산 알고리즘을 개발하였다. 수치실험을 통해 평면파 가정에서의 변형률과 입자속도 간의 관계식이 성립함을 확인하였다. 다양한 탐사환경에서 분포형 음향 센싱 자료에 대한 전파형역산의 적용 가능성을 확인하기 위해, 육상 및 해저면 탄성파 탐사 환경을 모사한 4층 및 수정된 Marmousi-2 속도모델을 이용하였다. 제안된 전파형역산을 통해 육상 및 해저면 탄성파 탐사 환경하에서 P파 및 S파 속도구조를 정확히 도출할 수 있었다.

• Elastomers and Composites
• /
• 제31권5호
• /
• pp.327-334
• /
• 1996

A correlative analysis has been carried out to predict the average particle size of rubber dispersed phase In high impact polystyrene manufactured by bulk polymerization. To do the correlation, a mechanistic model suggested previously by the author was used for describing the size of stabilizing particles agitated under the turbulent viscous shear subranges in a prepolymerization reactor, where the rubber particles were assumed to be formed at the time of phase inversion in the reactor. Viscosities required for the model were postulated to describe the overall behavior of butadiene rubber and polystyrene mixture along the wide range of conversion. The good agreement between the model and the experimental data from a plant was quite satisfactory for the prediction of the average rubber particle size of high impact polystyrene.

• 한국환경과학회지
• /
• 제21권7호
• /
• pp.815-824
• /
• 2012

The purpose of this study was to analyze the meteorological characteristics of wintertime high PM10 concentration episodes in Busan. $PM_{10}$ concentration has been reduced for the past four years and recorded near or exceeded 100 ${\mu}g/m^3$ (national standard of $PM_{10}$). High concentration episodes in Busan were 6 case, $PM_{2.5}/PM_{10}$ ratio was 0.36~0.39(mean 0.55). High $PM_{10}$ concentration occurred during higher air temperature, more solar radiation and sunshine, lower relative humidity, and smaller cloud amount. Synoptically, it also occurred when Busan was in the center or the edge of anticyclone and when sea breeze intruded. An analysis of upper air sounding showed that high $PM_{10}$ concentration occurred when surface inversion layer and upper subsidence inversion layer existed, and when boundary layer depth and vertical mixing coefficient were low. An analysis of backward trajectory of air mass showed that high $PM_{10}$ concentration was largely affected by long range transport considering that it occurs when air mass is intruded from China.

• 한국입자에어로졸학회지
• /
• 제9권3호
• /
• pp.133-137
• /
• 2013

Measuring particle size distribution is one of the primary concerns in aerosol studies. For a nano-particle size distribution measurement, many scientists use a combination of a differential mobility analyzer (DMA) and a condensation particle counter (CPC) system, which is a called scanning mobility particle sizer (SMPS). Although it has a very high particle size resolution, some issues still remain. These problems include residence time between a DMA and a CPC, discontinuity of a CPC, and disturbance due to long scanning time during the precise measurement of particles. In particular, long scanning time is not adequate for measuring particle size distribution since the particle concentration is changing during the measurement. In this study, we developed radial exhaust multi-port system (REM-system) with no scanning time and high resolution to measure real-time particle size distribution. As a result of the REM-system performed using mono-disperse particle, it is expected that this system will be suitable for measuring continuously changing aerosol. If the counting efficiency of multi-condensation particle counter (M-CPC) and data inversion matrix are completed, REM-system will be a very adequate system for unsteady aerosol, which changes for SMPS scanning time.

• 한국응용과학기술학회지
• /
• 제30권4호
• /
• pp.602-611
• /
• 2013

We have investigated the influence of system composition and preparation conditions on the particle size of vitamin E acetate (VE)-loaded nanoemulsions prepared by PIC(phase inversion composition) emulsification. This method relies on the formation of very fine oil droplets when water is added to oil/surfactant mixture. The oil-to-emulsion ratio content was kept constant (5 wt.%) while the surfactant-to-oil ratio (%SOR) was varied from 50 to 200 %. Oil phase composition (vitamin E to medium chain ester ratio, %VOR) had an effect on particle size, with the smallest droplets being formed below 60 % of VOR. Food-grade non-ionic surfactants (Tween 80 and Span 80) were used as an emulsifier. The effect of f on the droplet size distribution has been studied. In our system, the droplet volume fraction, given by the oil volume fraction plus the surfactant volume fraction, was varied from 0.1 to 0.3. The droplet diameter remains less than 350 nm when O/S is fixed at 1:1. The droplet size increases gradually as the increasing the volume fraction. Particle size could also be reduced by increasing the temperature when water was added to oil/surfactant mixture. By optimizing system composition and homogenization conditions we were able to form VE-loaded nanoemulsions with small mean droplet diameters (d < 50 nm). The PIC emulsification method therefore has great potential for forming nanoemulsion-based delivery systems for food, personal care, and pharmaceutical applications.

• KSBB Journal
• /
• 제16권2호
• /
• pp.115-122
• /
• 2001

Molecular imprinting has now been established as a technique which allows the creation of tailor-made binding sites for many classes of compounds. MIPs were prepared by covalent and non-covalent chemical bonding systems, by interactions between functional monomer and template. The shape of MIP is divided to particle and membrane. MIP membranes can be prepared by surface imprinting, in-situ polymerization, wet phase inversion and the dry phase inversion method. MIPs have been mainly used for analytical separation and biosensor systems to separate and detect chiral compounds and materials with similar structures. However the application of MIP by the chemical industries is still in its infancy stages. This review summarizes the preparative characteristics and applications of MIP with respect to chiral separations and biosensors.

• KSBB Journal
• /
• 제29권5호
• /
• pp.385-391
• /
• 2014

In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

• 폴리머
• /
• 제26권3호
• /
• pp.307-315
• /
• 2002

폴리스티렌의 취약한 성질을 개선한 내충격정 폴리스티렌 (HIPS)의 내충격성에 영향을 주는 요소는 분산된 고무상 입자의 크기 및 입도분포, 분자량, 형태구조, 그래프트율 등이다. 이에 따라 HIPS의 물성은 영향을 받으므로 이를 조절하거나 파악하는 것은 중요하다. 본 연구에서는 HIPS의 벌크-용액중합에서 용매함량이 고무입자의 형태구조 및 입도분포, 최종 물성에 미치는 영향에 대하여 고찰하였다. 먼저 중합 진행에 따른 분산상의 입도분포를 측정함으로써 상역전 현상의 변화 추이를 파악하여 전중합 시간을 결정하였다. 중합시 분산용매는 적절한 양에 도달하기 전까지는 고무입자의 크기가 증가하였으며, 그 후에는 점차적으로 감소하였다. 고무상의 형태구조는 분산용매가 증가함에 따라서 그래프트율이 증가하는 형태구조로 바뀌는 것으로 사료된다. 분산용매가 첨가됨에 따라 유변물성 및 인장물성이 취약해졌는데, 이는 분산용매에 의한 사슬이동반응이 매트릭스상인 폴리스티렌의 분자량을 감소시킨 점과 잔류 용매의 존재 때문이었다. 하지만 내충격성은 분산입자의 크기가 증가한 경우 향상되는 경향을 보였다.

• 접착 및 계면
• /
• 제11권1호
• /
• pp.9-14
• /
• 2010

유화제로 UNIQ-1 (isopropylamine alkyl aryl sulphonate)과 UNIQ-2 (alkoxylated glycol ether)를 혼합사용 하고, 오일 상으로 도료용 수지로 사용되는 유장 45% 알키드 수지를 사용하여 전상유화법으로 o/w 에멀젼을 제조하였다. 에멀젼 제조과정에서 HLB, 교반속도, 제조 온도가 입자크기에 미치는 영향을 조사하였으며, 입자크기는 HLB 값의 영향을 크게 받는 것으로 나타났다. 또한, 저장온도 및 자연광에 대한 안정성을 평가하였다. 최종적으로 제조된 에멀젼의 평균 입자 크기는 193 nm 이었으며, 기존 유성 수지에 비해 VOC 사용량을 90% 절감하였다.