• 한국분말재료학회지
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• 제31권2호
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• pp.163-168
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• 2024

As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 ℃ and hydrogen partial pressure above 0.5 atm, Ni and Li₂O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H₂O, and Li₂CO₃, with about 0.02 wt% Al as an impurity.

• 스마트미디어저널
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• 제3권1호
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• pp.39-45
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• 2014

제곱연산은 승수와 피승수가 동일한 곱셈의 특수한 경우로 병렬 제곱기의 부분곱 행렬에서 부분곱 비트들은 대칭을 이룬다. 이런 특성을 이용하여 부분곱을 폴딩(folding), 쉬프트, 재배열하여 부분곱 비트의 수와 부분곱 행렬의 최대높이들 감소시킨다. 본 논문에서는 제어신호에 따라 unsigned와 signed 제곱기로 동작하는 겸용 제곱기의 효율적인 설계 방법을 제안한다. 기존 겸용 제곱기와 달리 자리수(weight)가 다른 특정 부분곱 비트들의 덧셈에 대해 덧셈기를 사용하지 않고 계산하는 방법을 제안한다. 시뮬레이션을 통해 제안한 겸용 제곱기는 기존 겸용 제곱기와 비교하여 면적은 약 18%, 지연시간(propagated delay time)은 약 11%, 전력소모는 약 9% 감소시킬 수 있음을 보인다.

• 한국기후변화학회지
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• 제7권3호
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• pp.231-236
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• 2016

Electrocatalytic reduction can produce useful chemicals and fuels such as carbon monoxide, methane, formate, aldehydes, and alcohols using carbon dioxide, the green house gas, as a reactant through the supply of electrical energy. In this study, tin-lead (Sn-Pb) alloy electrodes are fabricated by electrodeposition on a carbon paper with different alloy composition and used as cathode for electrocatalytic reduction of carbon dioxide into formate in an aqueous system. The prepared electrodes are measured by Faradaic efficiency and partial current density for formate production. Electrocatalytic reduction experiments are carried out at -1.8 V (vs. Ag/AgCl) using H-type cell under ambient temperature and pressure and the gas and liquid products are analyzed by gas chromatograph and liquid chromatograph, respectively. As results, the Sn-Pb electrodes show higher Faradaic efficiency and partial current density than the single metal electrode. The Sn-Pb alloy electrode which have Sn:Pb molar ratio=2:1, shows the highest Faradaic efficiency of 88.7%.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2005년도 추계종합학술대회
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• pp.949-952
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• 2005

We propose the hardwired distributed arithmetic which is applied to multiple constant multiplications and the fixed data path in the inner product of fixed coefficient as a result of variable radix-2 multi-bit coding. Variable radix-2 multi-bit coding is to reduce the partial product in constant multiplication and minimize the number of addition and shifts. At results, this procedure reduces the number of partial products that the required multiplication timing is shortened, whereas the area reduced relative to the DA architecture. Also, this architecture shows the best performance for DCT/IDCT and DWT architecture in the point of area reduction up to 20% from reducing the partial products up to 40% maximally.

• 전자공학회논문지
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• 제50권3호
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• pp.50-58
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• 2013

본 논문에서는 제한된 범위의 Signed-Digit number 인코딩과 축약 단계를 이용한 고정소수점 병렬 십진 곱셈기를 제안한다. 제안한 병렬 십진 곱셈기는 승수와 피승수를 제한된 범위의 SD number로 인코딩하여 캐리 전달 지연 없이 빠르게 부분곱을 생성한다. 인코딩에 사용하는 숫자의 범위를 줄임으로써 SD number 다중 피연산자 덧셈의 한번에 연산 가능한 피연산자의 개수가 늘어나게 되고, 이에 따라 부분곱 축약 단계의 연산을 빠르게 수행 할 수 있다. 제안한 병렬 십진 곱셈기의 성능 평가를 위해 Design Compiler에서 SMIC사의 180nm CMOS 공정 라이브러리를 이용하여 합성한 결과 기존의 Signed-Digit number를 이용한 병렬 십진 곱셈기보다 전체 지연시간은 4.3%, 전체 면적은 5.3% 감소함을 확인 하였다. 전체 지연시간 및 면적에서 부분곱 축약 단계가 차지하는 비중이 가장 크므로 부분곱 생성 단계에서 약간의 지연시간 및 면적 증가가 있음에도 불구하고 전체 지연시간과 면적이 감소하는 결과를 얻을 수 있다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.631-635
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• 2000

Recently, the epoxy molded type PT for indoor and applied 25.8kV was often distroyed by degradation of insulation that effected many electric stress and defect of manufactured goods. therefore In this work, We can present a method of solution in the process of produce the PT through analysis of experiments. In order to reduce the PD (Partial Discharge) which was occurred at the insulation material of epoxy resin, we has many tried to remove faults In the process of the products,

• Bulletin of the Korean Chemical Society
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• 제15권2호
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• pp.132-138
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• 1994

Bis(diethylamino)aluminum hydride was utilized in a systematic study of the approximate rates and stoichiometry of the reaction of excess reagent with 55 selected organic compounds containing representative functional groups under standardized conditions (THF, $0^{\circ}C$, reagent to compound=4 : 1) in order to define the characteristics of the reagent for selective reductions. The reducing action of BEAH was also compared with that of the parent aluminum hydride. The reducing action of the reagent is quite similar to that of aluminum hydride, but the reducing power is much weaker. Aldehydes and ketones were readily reduced in 1-3 h to the corresponding alcohols. However, unexpectedly, a ready involvement of the double bond in cinnamaldehyde was realized to afford hydrocinnamyl alcohol. The introduction of diethylamino group to the parent aluminum hydride appears not to be appreciably influential in stereoselectivity on the reduction of cyclic ketones. Both p-benzoquinone and anthraquinone utilized 2 equiv of hydride readily without evolution of hydrogen, proceeded cleanly to the 1,4-reduction products. Carboxylic acids and acid chlorides underwent reduction to alcohols slowly, whereas cyclic anhydrides utilized only 2 equiv of hydride slowly to the corresponding hydroxylacids. Especially, benzoic acid with a limiting amount of hydride was reduced to benzaldehyde in a yield of 80%. Esters and lactones were also readily reduced to alcohols. Epoxides examined all reacted slowly to give the ring-opened products. Primary and tertiary amides utilized 1 equiv of hydride fast and further hydride utilization was quite slow. The examination for possibility of achieving a partial reduction to aldehydes was also performed. Among them, benzamide and N,N-dimethylbenzamide gave ca, 90% yields of benzaldehyde. Both the nitriles examined were also slowly reduced to the amines. Unexpectedly, both aliphatic and aromatic nitro compounds proved to be relatively reactive to the reagent. On the other hand, azo- and azoxybenzenes were quite inert to BEAH. Cyclohexanone oxime liberated 1 equiv of hydrogen and utilized 1 equiv of hydride for reduction, corresponding to N-hydroxycyclohexylamine. Pyridine ring compounds were also slowly attacked. Disulfides were readily reduced with hydrogen evolution to the thiols, and dimethyl sulfoxide and diphenyl sulfone were also rapidly reduced to the sulfides.

• 한국수소및신에너지학회논문집
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• 제13권2호
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• pp.119-126
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• 2002

The methanol partial oxidation using commercial $CuO/ZnO/Al_2O_3$ catalysts in a plug flow reactor was studied in the temperature range of $200{\sim}250^{\circ}C$ at atmospheric pressure, It was achieved the high activities by Cu-based catalysts and the selectivity of $CO_2$/$H_2$ was 100% when $O_2$ was fully convened. The reactivity changes and their hysteresis with increasing/decreasing temperatures were observed due to the chemical state differences between the oxidation and the reduction on the Cu surface, It was suggested as the two-step reaction: the complete oxidation and the following steam reforming for methanol, which was indicated by the distributions of final products vs. the residence time. In addition, the complete oxidation step was shown to be extremely fast and the total reaction rate can be controlled by the steam reforming reaction.

• Bulletin of the Korean Chemical Society
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• 제15권8호
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• pp.644-649
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• 1994

The approximate rates and stoichiometry of reaction of excess dipyrrolinoaluminum hydride (DPAH) with selected organic compounds containing representative functional groups under standardized conditions (tetrahydrofuran, 0, reagent : compound=4 : 1) were examined in order to define the characteristics of the reagent for selective reductions. The reducing ability of DPAH was also compared with that of bis(diethylamino)aluminum hydride (BEAH). The reagent appears to be stronger than BEAH, but weaker than the parent reagent in reducing strength. DPAH shows a unique reducing characteristics. Thus, the reagent reduces aldehydes, ketones, esters, acid chlorides, epoxides, and nitriles readily. In addition to that, ${\alpha},\;{\beta}$-unsaturated aldehyde is reduced to the saturated alcohol. Quinone are reduced cleanly to the corresponding 1,4-reduction products. The examination for possibility of achieving a partial reduction to aldehydes was also performed. Both primary and tertiary aromatic carboxamides are converted to aldehydes with a limiting amount of DPAH. Finally, disulfides and sulfoxides are readily reduced to thiols and sulfides, respectively.

• 전기학회논문지
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• 제57권4호
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• pp.625-628
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• 2008

Ba-Zn ferrite powders for electromagnetic insulator were synthesized by self-propagating high-temperature synthesis(SHS) with a reaction of $xBaO_2+(1-x)ZnO+0.5Fe_2O_3+Fe{\rightarrow}Ba_xZn_{1-x}Fe_2O_4$. In this study, phase indentification of SHS products was carried out by using x-ray diffractometry and quasi-nano sized Ba-Zn powders were prepared by a pulverizing process. SHS mechanism was studied by thermodynamical analysis about oxidation reaction among $BaO_2,\;ZnO,\;Fe_2O_3$, and Fe. As oxygen pressure increases from 0.25 MPa to 1.0 MPa, the SHS reactions occur well and make clearly the SHS products. X-ray analysis shows that final SHS products formed with the ratio of $BaO_2/ZnO$ of 0.25, 1.0 and 4.0, are mainly $Ba_xZn_{1-x}Fe_2O_4$. Based on thermodynamical evaluation, the heat of formation increases in the order of $ZnFe_2O_4,\;BaFe_2O_4$, and $Ba_xZn_{1-x}Fe_2O_4$. This supports that $Ba_xZn_{1-x}Fe_2O_4$ phase is predominately formed during SHS reaction. The SHS reactions to form $Ba_xZn_{1-x}Fe_2O_4$ depends on oxygen partial pressure, and the heat of formation during the SHS reaction. The SHS reactions tends to occur well with increasing the oxygen partial pressure and BaO2/ZnO ratio in the reactants This means that the SHS reaction for the formation of Ba-Zn ferrite includes the reduction of BaO2/ZnO and the oxidation of Fe. $Ba_xZn_{1-x}Fe_2O_4$ powders after pulverizing is agglomeratedwith a size of about $50{\mu}m$, in which quasi-nano sized particles with about 300nm are present.