• The Korean Journal of Ceramics
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• 제4권2호
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• pp.114-121
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• 1998

Using Hebb-Wagner's asymmetric cell, partial conductivities of holes and electrons in yttria stabilized zirconia doped with 10 mol% TiO2 have been estimated by a dc polarization measurement. The current interrruption method and ac impedance measurements have been also made to evaluate the ionic conductivity and to examine the consistency of the partial conductivities. Partial conductivities of electrons(σn) and holes (σp) were found to be pro-peortional to -1/4 and 1/4 power of partial pressure of oxygen gas, respectively, except for σn at reducing conditions. In comparison with 5 mol% doped YSZ, σn was found to increase with the increase of TiO2 concentration, but σp stayed at almost a constant value.

• 한국전산구조공학회논문집
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• 제20권1호
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• pp.9-18
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• 2007

본 연구에서는 위상최적화 알고리즘의 수렴성을 개선하기 위해 설계영역에 초기 구멍을 도입하는 방법을 제시하는데, 이것은 경계면에 기초한 최적화 방법의 느린 수렴성을 완화하기 위해, Eschenauer et al.에 의해 고안된 버블 방법의 설계영역 안에 구멍을 도입하는 개념과 연계된다. 버블 방법과 달리, 제안된 방법에서는 최적화 과정동안 구멍의 위치를 정의하는 특성함수를 이용하지 않고, 최적화 초기화 단계에서만 초기 구멍을 도입하는데, 이러한 초기 설계영역 안의 솔리드와 보이드 영역들은 고정되는 것이 아니라 합쳐지거나 쪼개지면서 변화된다. 따라서 위상최적화 알고리즘에서 구멍의 이동에 관련된 복잡한 수치적인 계산 없이 자동적으로 설계변수의 유한변화를 더욱 강화시키기 때문에 목적함수 값의 수렴성을 개선할 수 있다. 본 논문에서는 다양한 치수와 형상의 구멍을 포함하는 초기 설계영역을 가지는 Michell형 보의 위상 최적설계를 밀도분포법으로 불리는 SIMP를 이용하여 수행하였다. 이를 통해 위상최적화의 수렴성을 개선하고 최적위상과 형상에 영향을 미치는 초기 구멍의 효과를 검증하였다.

• The Korean Journal of Ceramics
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• 제6권2호
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• pp.150-154
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• 2000

Mobilities of electrons ($\mu_p$) and holes ($\mu_p$) in 2, 5, and 10 mol% $TiO_2$-doped yttria stabilized zirconia (TD-YSZ) have been estimated by a non-steady state gas permeation method using models proposed by Weppner and Maruyama. Values of $\mu_n$ and $\mu_p$ were found to be closed to those in non-doped YSZ reported earlier. The concentration of electrons and holes were calculated from $\mu_n$ and $\mu_p$ values and the partial conductivities of electrons and holes measured by a dc-polarization method. The concentration of electrons at unit oxygen partial pressure increased with increasing $TiO_2$concentration, while the hole concentration was almost independent of $TiO_2$concentration.

• 한국세라믹학회지
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• 제37권3호
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• pp.271-279
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• 2000

5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

• Steel and Composite Structures
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• 제38권4호
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• pp.399-414
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• 2021

This paper aims to verify the feasibility of rubber rings to mitigate the shear concentration in perfobond connector (PBL) groups. Firstly, modified push-out tests for five specimens with four holes were conducted to investigate the effects of rubber rings on the shear mechanism of PBL groups. The test results showed that by employing rubber rings on partial holes, more shear forces were distributed to the holes without rubber rings. The rubber rings significantly improved the slip ability of the specimens, and the ductility of PBL groups is dependent on the number and thickness of rubber rings. Subsequently, three-dimensional numerical models were established and validated by the experimental results. According to the plastic strain distribution in concrete dowels, the action principle of rubber rings in PBL groups was explained. Furthermore, the parametric study was conducted to investigate the influential factors on shear distributions, including the width of steel plates, the hole spacing, the number of holes, the rubber ring thickness, and the positions of rubber rings. The parametric analysis results showed that the redistribution of shear forces is significantly affected by the rubber rings with the smallest thickness. By properly employing rubber rings in PBL groups, the shear forces of holes are more even. Finally, an analytical model for PBL groups with rubber rings was proposed to predict the shear distribution at the serviceability stage.

• 한국가스학회지
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• 제24권4호
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• pp.25-31
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• 2020

산업용 혹은 발전용 가스터빈에 사용되는 이중 콘형 예혼합 연소기의 연소 특성을 이해하기 위하여 실험적 연구를 수행하였다. 노즐의 여러 연료 분사 방식에 대하여 NOx와 CO의 배출 특성, 화염 안정성 및 연소실 온도 분포에 대한 연소특성을 비교하였다. 주 연구 결과로는 연료홀 개수가 동일하고 연료 홀 직경이 감소하는 경우와 연료 홀면적이 동일하고 연료 홀 수가 감소되는 경우 연료의 연소용 공기층 침투가 커지기 때문에 NOx의 배출은 감소하지만 화염 안정성은 감소하게 된다. 그리고 동일 연료 홀 면적을 이용하는 분사방식에 있어서 연료 홀을 교차 변경하는 경우 연료의 평균 침투거리 증가로 NOx의 배출이 감소되며 연료 침투거리가 적은 연료가 화염을 안정화시키는 역할을 한다.

• 한국세라믹학회지
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• 제52권5호
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• pp.299-303
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• 2015

The electrolyte is an important component in determining the performance of Fuel Cells. Especially, investigation of the conduction properties of electrolytes plays a key role in determining the performance of the electrolyte. The electrochemical properties of Yttrium stabilized zirconia (YSZ) were measured to allow the use of this material as an electrolyte for solid oxide fuel cells (SOFC) in the temperature range of $700-1000^{\circ}C$ and in $0.21{\leq}pO_2/atm{\leq}10^{-23}$. A Hebb-Wagner polarization experimental cell was optimally manufactured; here we discuss typical problems associated with making cells. The partial conductivities due to electrons and holes for 8YSZ, which is known as a superior oxygen conductor, were obtained using I-V characteristics based on the Hebb-Wagner polarization method. Activation energies for holes and electrons are $3.99{\pm}0.17eV$ and $1.70{\pm}0.06eV$ respectively. Further, we calculated the oxygen ion conductivity with electron, hole, and total conductivity, which was obtained by DC four probe conductivity measurements. The oxygen ion conductivity was dependent on the temperature; the activation energy was $0.80{\pm}0.10eV$. The electrolyte domain was determined from the top limit, bottom limit, and boundary (p=n) of the oxygen partial pressure. As a result, the electrolyte domain was widely presented in an extensive range of oxygen partial pressures and temperatures.

• ETRI Journal
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• 제42권2호
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• pp.282-291
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• 2020

The study reports on the design and performance of two air-filled and two partial ethanol-filled photonic crystal fiber (PCF) structures with a tetra core for supercontinuum generation. The PCFs are nonlinear with ultra-flattened zero dispersion. Holes with smaller areas are used to create a tetra-core PCF structure. Ethanol is filled in the holes of smaller area while the larger holes of cladding region are airfilled. Optical properties including dispersion, effective mode area, confinement loss, normalized frequency, and nonlinear coefficient of the designed PCF structures are investigated via full vector finite difference time domain (FDTD) method. A PCF structure with lead silicate as wafer exhibits significantly better results than a PCF structure with silica as wafer. However, both structures report dispersion at a telecommunication wavelength corresponding to 1.55 ㎛. Furthermore, the PCF structure with lead silicate as wafer exhibits a very high nonlinear coefficient corresponding to 1375 W^-1 km^-1 at the same wavelength. This scheme can be used for optical communication systems and in optical devices by exploiting the principle of nonlinearity.

• The Korean Journal of Ceramics
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• 제5권3호
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• pp.288-295
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• 1999

Partial conductivities contributed by electron holes, oxygen ions, and protons were caluclated in $SrZr_{0.95}Y_{0.05}O_{2.975}$, using the reported formulae derived from the defect chemistry of HTPCs. Required parameters were obtained from the graphical analysis of total conductivity variation against partial pressure of water vapor and oxygen. Predicted overall conductivities showed a reasonable agreement with experimental measurements. The conductivity of the material showed a linear increase with square root of the water vapor pressure. This increase was due to proton conduction in an almost pure ionic conductivity. The calculation of partial conductivities at $800^{\circ}C$ resulted in an almost pure ionic conductivity at $P_{02}=10^{-10}$ atm and a predominant hole conductivity at $P_{02}=10^{-10}$ atm. Pure proton conduction was not expected at this temperature, contrary to the earlier reports. Discussions were made in relation with reported thermodynamic data and defect structure of the material. It was shown that from the total conductivity dependence on water vapor pressure, the pure ionic conductivity at low oxygen partial pressures could be separated into protonic and oxygen ionic conductivity in $ZrO_2$-based HTPCs.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.223-227
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• 2003

The method of flame hole dynamics is demonstrated as a mean to simulate turbulent flame extinction. The core of the flame hole dynamics involves derivation of a random walk mapping for the flame holes, created by local quenching, between the burning and quenched states provided that the dynamic characteristics of flame edges is known. Then, the random walk mapping is projected to a background turbulent field. The numerical simulations are carried out with the further simplifications of flame string and unconditioned scalar dissipation rate. The simulation results show how the chance of partial quenching is influenced by the crossover scalar dissipation rate. Finally, a list of improvements, necessary to achieve more realistic turbulent flame quenching simulation, are discussed.