• Title/Summary/Keyword: papermaking additives

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A Study on the Accumulation Phenomena of Oxidized Starch in White Water of closed Fine Papermaking Process (Part 2) -Effect of broke use ratio and surface sizing pick up- (백상지 공정 폐쇄화에 따른 백수 내 산화전분의 축적 현상에 관한 연구 (제2보) -파지혼합비율 및 표면사이징 픽업량 변화의 영향-)

  • Ahn, Hyun-Kyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.3
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    • pp.35-43
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    • 2004
  • Reduction of fresh water consumption and effluent discharge provide diverse advantages in raw materials and energy savings. Papermaking system closure, however, reduces the efficiency of additives, decreases retention and dewatering, and causes many other Problems in papermaking. Accumulation of inorganic and organic substances in the process white water is the prime cause of these problems. Understanding of the accumulation phenomena of the detrimental substances in the papermaking process is of great importance for papermaking system closure. In this study a process simulation method was employed to analyze the accumulation phenomena of anionic starch in the process white water as the reuse rate of dry broke and pick up of surface sizing agent is increased. Steady state simulation studies were carried out based on the model developed in previous study. The variation of dissolved starch concentration in each process unit was monitored as a function of reuse rate of dry broke and surface sizing agent pick up rate. The result showed that dissolved starch concentration Increased as reuse rate of dry broke and surface sizing agent pick up rate was increased.

Exploration of retention system for papermaking system closure (제지공정의 무방류화를 위한 보류시스템 탐색)

  • 이학래;함충현;이지영;황남선;이상길;김종민
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.1-7
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    • 2001
  • Use of high yield pulp and recycled fiber as raw materials and water system closure result in higher fines content and buildup of organic and inorganic contaminants in white water. These are detrimental for the effectiveness of chemical additives including retention aids. Thus it is imperative to employ a retention systems that maintains its efficiency in closed papermaking system for reducing fresh water consumption. The performance of four different microparticle retention systems including cationic polyacrylamide (C-PAM)/bentonite, highly charged cationic starch (HCS)/silica, C-PAM/micropolymer, cationic guar gum (CGG)/silica was evaluated and compared at three different levels of papermaking system closure. Buildup of detrimental substances in a closed white water system increased cationic demand and finally reduced the performance of retention systems. Cationic starch and guar gums maintained their effectiveness in retention in closed white water systems contaminated with anionic trashes because of their structural rigidity and hydrogen bonding ability. Particularly, cationic guar gums, due its stiffness of molecular structure, appeared perform better than catinonic starch.

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Novel Biocide Controls Biofilm Formation without Adversely Affecting the Papermaking Process

  • Bharti, Shashank;Kim, Hyung-Ju;Kim, Ik-Dong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.67-71
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    • 2006
  • Strong oxidizing biocides are commonly used to control biofilm formation in alkaline papermaking systems. However, paper streams contain many substances that react with or consume oxidizers (e.g., fiber and starch, Therefore, to achieve effective microbiological control, the oxidizer must be overfed to overcome the effect of these substances. When dosed in this manner, the oxidizer can cause many unwanted reactions and adverse side effects, including the consumption of costly papermaking additives increased corrosion rates, and reduced felt life. Some oxidizers also contribute to the formation of halogenated organic compounds. When used for biofilm control, strong oxidizers can cause more problems than they remedy. A patented biocide that effectively controls biofilm without the adverse side effects associated with strong oxidizing biocides is available from Hercules. $Spectrum^{(R)}$ XD3899 Ammonium Bromide Technology, which can be described as a mild oxidizer, is currently used on more than 300 machines globally and has resulted in numerous production and/or machine efficiency records since its introduction in 2001.

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A Study on the Accumulation Phenomena of Oxidized Starch in White Water in Closed Fine Papermaking Process (Part 1) -Effect of Papermaking system closure- (백상지 공정 폐쇄화에 따른 백수 내 산화전분의 축적 현상에 관한 연구 (제1보) -공정 폐쇄화의 영향-)

  • Ahn, Hyun-Kyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.3
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    • pp.15-34
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    • 2004
  • Diverse benefits such as reduction of fresh water consumption and effluent discharge, efficient use of raw materials and energy savings can be obtained by papermaking system closure. Closure of papermaking processes, however, causes many problems including reduction of the efficiency of additives, decrease of retention and dewatering, felt plugging, poor Paper quality, generation of slime and odor, poor vacuum efficiency, etc, and it has been recognized that accumulation of Inorganic and organic substances in the process white water is the prime cause of these problems. Therefore, technological developments for preventing accumulation of these detrimental substances are urgently required for Implementing papermaking system closure. Understanding of the accumulation phenomena of the inorganic and organic substances in the papermaking process white water is prerequisite for papermaking system closure. In this study a process simulation method was used to analyze the accumulation phenomena of anionic starch In the process white water as the closure level of a fine paper making process is increased. A pilot paper machine was used as a model process. Starch adsorption and desorption models were developed based on the concept of starch adsorption ratio, which was not considered in previous studies. Steady state simulation studies were carried out based on this model using a commercial simulator. In steady state simulation, the variation of dissolved starch concentration in each process unit was monitored as a function of white water usage for wire shower. The result of the steady state simulation showed that dissolved starch concentration and its increase ratio in Process units increased as white water usage ratio for wire shower increased.

A Study on Applicability of Citrus Sludge for the Manufacture of Corrugated Medium (골심지 제조를 위한 감귤 착즙 슬러지의 적용성 평가)

  • Lee, Tai-Ju;Kim, Hyoung-Jin;Lee, Chang-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.5
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    • pp.47-53
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    • 2010
  • It is important to utilize the citrus sludge in terms of the reuse of waste materials in the manufacture of corrugated medium. Especially, the mandarin industry occupies the first place in Jeju province. In this paper, the application of citrus sludge mixed with KOCC recycled fibers into the manufacture of corrugated medium was studied. The citrus sludge was acidic in pH value. Also, the constituents of citrus sludge contain some short fibers, fines, and mucus which contain flavonoids, pectins and so on. In papermaking application, these components cause some troubles like foams, bad smell, fouling on the paper machine, and bad drainage and web breaks of wet web. The strength properties of handsheets prepared from KOCC and citrus sludge was decreased, compare to handsheets made of only KOCC. To compensate the problems on strength properties, some kinds of additives were tried to apply into papermaking wet-end system in laboratory scale. As a result, mixing conditions of alum, starch and anionic additives showed the best options in the recovery of strength properties and formations of corrugated medium.

Fundamental Study on Developing Lignocellulosic Fillers for Papermaking(I) (목질계 제지용 충전제 개발을 위한 기초연구(I))

  • Shin, Tae-Gi;Kim, Chul-Hwan;Chung, Ho-Kyung;Seo, Jung-Min;Lee, Young-Rok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.8-15
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    • 2008
  • Wastewoods (logging residues) generated in Korea were used to make lignocellulosic fillers for papermaking. Lignocellulosic fillers could play great roles to increase retention efficiency and thus decrease turbidity of white water in papermaking process. In addition, lignocellulosic fillers could be used to improve physical properties of paper through their high affinity to cellulosic fibers, leading to the less use of chemical additives like retention aids. Wastewoods including Pinus densiflora and Quercus variabilis were chemically and mechanically treated for making fine particles passing through 100 mesh wire. The newly generated fillers showed larger particle size distribution than ground calcium carbonates but similar distribution to talc. In particular, pretreatment by hot water was more effective to generate smaller particle size than by alkali treatment. Lignocellulosic particles mixed with ground calcium carbonates under intense hybridizing condition greatly contributed to surface coverage of organic fillers in addition to filling to lumen and pits.

Effect of the Ontamination of White Water Obtained from Paper Mill on Paper Strength (제지공정수 폐쇄화 수준이 수질 및 종이 물성에 미치는 영향)

  • Lee Hak Lae;Ham Choong Hyun;Lee Ji Young;Lee Sang Gil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.16-24
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    • 2004
  • The reduction of paper machine water usage is precursor to the water system closure of any mills. This reduction in water consumption reduces the loss of solids; especially fine particulates and their surface adsorbed chemical additives, from mills, which causes an inevitable increase of fine materials in papermaking systems. Also the reduction of paper machine water usage causes substantial increase of organic and inorganic substances in process water. The deterioration of the papermaking process water quality accompanying the reduction of papermaking system closure can be a prime source of the aggravation of paper quality and process efficiency. It is of great importance for paper mills to investigate the influence of the level of papermaking system closure on the paper properties and process runnabililty before implementing process closure. To predict the changes in paper properties at different levels of system closure, highly cotaminated white water was prepared using reverse osmosis technology and used to prepare handsheets from fine paper and newsprint stocks. Results showed that the quality of process water affects the strength. Preparation of highly contaminated process water and handsheet forming with headbox stocks provided important criteria to determine the relationship between the qualities of process water and paper products.

Interaction between Polyelectrolytes Layer-by-Layer Assembled Fibers and Fluorescent Whitening Agent (고분자전해질 LbL multilayering 처리된 섬유와 형광증백제와의 반응성)

  • Sim, Kyu-Jeong;Lee, Sung-Rin;Chin, Seong-Min;Ryu, Jae-Ho;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.4
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    • pp.71-77
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    • 2010
  • To utilize modified pulp fibers in papermaking system, it is necessary to evaluate the interaction between modified fibers and papermaking additives. Fluorescent whitening agent (FWA) is an important additive which has been widely used for production of writing and printing paper. We modified pulp fiber surface by Layer-by-Layer multilayering of polyelectrolytes, and investigated the interaction between these fibers and FWA used in internal addition or surface treatment. Pulp fiber with cationic surface charge showed a good affinity to internal FWA. For FWA in surface sizing agent, whiteness and brightness of paper was dependent on pickup weight and polyelectrolyte type. Pulp fibers with C-starch/PSS multilayer showed better optical properties than poly-DADMAC/PSS treatment. It indicated that polyelectrolyte type in Layer-by-Layer multilayering as well as a good affinity to FWA is important to get better whiteness and brightness.

Application of Cationic PVAm - Anionic PAM Dry Strength Aids System on a Kraft Paper Mill (양이온성 PVAm - 음이온성 PAM 건조지력증강제 시스템의 크라프트지 적용 사례)

  • Cho, Byoung-Uk;Ryu, Jeong-Yong;Son, Dong-Jin;Song, Bong-Keun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.50-57
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    • 2010
  • A mill trial was performed in a kraft paper mill in order to evaluate the possibility of utilizing dual polymer dry strength aids system consisting of cationic PVAm and anionic PAM. It was found that the cationic PVAm - anionic PAM dry strength additives can improve paper strength without significantly disturbing the stability of the kraft papermaking process when virgin UKP was used as a furnish. Tensile strength (25.3% in machine direction, 48.4% in cross machine direction), elongation of paper (31.6%, 15.6%) and tensile energy absorption (48%, 54%) were improved. Air permeability of the kraft paper was improved as well (22%). Tear strength was decreased with PVAm dry strength aids system, but it can be compensated with decreasing refining degree. In addition, the mill trial results indicate that highly air permeable kraft sack paper can be produced by the addition of PVAm dry strength agents at the stock with reduced freeness.

Study on Drainage and Physical Properties of KOCC Handsheet Containing Pretreated Wooden Fillers (전처리 목질계 충전제를 이용한 KOCC 수초지의 탈수속도와 물성 변화)

  • Chae, Hee-Jae;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.21-29
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    • 2011
  • Recently, the use of recycled fibers was increased in order to replace the virgin pulp for low production cost and forest conservation. However, the recycled fibers decreases drainage rate, papermaking efficiency and product quality by short fibers and low wettability because of hornification. To overcome the limitation of low drainage rate, the technology of organic fillers were applied. Wooden fillers gave high bulk and stiffness of paper, but they reduced the strength of paper. In order to improve strength properties 4 types of strength additives were added and analyzed. Cationic starch, branched strength additive, linear wet strength additive, and linear dry strength additive were used. The drainage rate and paper properties such as bulk, air permeability and tensile strength were measured. As results of analysis, addition of branch type of strength agent such as C-starch was effective than linear type of strength agent in the drainage rate. Nevertheless there was no effect on the drainage rate by adding the pretreated wooden fillers. By adding the pretreated wooden fillers, bulk, air permeability and tensile strength of handsheets were improved with low dosage than non-pretreated fillers.