• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.11a
• /
• pp.359-362
• /
• 2000

The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.25 no.8
• /
• pp.30-38
• /
• 2011

This paper proposes a new intelligent diagnosis equipment for the partial discharge, which keeps deteriorating the insulating materials inside electric machineries, ultimately leading to electrical breakdown. In order to simulate experimentally the partial discharge inside the electric machinery, the tip-to-plate, the sphere-to-plate, the sphere-to-sphere and the plate-to-plate electrodes are used respectively, of which the gaps are 1[mm], 3[mm] or 5[mm] and the applied voltages are 3[kV], 5[kV] or 7[kV]. Ceramic coupler sensor and FIR digital filter are used to measure the partial discharge and the artificial neural network is used for the deterioration diagnosis of the electric machinery. The microprocessor of PD diagnosis equipment is DSP (TMS320C6713) with FPGA (Cyclone II). The results of the real-time and on-line experiments performed with the developed equipment are also explained.

• Proceedings of the KIEE Conference
• /
• 1999.07f
• /
• pp.2590-2593
• /
• 1999

This paper describes the development of Emergency Generator Equipments Diagnosis System for monitoring generator equipments and battery system. This system is capable of measuring on up to 20 separate sites of generator, engine and periphral equipment's. Battery system also capable of measure the setting time, float and discharge voltage of up to 240 cells in a single installation, and has the memory capacity to store battery's alarm data information on up to 200 separate sites. This system are easy to maintain and attain cost effectively, so that prepared for meeting the customer's service needs immediately. The system is additionally programmed with a each model, that will enable to accurately determine the generator equipments and remain battery capacity in a system following a short discharge test. It is also equipped with remote interrogation and control facilities.

• Proceedings of the KIEE Conference
• /
• 1998.07f
• /
• pp.2156-2159
• /
• 1998

This paper describes a Battery Checking & Monitoring System for monitoring battery cell and power system in Uninterruptible Power Supplies(UPS). The system is capable of measuring, in a matter of setting time, float and discharge voltage of up to 240 cells in a single installation, and has the memory capacity to store battery's alarm data information on up to 200 separate sites. This system are easy to maintain and attain cost effectively, so that prepared for meeting the customer's service needs immediately. The system is additionally programmed with a each model, that will enable to accurately determine the remain battery capacity in a UPS system following a short discharge test. It is also equipped with remote interrogation and control facilities.

• Tribology and Lubricants
• /
• v.35 no.3
• /
• pp.169-175
• /
• 2019

In lithium-ion batteries (LIBs), the stress induced by the volume change of an electrode during charge-discharge processes may often cause the mechanical integrity of the electrode to degrade. Polymer binders with enhanced mechanical properties are preferred for improved mechanical integrity and cycling stability of the electrode. In addition, given that sliding and shearing between the polymer binder and components in the electrode may readily occur, frictional and adhesion characteristics of the polymer binder may play a critical role in the mechanical integrity of the electrode. In this study, frictional and adhesion characteristics of polyacrylonitrile (PAN) and polyvinylidene fluoride (PVDF) were investigated using a colloidal probe atomic force microscope. Friction loops were obtained under various normal forces ranging from 0 to 159 nN in air and electrolyte and then the interfacial shear strengths of PAN and PVDF in air were calculated to be $1.4{\pm}0.5$ and $1.3{\pm}0.3MPa$, respectively. The results show that in electrolyte, interfacial shear strength of PAN decreased slightly ($1.2{\pm}0.2MPa$), whereas that of PVDF decreased drastically ($0.06{\pm}0.01MPa$). Decreases in mechanical properties and adhesion in electrolyte may be responsible for the decrease in interfacial shear strength in electrolyte. The findings from this study may be helpful in developing polymer binders to improve the mechanical integrity of electrodes in LIBs.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.2
• /
• pp.81-87
• /
• 1999

Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.57 no.12
• /
• pp.2300-2307
• /
• 2008

This study receives the noise transmitted in a constant audio frequency range through a microphone array in which the noise(like grease in a pan) occurs on the power supply line due to the troublesome partial discharge(arc). Then by going through a series of signal processing of removing noise, this study measures the distance and direction up to the noise caused by the troublesome partial discharge(arc) and monitors the result by displaying in the analog and digital method. After these, it determines the state of each size and judges the distance and direction of problematic part. When the signal sound transmitted by the signal source of bad insulator is received on each microphone, the signal comes only in the frequency range of 20 kHz by passing through the circuit of amplification and 6th low pass filter. Then, this signal is entered in a digital value of digital signal processing(TMS320F2812) through the 16-bit A/D conversion. By doing so, the sound distance, direction and coordinate of bad insulator can be detected by realizing the correlation method of detecting the arriving time difference occurring on each microphone and the algorithm of detecting maximum time difference.

• Journal of Industrial and Engineering Chemistry
• /
• v.68
• /
• pp.140-145
• /
• 2018

Bulky carbon layer uniformly distributed with nanoscale $Fe_2O_3$ was prepared via a direct carbonation of $Fe^{3+}$-polyacrylonitrile complexes at $700^{\circ}C$ under $N_2$ flow. The iron oxide carbon composites exhibited an excellent cycling performance for lithium storage with a reversible capacity of ${\sim}810mAh\;g^{-1}$ after 250 cycles at a current rate of $100mA\;g^{-1}$. The enhancement was mainly attributed to dual functions of bulky carbon layer which facilitated the lithium-ion diffusion and accommodated the volume changes of active $Fe_2O_3$ during charge/discharge process. Our novel chemical strategy is quite effective for scalable fabrication of high capacity lithium-storage materials.

• Journal of the Korean Electrochemical Society
• /
• v.4 no.1
• /
• pp.6-9
• /
• 2001

[ $SiO_2$ ] effect on the electrochemical properties of polymeric gel electrolytes(PGEs) reinforced with glass fiber cloth(GFC) was investigated . PGEs were composed of polyacrylronitrile(PAN), poly(vinylidenefluoride-co-hexafluoropropylene) (P(VdF-co-HFP)), $LiClO_4$ and three kind of plasticizer(ethylene carbonate, dietyl carbonate, propylene carbonate). $SiO_2$ was added to PGEs in the weight fraction of 10, 20, $30\%$ respectively. PGEs containing $SiO_2$ showed conductivity of over $10^{-3}S/cm\;at\;23^{\circ}C$ and electrochemical stability window to 4.8V. In the impedance spectra of the cells, which were constructed by lithium metals as electrodes, interfacial resistance increased due to growth of passivation layer during storage time and remarkable difference was not observed with content of $SiO_2$. In the impedance spectra of the lithium ion polymer batteries consisted of $LiClO_2$ and mesophase pitch-based carbon fiber(MCF), ohmic cell resistance of $SiO_2-free$ PGE was changed continuously with number of cycle, but those of $SiO_2-dispersed$ PGEs were not. Discharge capacity of the PGE containing $20wt\%\;SiO_2$ showed 132 mAh/g at 0.2C rate and $85\%$ of discharge capacity was retained at 2C rate.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2001.10a
• /
• pp.147-158
• /
• 2001

In general, two methods have been used to predict settlement of soft ground. One method is Terzaghi's one dimensional consolidation theory which gives time-settlement relationship using the standard consolidation test results. The other is forecasting method of ground settlement to be occured in the future using in-situ monitoring data. The above both methods have some defects in application manner or in itself especially in very deep and soft clayey ground. In view of the lessons and experiences of soft ground improvement projects, several techniques were proposed for more accurate theorectical calculation of consolidation settlement as follows ; ① Subdivision of soft ground, ② Consideration of secondary compression, ③ Using the modified compression index, etc. And also, revised hyperbolic fitting method was suggested to minimize the error of predicted future settlement. In addition, revised De-Beer equation of immediate settlement of loose sandy soil was proposed to overcome the tendency to show too small settlement calculation results by original De-Deer equation. And also, considering the various effects of settlement delay in the improved ground by vertical drains, time-settlement caculation equation(Onoue method) was revised to match the tendency of settlement delay by using the characteristics of discharge capacity decreases of vertical drain with time elapse by the pattern of hyperbolic equation.