• Journal of the Korean Solar Energy Society
• /
• v.30 no.5
• /
• pp.17-24
• /
• 2010

태양열 제습냉방은 액체흡수제를 이용한 냉각효과로 기존의 전기에너지를 가능케 하는 해결책중 하나이다. 따라서 태양열을 거의 활용하지 않는 여름에 가열온수를 열원으로 활용하여 쾌적조건을 구현하는 본 연구의 대상인 태양열냉방시스템은 제습기와 재생기로 크게 이루어져 있다. 본 논문은 제습기의 유량 변화에 따른 열전달 및 물질전달의 변화를 실험과 이론적 해석으로 규명하고 있는데, 흐름의 양상은 병렬형과 대향류형을 대상으로 하고 있다. 실험결과와 이론해석이 비교적 잘 일치하였으며, 대향류형이 병렬형보다도 물질전달 면에서 유리하게 나타났으며, 입 출구의 엔탈피 차이에서도 크서 열전달에서도 우수한 것으로 나타났다. 또한 그 차이를 본 논문에서는 나타내었으며, 일정한 높이나 길이 이상에서는 항상 일정함을 알 수 있었다. 따라서 본 논문의 결과들은 제습기의 유동흐름을 통한 태양열냉방시스템 중 제습기의 설계 및 성능 향상에 도움을 줄 것이다.

• 한국태양에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.161-167
• /
• 2009

The liquid solar air conditioning system is introduced as an alternative solution to control air condition and to save electrical energy consumption. The heat and mass transfer performances of dehumidifier/regenerator in liquid solar air conditioning system are influenced by air and desiccant condition. The application of this system, the thermal energy from the sun and inlet air are unable to control, but operation parameter of other components such as pump, fan and sensible cooling unit are able to control. The equilibrium point of heat and mass transfer are the liquid desiccant and inlet air conditions, where, the heat and mass are not transferred between the liquid desiccant and vapor air. By knowing equilibrium point of heat and mass transfer, the suitable optimal desiccant conditions for certain air condition are funded. This present experiment study is investigated the equilibrium point heat and mass transfer in various air and desiccant temperature. The benefit of equilibrium point heat and mass transfer will be helpful in choose and design proper component to optimize electrical energy consumption.

• Journal of ILASS-Korea
• /
• v.24 no.1
• /
• pp.8-14
• /
• 2019

The purpose of this study is to develop a packing-free wet scrubber to prolong the maintenance interval compared with the conventional packed bed wet scrubbers with which frequent operation stops are unavoidable to clean the packing materials. The main- and interaction-effects were quantitatively analyzed by regression analysis for the measured ammonia scrubbing data from the experiments prepared by experimental design. The scrubbing efficiency of the newly developed wet scrubber was found to be over 95% under the condition of flue gas flow rate of 90CMM and liquid-to-gas ratio $2l/m^3$ for all considered trials of experimental design. The interaction effect between the inlet duct spray and the filter was found to be important, which controls the droplet growth due to the droplet collisions between the duct- and scrubbing tower-spray. The presented methodology to analyze the impacts of operational and design factors on the scrubber efficiency showed potential for applications to optimize the future flue gas abatement process in semiconductor plants.

• Journal of Energy Engineering
• /
• v.6 no.2
• /
• pp.203-211
• /
• 1997

This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

• Clean Technology
• /
• v.7 no.2
• /
• pp.127-132
• /
• 2001

The effects of activated-carbon (AC) packing length on the Pressure Swing Adsorption (PSA) performance was investigated for the hydrogen separation from the multicomponent mixture gas. Linear driving force model was used to describe mass transfer between two phase and coupled Langmuir isotherm was used for each component as a nonlinear adsorption isotherm. When two adsorbents with a different adsorption capacity were packed consecutively in one bed, it is very important to determine the packing ratio of zeolite to activated carbon affecting the purity and recovery of the product. The activated carbon packing length in adsorption tower of 120 cm was determinated by the ending point of $CO_2$ contration. The optimum length of an activated carbon layer was 65 cm for production of high-purity hydrogen.

• Journal of the Korean Society of Safety
• /
• v.35 no.6
• /
• pp.85-92
• /
• 2020

Wet Scrubber reacts the incoming pollutant gas with cleaning water (water + absorbent) to absorb pollutants and release the clean air to the atmosphere. Wet scrubbers and packed tower scrubbers using this principle are widely used in businesses that emit acid gases. In particular, in the etching process using hydrochloric acid (HCl), alkaline washing water (NaOH) having a pH of about 8 to 11 is used to absorb a large amount of acid gas. However, These salts are attached to the injection nozzle (nozzle), filling material (packing), and the demister (Demister), causing air pollution, human damage, and inoperability due to clogging and acid gas discharge. Therefore, In this study, an improvement plan was proposed to manage the washing water with pH 3~4 acidic washing water. The test method takes samples from the Wet Scrubber flue measurement laboratory twice a month for 1 year. Hydrogen chloride (HCl) concentration (ppm) was measured, and nozzle clogging and scale conditions were measured, compared, and analyzed through a differential pressure gauge and a pressure gauge. As a result of the check, it was visually confirmed that the scale was reduced to 50% or less in the spray nozzle, filler, and demister. In addition, the emission limit of hydrogen chloride in accordance with the Enforcement Regulation of the Air Quality Conservation Act [Annex 8] met 3 ppm or less. Therefore, even if the washing water is operated in an acidic pH range of 3 to 4, it is expected to reduce air pollution and human damage due to clogging of internal parts, and it is expected to reduce maintenance costs such as regular cleaning or replacement of parts.

• Clean Technology
• /
• v.27 no.3
• /
• pp.255-260
• /
• 2021

A drawback in the CO₂ capture process using an aqueous amine solution is the high energy requirement for the regeneration process. In order to overcome this disadvantage, this study investigated CO₂ capture characteristics using a biphasic absorbent in which isopropanol (IPA) was introduced into an aqueous solution of diethylenetriamine (DETA). When the IPA composition exceeded 20 wt% in 20 wt% DETA aqueous solution, the absorbent phase was liquid-liquid separated into a CO₂-rich phase and a CO₂-lean phase because of the low solubility of the salt formed by the reaction of CO₂ with DETA in isopropanol. When the isopropanol composition in the DETA aqueous solution increased, the phase volume ratio of the CO₂-rich phase to the volume of the CO₂-lean phase increased; and, accordingly, the CO₂ in the CO₂-rich phase was more concentrated. The results of absorbing CO₂ in a packed tower using 20 wt% DETA + IPA + water absorbent confirmed that both the CO₂ absorption capacity and the absorption rate were higher than that of the 20 wt% DETA aqueous solution. When a biphasic absorbent composed of DETA + IPA + water is applied to CO₂ capture, it can be expected to concentrate CO₂ because of phase separation and thereby reduce regeneration energy owing to volume reduction of the CO₂-rich phase.

• Korean Chemical Engineering Research
• /
• v.61 no.4
• /
• pp.555-560
• /
• 2023

Conventional aqueous amine-based CO₂ capture has a problem in that a large amount of renewable energy is required for CO₂ stripping and solvent regeneration in its industrial applications. This work proposes a water-lean absorbent that can reduce regeneration energy by lowering the water content in the absorbent with high absorption capacity for CO₂. To this purpose, this water-lean solvent introduced NMP (N-methyl-2-pyrrolidone), which has a higher physical solubility in CO₂ and a low specific heat capacity comparing to water, along with 3-methylaminopropylamine (MAPA), a diamine, into the absorbent. The circulating absorption capacity and absorption rate for CO₂ of this water-lean solvent were measured using a packed tower. When NMP was added to the absorbent, the absorption rate was improved. In the case of the absorbent containing 2.5M MAPA was used, the maximum circulating absorption capacity was obtained when 10 wt% of NMP was included in absorbent. The overall mass transfer coefficient increased as the concentration of NMP increased. However, at loading values higher than 0.5, the increment in mass transfer coefficient decreased as the concentration of NMP increased. When the lean loading value is low, the mass transfer resistance due to viscosity of the absorbent is low, so the overall mass transfer coefficient increases with the addition of NMP. However, as the lean loading value increases, the viscosity of the absorbent increases, and the diffusivity of CO₂ and MAPA decreases, resulting in sharply decreasing of the overall mass transfer coefficient.