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http://dx.doi.org/10.14346/JKOSOS.2020.35.6.85

Efficient Management of the pH of the Wet Scrubber Washing Water for Risk Mitigation  

Joo, Dong-Yeon (Department of Safety Engineering, Korea National University of Transportation)
Seoe, Jae Min (Ministry of Employment and Labor)
Kim, Myung-Chul (Department of Safety Engineering, Korea National University of Transportation)
Baek, Jong-Bae (Department of Safety Engineering, Korea National University of Transportation)
Publication Information
Journal of the Korean Society of Safety / v.35, no.6, 2020 , pp. 85-92 More about this Journal
Abstract
Wet Scrubber reacts the incoming pollutant gas with cleaning water (water + absorbent) to absorb pollutants and release the clean air to the atmosphere. Wet scrubbers and packed tower scrubbers using this principle are widely used in businesses that emit acid gases. In particular, in the etching process using hydrochloric acid (HCl), alkaline washing water (NaOH) having a pH of about 8 to 11 is used to absorb a large amount of acid gas. However, These salts are attached to the injection nozzle (nozzle), filling material (packing), and the demister (Demister), causing air pollution, human damage, and inoperability due to clogging and acid gas discharge. Therefore, In this study, an improvement plan was proposed to manage the washing water with pH 3~4 acidic washing water. The test method takes samples from the Wet Scrubber flue measurement laboratory twice a month for 1 year. Hydrogen chloride (HCl) concentration (ppm) was measured, and nozzle clogging and scale conditions were measured, compared, and analyzed through a differential pressure gauge and a pressure gauge. As a result of the check, it was visually confirmed that the scale was reduced to 50% or less in the spray nozzle, filler, and demister. In addition, the emission limit of hydrogen chloride in accordance with the Enforcement Regulation of the Air Quality Conservation Act [Annex 8] met 3 ppm or less. Therefore, even if the washing water is operated in an acidic pH range of 3 to 4, it is expected to reduce air pollution and human damage due to clogging of internal parts, and it is expected to reduce maintenance costs such as regular cleaning or replacement of parts.
Keywords
wet scrubber; HCl; ppm; NaOH; pH; washing water; acid gas; scale;
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  • Reference
1 S. W. Ko, K. C. Noh and H. S. Yoo, "Numerical Study on the Optimal Design of Spray System in Packed Bed Scrubber", Journal of Computational Fluid Engineering, Vol. 12, No. 1, pp. 28-34, 2007.
2 H. J. Nam, "A Study on Wet Scrubber Management Methodology Using Chemical Equilibrium Model", Masters thesis Department of Environment Science,
3 H. D. Yang and Y. K. Oh, "A Study on Improvement of Inhalation Efficiency of Hood in Ventilation System for Elimination of Industrial Dust", J. Korean Soc. Saf., Vol. 23, No. 2, pp. 1-6, 2008
4 Ministry of Environment, Air Pollution Process Test Method, 2016.
5 T. Kyotani, "Method for Preventing Scaling in Wet-process Waste Gas Treatment Equipment", US Patent 6,409,802, pp. 1-2, 2002.
6 S. Kill, H. Nygaard and J. E. Johnsson, "Simulation Studies of the Influenece of HCl Absorption on the Performance of a wet Flue Gas Desulphurisation Pilot Plant", Chemical Engineering Science, Vol. 57, Issue 3, pp. 347-354, 2002.   DOI
7 K. H. Yoo, H. H. Roh, E. S. Choi and J. K. Kim, "An Experiment on the Particle Collection Characteristics in a Packed Wet Scrubber", Journal of the Society of Air-Conditioning and Refrigerating Engineers of Korea, Vol. 4, pp. 305-311, 2003.
8 M. H. Lee, S. B. Kim, Y. S. Hwang, J. H. Kim and K. S. Kim, "Effective Control of fine Particles Using an Electrostatic Coagulation Between Particle and Water Droplet", Journal of The Institute for Liquid Atomization and Spray Systems-Korea, Vol 11, No. 2, pp. 98-104, 2006.
9 K. R. Jung, B. G. Lee, J. H. Lee and S. H. Park, "Develpment of a Novel Hybrid System of Cyclone and Scrubber", Conference of the Korean Society for Atmospheric Environment, pp. 455-456, 2004.
10 J. H. Kim, E. H. Hwang, Y. S. Hwang and H. J. Choi, "Removal of Fine Dust using Charged Droplet Scrubber", Conference of the Korean Society for Atmospheric Environment, pp. 488-490, 2005.
11 A. Jaworek, W. Balachandran, M. Lackowski, J. Kulon and A. Krupa, "Multi-nozzle Electro Spray System for Gas Cleaning Processes", Journal of Electrostatics, Vol. 64, Issues 3-4, pp. 194-202, 2006.   DOI
12 B. N Son, K. S Shin and H. C Choi, "Scrubber System for Removing Acidic Gases", Patent 10-0521398, 2005.
13 K. H. Kang, S. W. Jeong and N. R. Kim, "Acidic Gas Treatment Apparatus", Patent 10-0813658, 2008.