• Title/Summary/Keyword: pH-sensitivity

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CO Gas Sensing Characteristic of ZnO Thin Film/Nanowire Based on p-type 4H-SiC Substrate at 300℃ (P형 4H-SiC 기판에 형성된 ZnO 박막/나노선 가스 센서의 300℃에서 CO 가스 감지 특성)

  • Kim, Ik-Ju;Oh, Byung-Hoon;Lee, Jung-Ho;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.2
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    • pp.91-95
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    • 2012
  • ZnO thin films were deposited on p-type 4H-SiC substrate by pulsed laser deposition. ZnO nanowires were formed on p-type 4H-SiC substrate by furnace. Ti/Au electrodes were deposited on ZnO thin film/SiC and ZnO nanowire/SiC structures, respectively. Structural and crystallographical properties of the fabricated ZnO thin film/SiC and ZnO nanowire/SiC structures were investigated by field emission scanning electron microscope and X-ray diffraction. In this work, resistance and sensitivity of ZnO thin film/SiC gas sensor and ZnO nanowire/SiC gas sensor were measured at $300^{\circ}C$ with various CO gas concentrations (0%, 90%, 70%, and 50%). Resistance of gas sensor decreases at CO gas atmosphere. Sensitivity of ZnO nanowire/SiC gas sensor is twice as big as sensitivity of ZnO thin film/SiC gas sensor.

Effect of Environmental Factors on the Determination of the Ecotoxicological Threshold Concentration of Cu in Soil Pore Water through Biotic Ligand Model and Species Sensitivity Distribution (Biotic ligand model과 종 민감도 분포를 이용한 토양 공극수 내 Cu의 생태독성학적 허용농도 결정에 미치는 환경인자의 영향)

  • Yu, Gihyeon;An, Jinsung;Jeong, Buyun;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.22 no.1
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    • pp.49-58
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    • 2017
  • Biotic ligand model (BLM) and species sensitivity distribution (SSD) were used to determine the site-specific Cu threshold concentration (5% hazardous concentration; HC5) in soil pore water. Model parameters for Cu-BLM were collected for six plants, one collembola, and two earthworms from published literatures. Half maximal effective concentration ($EC_{50}\{Cu^{2+}\}$), expressed as $Cu^{2+}$ activity, was calculated based on activities of major cations and the collected Cu-BLM parameters. The $EC_{50}\{Cu^{2+}\}$ varied from 2 nM to $251{\mu}M$ according to the variation in environmental factors of soil pore water (pH, major cation/anion concentrations) and the type of species. Hazardous activity for 5% (HA5) and HC5 calculated from SSD varied from 0.076 to $0.4{\mu}g/L$ and 0.4 to $83.4{\mu}g/L$, respectively. HA5 and HC5 significantly decreased with the increase in pH in the region with pH less than 7 due to the decrease in competition with $H^+$ and $Cu^{2+}$. In the region with pH more than 7, HC5 increased with the increase in pH due to the formation of complexes of Cu with inorganic ligands. In the presence of dissolved organic carbon (DOC), Cu and DOC form a complex, which decreases $Cu^{2+}$ activity in soil pore water, resulting in up to 292-fold increase in HC5 from 0.48 to $140{\mu}g/L$.

Fabrication and pH response characteristics of LAPS(Light addressable potentiometric sensor) with electrolyte/$Si_3N_4/SiO_2$/Si structure (Electrolyte/$Si_3N_4/SiO_2/Si$ 구조의 LAPS 제작 및 pH 응답특성)

  • Chang Su-Won;Koh Kwang-Nak;Kang Shin-Won
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.40-44
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    • 1998
  • The LAPS device of fast response and high sensitivity, based on electrochemical potential difference, and its system were fabricated for the precise measurement of pH changes and its characteristic were investigated. The electrostatic variation characteristics of LAPS according to the pH changes and parameters in the device were verified through a simulation using LAPS equivalent circuit model. The LAPS device and its system were fabricated on the basis of the result of simulation. The fabricated LAPS system showed linear sensitivity (about 56 mV/pH within the range of pH 2 to pH 11. In order to overcome the defect of general urea sensor (especially slow response time), urease immobilized nitrocellulose membrane was attached on the LAPS and resulted in the very fast response time, 0.29 mV/sec, 0.86 mV/sec at urea concentration of $50{\mu}g/ml,\; 500{\mu}g/ml$, respectively. And also in order to measure the uranyl ion, the uranyl ion selective sensing membrane with calix[6]arene derivative was used and its sensitivity was 25mV/concentration decade in the wide uranyl ion concentration range of $10^{-11}M\;to\;10^{-4}M$.

Regional Heterogeneity of Morphological Changes in Cultured Rat Astrocytes

  • Won, Chung-Kil;Oh, Young-S.
    • The Korean Journal of Physiology and Pharmacology
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    • v.5 no.6
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    • pp.467-477
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    • 2001
  • We examined astrocyte regional heterogeneity in their morphological changes in response to various stimuli. Astrocytes were cultured from six different neonatal rat brain regions including cerebral cortex, hippocampus, cerebellum, mid brain, brain stem and hypothalamus. Astrocyte stellation was induced by serum deprivation and the maximum stellation in different regional astrocytes was achieved after 2 h. After 24 h, in all astrocyte cultures, the level of stellation returned to their original level. Cerebellar or hypothalamic astrocytes were the most or the least sensitive, respectively, to serum deprivation. The order of maximum sensitivity to serum deprivation among different regional astrocytes was: cerebellum>mid $brain{\ge}hippocampus,\;brain\;stem{\ge}cerebral$ cortex>hypothalamus. Isoproterenol-induced astrocyte stellation was also examined in different regional astrocytes, and similar order of maximum sensitivity as in serum deprivation was observed. Next a possible developmental effect on astrocyte morphological changes was examined in cerebral cortex and cerebellum astrocytes cultured from postnatal day 1 (P1), P4 and P7 rat brains. A much higher sensitivity of cerebellum astrocytes to serum deprivation as well as isoproterenol treatment was consistently observed in P1, P4 and P7-derived astrocytes compared to cerebral cortex astrocytes. The present study demonstrates different regional astrocytes maintain different levels of morphological plasticity in vitro.

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Sensitivity of the Pyrenophora teres Population in Algeria to Quinone outside Inhibitors, Succinate Dehydrogenase Inhibitors and Demethylation Inhibitors

  • Lammari, Hamama-Imene;Rehfus, Alexandra;Stammler, Gerd;Benslimane, Hamida
    • The Plant Pathology Journal
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    • v.36 no.3
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    • pp.218-230
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    • 2020
  • Net blotch of barley caused by Pyrenophora teres (Died.) Drechsler, is one of the most destructive diseases on barley in Algeria. It occurs in two forms: P. teres f. teres and P. teres f. maculata. A total of 212 isolates, obtained from 58 fields sampled in several barley growing areas, were assessed for fungicide sensitivity by target gene analysis. F129L and G137R mitochondrial cytochrome b substitution associated with quinone outside inhibitors (QoIs) resistance, and succinate dehydrogenase inhibitors (SDHIs) related mutations (B-H277, C-N75S, C-G79R, C-H134R, and C-S135R), were analyzed by pyrosequencing. In vitro sensitivity of 45 isolates, towards six fungicides belonging to three chemical groups (QoI, demethylase inhibitor, and SDHI) was tested by microtiter technique. Additionally, sensitivity towards three fungicides (azoxystrobin, fluxapyroxad, and epoxiconazole) was assessed in planta under glasshouse conditions. All tested isolates were QoI-sensitive and SDHI-sensitive, no mutation that confers resistance was identified. EC50 values showed that pyraclostrobin and azoxystrobin are the most efficient fungicides in vitro, whereas fluxapyroxad displayed the best disease inhibition in planta (81% inhibition at 1/9 of the full dose). The EC50 values recorded for each form of net blotch showed no significant difference in efficiency of QoI treatments and propiconazole on each form. However, in the case of fluxapyroxad, epoxiconazole and tebuconazole treatments, analysis showed significant differences in their efficiency. To our knowledge, this study is the first investigation related to mutations associated to QoI and SDHI fungicide resistance in Algerian P. teres population, as well as it is the first evaluation of the sensitivity of P. teres population towards these six fungicides.

Cation Leaching from Soils Percolated with Simulated Sulfuric Acid Rainn (人工酸性 빗물에 의한 여러 土壤으로부터의 이온 洗脫)

  • Rhyu, Tae-Cheol;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.16 no.2
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    • pp.169-180
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    • 1993
  • Soils of four combinations, sand with high content of organic matter(SL), sand with low content of OM(SS), siltyl loam with high content of OM(LL) and silty loam with low content OM (LS), were filled on column and then percolated with simulated sulfuric acid rain with pH 5.6, 4.0, 3.5, 3.0 and 2.5. From soil leachates, pH and concentrations of basic cations and Al were determined. Cation concentrations in the leachates increased as pH of the rain decreased. The orders of buffering capacity of soil, leachability of cation from soil, leaching sensitivity of ion andbase saturation sensitivity of soil to acidity of the rain water were SS$\leq$K <$\leq$LL

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Thickness Dependence of Solution Deposited HfOx Sensing Membrane for Electrolyte-Insulator-Semiconductor (EIS) Structures (용액 공정으로 증착된 HfOx 감지막을 갖는 Electrolyte-Insulator-Semiconductor 소자의 두께 의존성)

  • Lee, In-Kyu;Cho, Won-Ju
    • Journal of Sensor Science and Technology
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    • v.22 no.3
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    • pp.233-237
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    • 2013
  • We fabricated electrolyte-insulator-semiconductor (EIS) devices using a solution process and measured the sensing properties of EIS devices according to the thicknesses of sensing membrane. For high pH sensitivity and better stability properties, we used $SiO_2/HfO_x$ (OH) layer as a sensing membrane. In this work, $HfO_x$ sensing membranes were deposited on 5 nm thick $SiO_2$ buffer layer by spin coater with thicknesses of 15, 31, 42, 55 nm, respectively. As a result, we founded that the thickness of $HfO_x$ sensing membrane affects to sensitivity and chemical stability of EIS device. Especially, the EIS device with 42 nm thick $HfO_x$ membrane showed superior sensing ability in terms of pH-sensitivity, linearity, hysteresis voltage and drift rate characteristics than the other devices. In conclusion, we confirmed that it is possible to improve the sensing ability and the chemical stability properties using optimized thickness of sensing membrane and proper annealing process.

Influence of Corrosion Potential and Current Density on Polarization Curve Variations using Polycarbonate[III]

  • Park, Chil-Nam;Yang, Hyo-Kyung;Kim, Sun-Kyu;Kim, Myung-Sun;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.43-50
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    • 2000
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves using polycarbonate. The results were particularly examined to identify the influences affecting the corrosion potential including various conditions such as temperature, pH, catalytic enzyme, and salt. The lines representing the active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme, and salt. The tafel slope for the anodic dissolution was determined based on the polarization effect with various conditions. The slope of the polarization curves describing the active-to-passive transition region were noticeably shifted in direction. Also, from the variation in the conditions, the optimum conditions were established for the most rapid transformation, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(Ir/If). The value of Ir/If was then used in measuring the extent of the critical corrosion sensitivity of the polycarbonate. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

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Amperometric Detection of Hydroquinone and Homogentisic Acid with Laccase Immobilized Platinum Electrode

  • Quan, De;Shin, Woon-Sup
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.833-837
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    • 2004
  • DeniLite$^{TM}$ laccase immobilized platinum electrode was used for amperometric detection of hydroquinone (HQ) and homogentisic acid (HGA) by means of substrate recycling. In case of HQ, the obtained sensitivity is 280 nA/ ${\mu}$M with linear range of 0.2-35 ${\mu}$M ($r^2$ = 0.998) and detection limit (S/N = 3) of 50 nM. This high sensitivity can be attributed to chemical amplification due to the cycling of the substrate caused by enzymatic oxidation and following electrochemical regeneration. In case of HGA, the obtained sensitivity is 53 nA/ ${\mu}$M with linear range of 1-50 $[\mu}M\;(r^2$ = 0.999) and detection limit of 0.3 ${\mu}$M. The response times ($t_{90%}$) are about 2 seconds for the two substrates and the long-term stability is 60 days for HQ and around 40-50 days for HGA with retaining 80% of initial activities. The very fast response and the durable long-term stability are the principal advantages of this sensor. pH studies show that optimal pH of the sensor for HQ is 6.0 and that for HGA is 4.5-5.0. This shift of optimal pH towards acidic range for HGA can be attributed to the balance between enzyme activity and accessibility of the substrate to the active site of the enzyme.

Sensitivity of BOD Sensor with Heavy Metal Tolerant Serratia marcescens LSY4 (Serratia marcescens LSY4 중금속 내성주를 이용한 BOD센서의 감응도)

  • Kim Mal-Nam;Lee Sun-Young
    • Korean Journal of Environmental Biology
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    • v.22 no.3
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    • pp.394-399
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    • 2004
  • A BOD sensor was prepared with S. marcescens LSY4 and was applied for measurement of BOD values of a solution containing the standard organic pollutants. The sensor sensitivity was nearly independent of the culture time in the range of 9-16 hours. It was also affected little by the cell mass in the range of 0.22-0.75 mg $cm^{-2}$. A cyclic change in the solution pH in the range of 4-9 was accompanied by a reversible variation in the sensor sensitivity. However, the reversibility was lost when the solution pH became more acidic or more basic. Heavy metal ions lowered the sensor sensitivity, which took place more precipitously in the presence of $Cu^{2+}$ and $Ag^+$ rather than in the presence of $Zn^{2+}$ and $Cd^{2+}$. The reduction of the sensor sensitivity was significantly attenuated by loading heavy metal ion tolerance induced strain. The $Cu^{2+}$tolerance induced strain was more efficient for the attenuation than $Zn^{2+}$ and $Cd^{2+}$ tolerance induced strain.