• 제목/요약/키워드: pH values

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수용액중(水溶液中)에서의 Kaolinite 입자(粒子)의 전기화학적(電氣化學的) 성질(性質) (Electrochemical Properties of Kaolinite in Aqueous Suspension)

  • 임형식
    • 한국토양비료학회지
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    • 제16권4호
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    • pp.318-324
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    • 1983
  • 이온흡착, 전위차적정, 전기이동법 등을 이용 하여 kaolinite 현탄액의 전기 화학적 성질을 연구하였다. 0.001M 또는 0.1M NaCl 용액중에서 kaolinite로부터 용해되어 나온 알루미늄 이온이 $Na^+$$Cl^-$과 같이 지시이온으로서 kaolinite 표면에 흡착되는 것을 고려할 때 kaolinite는 pH independent + 및 -전하와 pH dependent + 및 -전하를 모두 가지고 있었다. 증류수와 0.001M NaCl 용액중에서 kaolinite 입자의 전기이동은 전기 이동셀(cell)에서 측정이 시작된 후 시간경과(전기이동 측정시간)에 관계없이 일정한 이동성을 나타냈으나 0.1M NaCl 용액중에서 kaolinite 입자는 등전점 (pH 4.7) 이상에서는 측정시간이 경과함에 따라 전하가 -에서 +로 변화하였다. 즉 최초 10초 동안에는 -전하를 가지며 그 후에는 +전하를 띠면서 전기이동 속도가 단계적으로 증가하게 되는데 약 10분 후에는 일정하게 되었다. 이것은 아마도 제일 바깥쪽 Octahedral layer 표면의 aluminol group의 부분들이 높은 이온 강도의 전해질 용액중에서 분해되어 복잡한 전기이중층(electric double layer)을 이루고 이것이 전기장 내에서 이동할 때 표면으로부터 counter이온들이 점차 떨어져 나가는 과정에서 전하(net charge)의 변화가 생기는 것으로 생각된다.

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雨水採取機가 雨水成分에 미치는 影響 (Effects of Rain Water Sampler on the Results of Analysis)

  • 李敏熙;韓義正;辛燦基;韓振錫
    • 한국대기환경학회지
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    • 제3권2호
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    • pp.53-61
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    • 1987
  • Automatic and manual rain smaplers wre installed at the roof of National Institute of Environmental Research (NIER), and the rain sampling and measurement were conducted during the period April to August 31, 1987. The rain sampling and measurement were carried out in the following manners: The 1st : Acidity and conductivity were measured entirely by automatic rain sampler (continuous measurement) The 2nd : Acidity and conductivity wrer measured in the laboratory with the sample that was taken out of automatic rain sampler. The 3rd : Acidity and conductivity were measured in the laboratory with the sample that was taken out of manual rain sampler. Afterwards, those different measurement values were compared each other and the following conclusions were obtained: 1) The pH of the continous measurement by the automatic sampler was lower than that of the laboratory measurement, and it was reversed in case of the conductivity. 2) The significance was recognized at 5% risk ratio for the population mean of difference of the measurement values of the pH and conductivity from both samples. 3) The significance was not recognized at 5% risk ratio by the analysis of variance by one way layout for the pH and conductivity. 4) The significance was recognized at 5% risk ratio by the analysis of variance by two way layouts for the pH conductivity. 5) The significance was recognized at 5% rrisk ratio for the differences of the pH values obtained by oboth samplers, and no significance was recognized for conductivity. 6) In comparison of the measurement values from the two samplers were shown a good correlation for pH; correlation coefficient (r) = 0.63, and regression equation Y = 0.53X + 2.78. For conductivity, the correlation was also excellent; correlation coefficient (r) = 0.53 and regression equation Y = 0.63X + 5.65.

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Viscosity and Wettability of Hyaluronic Acid according to Antimicrobial Supplementation, Ionic Strength, and pH

  • Kho, Hong-Seop;Chang, Ji-Youn;Kim, Yoon-Young;Park, Moon-Soo
    • Journal of Oral Medicine and Pain
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    • 제39권3호
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    • pp.90-95
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    • 2014
  • Purpose: To investigate viscosity and wettability of hyaluronic acid (HA) solutions according to supplementation of lysozyme and/or peroxidase, and different ionic strength and pH conditions. Methods: Solutions containing HA were prepared using distilled deionized water (DDW) and simulated salivary buffer (SSB) in different conditions. Different concentrations of hen egg-white lysozyme and bovine lactoperoxidase was added into HA solutions. HA solutions with antimicrobials in different ionic strength and pH conditions were prepared. Viscosity was measured using cone-and-plate digital viscometer at six different shear rates and wettability on acrylic resin and Co-Cr alloy was determined by contact angle. Results: The viscosity values of HA dissolved in DDW were decreased in order of HA, HA containing lysozyme, HA containing peroxidase, and HA containing lysozyme and peroxidase. The viscosity values for HA in DDW were decreased as the concentration of lysozyme and/or peroxidase increased. However, the viscosity values for HA in SSB showed no significant changes according to the concentration of lysozyme and/or peroxidase. The viscosity values of HA solutions were inversely proportional to ionic strength and pH. The contact angle of HA solutions showed no significant differences according to tested surface materials, addition of lysozyme and/or peroxidase, and different ionic strength and pH conditions. Contact angles on acrylic resin by HA solutions in all tested conditions were much higher than those by human saliva. Conclusions: The rheological properties of HA supplemented with lysozyme and/or peroxidase in different ionic strength and pH conditions were objectively confirmed, indicating the possibility of HA with lysozyme and/or peroxidase as main components in the development of effective saliva substitutes.

수경재배 양액조건이 2년생 인삼의 생육 및 진세노사이드 함량에 미치는 영향 (Effects of Nutrient Solution on Growth and Amount of Ginsenoside of Two Year Old Ginseng Grown under Hydroponic Culture)

  • 유진;장인배;서수정;권기범
    • 한국약용작물학회지
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    • 제24권3호
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    • pp.198-206
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    • 2016
  • Background: Electrical conductivity (EC) and pH are important features of nutrient solution, affecting both growth and quality of crops by altering nutrient uptake. Methods and Results: The pH values of nutrient solutions were controlled at 5.0, 5.5, 6.0, 6.5 and EC values were controlled at 0.68, 0.84, 1.23, 1.41 dS/m. Gingesng root weights were higher during the initial growth period when the plants were treated with low pH and low EC nutrient solutions. However, the higher pH and EC levels, the greater the increase in the rate of root weight between the initial and middle growth periods. The highest ginsenoside amount changed during growth period. The total ginsenoside amount was highest in the root, and the lowest in leaves at 45 and 90 days after treatment, respectively, with solution at a pH of 6.0. After 135 days of treatment, the highest total ginsenoside amount was detected in root treated with soluton with EC values of 1.23 dS/m. Conclusions: For the cultivation of ginseng using a nutriculture system, the pH and EC values of nutrient solutions should to be controlled based on the stage of growth and targeted plant organ (root or leaves).

들깨종실단백질 중의 phytate 제거에 관한 연구 (Studies on the Removal of Phytate from Korean Perilla (Perilla ocimoides, L.) Protein)

  • 박진희;양차범
    • 한국식품과학회지
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    • 제22권3호
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    • pp.343-349
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    • 1990
  • pH를 달리한 수용액 및 농도를 달리한 염류수용액에서 들깨종실의 단백질과 phytate의 용해도를 측정하여 단백질로부터 phytate를 제거할 수 있는 조건을 검토하였다. 들깨종실단백질의 용해도는 pH4.0에서 가장 낮은 9.5%로 등전점을 보였고, 그보다 산성 또는 알칼리성쪽으로 갈수록 증가되었다. 반면에 phytate의 용해도는 pH5.0에서 가장 높았으며 그보다 산성 또는 알칼리성쪽으로 갈수록 감소되었다. NaCl 수용액을 처리하였을 때 단백질의 용해도는 pH $3.0{\sim}4.0$ 범위에서 가장 낮았고 pH 6.0 이상에서는 현저히 증가되었다. Phytate의 용해도는 pH$2.0{\sim}5.0$ 범위에서는 약 90%내외로 높았으나 pH6.0 이상에서는 급격히 감소되었다. $Na_2SO_3$ 수용액처리에서는 단백질 용해도가 $pH2.0{\sim}3.0$ 범위에서 가장 낮았고 phytate의 용해도는 $pH5.0{\sim}6.0$에서 최대치를 보였고, 3%의 경우는 전 pH 구간에 걸쳐서 낮았으나 5%와 7%에서는 전 구간에서 높았다. $CaCl_2$ 수용액처리에서는 단백질 용해도가 3% 수용액에서는 전 pH 구간에서 낮았으나 5%와 7%에서는 $pH5.0{\sim}10.0$에서 높은 값을 보였으며 phytate의 용해도는 $pH2.0{\sim}3.0$ 사이에서 최대값을 나타내고 pH4.0이상에서는 급격히 감소하였다. 이상의 결과에서 3% NaCl 용액을 사용하여 pH9.0에서 단백질을 추출하고 pH4.0에서 침전시켰을 때 단백질 수율이 좋고 phytate 잔존량이 가장 적어, 저(低)phytate 분리단백질을 만드는 가장 좋은 조건이었다..

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돈육의 사후 24시간 pH 수준에 따른 육질 특성 (Comparison of Pork Quality by Different Postmortem pH24 Values)

  • 박범영;조수현;유영모;김진형;채현석;안종남;김용곤;이종문;윤상기
    • Journal of Animal Science and Technology
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    • 제44권2호
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    • pp.233-238
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    • 2002
  • 도축 후 돈육의 육질평가에 있어 중요한 요인인 사후 24시간 pH를 측정하여 pH가 5.31-5.50, 5.51-5.70, $\geq$5.71에 따른 육질을 조사한 결과, 사후 pH가 더 낮을수록 단백질 함량이 높고, 지방 함량이 낮았다(P$<$0.05). 사후 24시간 pH가 높을수록 보수력은 증가하였으며, 가열감량과 육즙감량은 유의적으로(P$<$0.05) 감소하였다. 육의 경도, 탄력성, 씹힘성과 지방경도 역시 사후 24시간 pH가 높을수록 유의적인 증가를 보였다(P$<$0.05). 육색특성 중 CIE L*값은 사후 24시간 pH가 낮을수록 유의적으로 높았으며, a*와 b*값, chroma 값은 최종 pH가 5.71 이상의 돈육에서 유의적으로 낮게 나타났다(P$<$0.05). Hue 값은 pH 5.31-5.70 범위에서 가장 높았으며, $\Delta$E 값도 pH 5.31-5.50에서 가장 높았다. 관능적 특성의 분석결과, 다즙성과 연도는 최종 pH가 높을수록 향상되었으나, 향미는 최종 pH 범위에 따른 차이가 인정되지 않았다. 따라서 본 연구결과, 도축 후 24시간 돈육의 pH 범위에 따라 육질의 차이를 보이기 때문에 사후 적정 pH를 유지할 수 있도록 도축전 관리, 도축방법, 도축 후 냉각 온도관리 등을 개선하는 것이 고품질 돈육생산에 있어 중요한 것으로 사료된다.

강원도 중왕산 지역에서 5개 수종의 임외강우와 수간류의 수량 및 수질특성(I) - pH값을 중심으로 - (Characteristics of Quantiy and Quality for Bulk Precipitation and Stemflow of 5 Tree Species in Mt. Joongwang, Gangwon-do - A Centering Around the pH Value -)

  • 정문호;이광수
    • 한국산림과학회지
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    • 제97권3호
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    • pp.229-236
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    • 2008
  • 본 연구는 산림생태계내 물질순환의 한 경로인 수간류를 대상으로 수종에 따른 수간류량과 pH값의 특성을 살펴보기 위해 강원도 평창군에 위치한 중왕산 지역에서 2004년과 2005년에 매년 6월부터 10월까지 임외강우와 활엽수종인 신갈나무, 거제수나무, 음나무, 물푸레나무와 대표적 조림수종인 낙엽송 등 5개 수종의 수간류의 유입량과 pH값을 분석하였다. 수종별 수간류량은 신갈나무에서 조사기간 동안 9.9 mm가장 많았고, 거제수나무, 음나무, 낙엽송, 물푸레나무가 각각 7.5 mm, 5.9 mm, 3.8 mm, 3.2 mm였다. 임외강우량이 증가할수록 수간류량도 증가하였으며, 단기간 집중호우가 많이 발생한 2004년에 임외강우의 증가에 따른 수간류의 증가량이 적게 나타났다. 각 수종별 수간류의 pH값은 물푸레나무에서 평균 5.56으로 가장 높았으며, 음나무 5.64, 거제수나무 5.80, 신갈나무 5.91, 낙엽송 5.25 순이었다. 대체로 임외강우의 pH값이 증가함에 따라 수간류의 pH값도 증가하였으며, 임외강우의 평균 pH값은 6.39로 모든 수종의 pH값이 임외강우의 pH값보다 낮았다.

Effects of Ensiling Alfalfa with Whole-crop Maize on the Chemical Composition and Nutritive Value of Silage Mixtures

  • Ozturk, Durmus;Kizilsimsek, Mustafa;Kamalak, Adem;Canbolat, Onder;Ozkan, Cagri Ozgur
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권4호
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    • pp.526-532
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    • 2006
  • The aim of this study was to evaluate the chemical composition, in vitro DM degradability, ME and OMD of alfalfa-maize silage mixtures in comparison to pure maize and alfalfa silages, and to test the existence of associative effects of ensiling alfalfa forage with whole-crop maize using the in vitro gas production technique. Ensiling alfalfa with whole-crop maize had a significant (p<0.001) effect on chemical composition, pH, in vitro DM degradability, OMD and estimated ME values of mixtures. DM content of the resultant silages significantly increased with increasing proportion of whole-crop maize in the mixtures, whereas the pH value, crude protein (CP), acid detergent fibre (ADF) and ash contents of mixtures decreased due to the dilution effect of whole-crop maize which was low in CP, ADF and ash. The pH values of all alfalfa-maize silage mixtures were at the desired level for quality silage. Gas production of alfalfa-maize silage mixtures at all incubation times except 12 h increased with increasing proportion of whole-crop maize. When alfalfa was mixed with whole-crop maize in the ratio 40:60, ME and OMD values were significantly (p<0.001) higher than other silages. Maximum gas production ($A_{gas}$) ranged from 65.7 to 78.1 with alfalfa silage showing the lowest maximum gas production. The results obtained in this study clearly showed that maximum gas production increased with increased percentage of whole-crop maize in the silage mixtures (r = 0.940, p<0.001). It was concluded that ensiling alfalfa with whole-crop maize improved the pH, OMD and ME values. However, trials with animals are required to see how these differences in silage mixtures affect animal performance.

인공해수의 pH에 따른 강 용접부의 응력 부식균열거동에 관한 연구 (A Study on the Stress Corrosion Cracking Behaviors for Weld Joint of Steel with Various pH Values in Synthetic Sea Water)

  • 유효선;나의균;정세희
    • Journal of Welding and Joining
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    • 제13권1호
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    • pp.78-88
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    • 1995
  • This paper was performed to study the utility of the SP(small punch) test and the AE(acoustic emission) test in the evaluation of SCC(stress corrosion cracking) susceptibility for parent metal and bond line of HT80 steel-weld joint by SAW(submerged arc welding) with the various pH values. The loading rate used was 3*10$^{-4}$ mm/min and the corrosive environment used was synthetic sea water during the SP test and the AE test. According to the test results, the SCC susceptibility of the parent metal was increased in the order of pH6.0, pH8.2 and pH10.0. On the other hand, the bond line showed almost the same high SCC susceptibility in all pH concentrations. Synthetically, from the results of the SCC susceptibility, the macro- and micro-SEM observation, the microfracture behaviors by AE test and the relationship between SCC susceptibility and displacement at incipient failure, .delta.$_{i.f-AE}$, it can be concluded that the SP test and the AE test are the good test methods to evaluate the SCC susceptibility for parent metal and bond line of the weld joint with the change of environmental factors.

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pH 변화에 따른 Tungstophosphates 화합물의 분자형태 변화에 대한 분광학적 연구 (A Study on the Molecular Changes of Tungstophosphate Species at Different pH Values using Spectroscopy)

  • 안범수
    • 한국응용과학기술학회지
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    • 제28권3호
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    • pp.284-289
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    • 2011
  • All spectroscopic methods used in this work indicate the instability of tungstophosphates in aqueous solutions and considerable dependence on pH with regard to the dominant species present in the solution. UV spectroscopy indicates that some changes occur in the system but they cannot be specified. IR spectroscopy gives more information on the identification of the dominant species as a function the pH of the solution. NMR spectroscopy provides unique data, which can be used for more accurate interpretation of changes in the solution of various pH values. In the case of aqueous solutions of tungstophosphates, the parent anion was present only in a very acidic solution of ca. pH 1. Some differences in interpretation of the molecular species present under various experimental conditions can be ascribed to some extent to the diversity of chemical shifts of NMR. Under physiological conditions attained with the addition of NaOH, tungstophosphates was dominantly present in the form of the lacunary monovacant anion.