• Title/Summary/Keyword: pH studies

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Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution

  • Ahmed, S.A. Sayed;El-Enin, Reham M.M. Abo;El-Nabarawy, Th.
    • Carbon letters
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    • v.12 no.3
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    • pp.152-161
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    • 2011
  • Activated carbon was prepared from pre-carbonized petroleum coke. Textural properties were determined from studies of the adsorption of nitrogen at 77 K and the surface chemistry was obtained using the Fourier-transform infrared spectrometer technique and the Boehm titration process. The adsorption of three aromatic compounds, namely phenol (P), p-nitrophenol (PNP) and benzoic acid (BA) onto APC in aqueous solution was studied in a batch system with respect to contact time, pH, initial concentration of solutes and temperature. Active carbon APC obtained was found to possess a high surface area and a predominantly microporous structure; it also had an acidic surface character. The experimental data fitted the pseudo-second-order kinetic model well; also, the intraparticle diffusion was the only controlling process in determining the adsorption of the three pollutants investigated. The adsorption data fit well with the Langmuir and Freundlich models. The uptake of the three pollutants was found to be strongly dependent on the pH value and the temperature of the solution. Most of the experiments were conducted at pH 7; the $pH_{(PZC)}$ of the active carbon under study was 5.0; the surface of the active carbon was negatively charged. The thermodynamic parameters evaluated for APC revealed that the adsorption of P was spontaneous and exothermic in nature, while PNP and BA showed no-spontaneity of the adsorption process and that process was endothermic in nature.

Studies on the Water Purification Using Glycine max Merr Seedling (콩(Glycine max Merr)유묘를 이용한 수질정화에 관한 연구)

  • 김순진;나규환
    • Journal of Environmental Health Sciences
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    • v.23 no.1
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    • pp.50-54
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    • 1997
  • The removal efficiency of nutrient was investicated by using Glycine max Meer seedling. After budding, Glycine max Merr was raised at darkness for 4 days. During cultivation, the removal efficiency of $NO_2-N+NO_3-N$ was up to 90% with initial concentration of 20-100 ppm. The removal efficiency of PO$_4$-P was up to 80% with initial concentration at 30 ppm, but it was down to 22% and 27% at 40 ppm and 50 ppm. When the removal efficiency of nutrient was compared with alternating 12 hours' light and darkness, the removal efficiency of NO$_2$-N + NO$_3$-N was up to 90% at below 60 ppm. It was not different from each other. But it was particularly low about 62% and 34% at 80 ppm and 100 ppm in alternating 12 hours' light. The removal efficiency of PO$_4$-P was low at alternating 12 hours' light between 10-50 ppm on the whole range. The neutralizing capacity of pH was shown in acidity and alkalinity except strong acidity(below pH 3). The initial pH was neutralized at 6.0-7.7 of pH after 4 days. Particularly, Glycine max Meer seedling that was difference from other water plants, was shown the neutralizing capacity in strong alkalinity.

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Bias-corrected Hp(10)-to-Organ-Absorbed Dose Conversion Coefficients for the Epidemiological Study of Korean Radiation Workers

  • Jeong, Areum;Kwon, Tae-Eun;Lee, Wonho;Park, Sunhoo
    • Journal of Radiation Protection and Research
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    • v.47 no.3
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    • pp.158-166
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    • 2022
  • Background: The effects of radiation on the health of radiation workers who are constantly susceptible to occupational exposure must be assessed based on an accurate and reliable reconstruction of organ-absorbed doses that can be calculated using personal dosimeter readings measured as Hp(10) and dose conversion coefficients. However, the data used in the dose reconstruction contain significant biases arising from the lack of reality and could result in an inaccurate measure of organ-absorbed doses. Therefore, this study quantified the biases involved in organ dose reconstruction and calculated the bias-corrected Hp(10)-to-organ-absorbed dose coefficients for the use in epidemiological studies of Korean radiation workers. Materials and Methods: Two major biases were considered: (a) the bias in Hp(10) arising from the difference between the dosimeter calibration geometry and the actual exposure geometry, and (b) the bias in air kerma-to-Hp(10) conversion coefficients resulting from geometric differences between the human body and slab phantom. The biases were quantified by implementing personal dosimeters on the slab and human phantoms coupled with a Monte Carlo method and considered to calculate the bias-corrected Hp(10)-to-organ-absorbed dose conversion coefficients. Results and Discussion: The bias in Hp(10) was significant for large incident angles and low energies (e.g., 0.32 for right lateral at 218 keV), whereas the bias in dose coefficients was significant for the posteroanterior (PA) geometry only (e.g., 0.79 at 218 keV). The bias-corrected Hp(10)-to-organ-absorbed dose conversion coefficients derived in this study were up to 3.09- fold greater than those from the International Commission on Radiological Protection publications without considering the biases. Conclusion: The obtained results will aid future studies in assessing the health effects of occupational exposure of Korean radiation workers. The bias-corrected dose coefficients of this study can be used to calculate organ doses for Korean radiation workers based on personal dose records.

Studies on the Phosphate Accumulation in Tobacco Production Area (연초경작지 토양의 인산 축적에 관한 연구)

  • 김용현;정훈채;박수준;윤병익;김웅주
    • Journal of the Korean Society of Tobacco Science
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    • v.13 no.2
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    • pp.71-79
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    • 1991
  • The experiment was conducted to investigate accumulation o( phosphate in tobacco production area. The results are as follows: 1) The content of available P in burley production area was about 200ppm higher than that in flue-cured tobacco production area, the available P content of 20% tobacco fields surveyed was above 1000ppm P. 2) Tobacco fields having 200ppm of available P which were grouped as medium category for phosphate recommendation were more than 90% out of tobacco fields surveyed. 3) Total phosphate content was above 4000ppm in 42.5% burley tobacco fields before transplanting, and 2000~3000ppm in about 40% flue-cured tobacco fields. 4) Phosphate fractions in soil increased in order of Al-P > Fe-P > Ca-p, and their content was about 50% of total phosphate in tobacco fields surveyed. 5) pH value in most of tobacco fields surveyed ranged from 4.5 to 5.0 and, field soils with pH value below 5.5 were 64 %.

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A Study of Laminated Evaporator Performance Characteristics through Numerical Analysis (전산해석을 이용한 적층형 증발기 성능특성 연구)

  • 시종민;한창섭;김재훈;우승길
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.3
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    • pp.210-219
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    • 2003
  • A laminated evaporator performance simulation software has been developed and the performance characteristics have been examined with variation of important design parameters, number of plate ( $P_{N}$), plate inner height ( $P_{h}$), Plate thickness ( $p_{t}$) and plate wetted Perimeter ( $P_{wl}$ ). To confirm the program, performance experiment was carried out for two different evaporators. The simulation results matched with experiments within $\pm$10%. Through the parametric studies, $P_{N}$ was shown to be most influential. The $P_{N}$, $P_{h}$ and $P_{wl}$ had a maximum cooling capacity point in the calculation range. In case of $P_{t}$, the smaller was the better.ter.etter.ter.

Studies on the Stability of Natural Pigment Extracted from Ascidian shell (멍게 껍질(Ascidian shell)로부터 추출한 천연색소의 안정성에 대한 연구)

  • Park, Sin-Ho;Yang, Jae-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.292-298
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    • 2018
  • In this study, Ascidian shell pigment was extracted, first using a 100.0 % ethanol solvent, proceeding with the dilution of it with DMSO (Dimethyl sulfoxide). The extracted pigment was evaluated to verify the stability. The absorbance of light have been evaluated according to pH levels and using the color-difference meter. As a result, it could be seen that absorbance and chromaticity ${\pm}a$ values were most stable at a pH level of 7.0 By keeping the sample at a pH level of 3.0, it could be observed that the absorbance and the chromaticity ${\pm}a$ values were decreased. Based on this observation, it can be deduced that the discoloration of the pigment can be prevented if kept at a neutral pH level. When antioxidants were added, the absorbance of the pigment increased, and the best effects could be seen in the ${\alpha}-tocopherol$ and glutathione samples.

Studies on Enzyme of the Thermophilic Mold-Part. 3. Thermophilic mold amylase- (고온성 사상균의 효소에 관한 연구-(제3보) 고온성 사상균의 Amylase-)

  • Chung, Dong-Hyo;Lee, Ke-Ho
    • Applied Biological Chemistry
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    • v.13 no.3
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    • pp.231-235
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    • 1970
  • 1. Purification of amylase system produced from Humicola sp. by a submerged culture eras carried out. 2. By DEAE-Cellulose column chromatography amylase system was separated into two fractions eluted at 0.05M and 0.5M phosphate buffer solution of pH 6.0. 3. The saccharogenic amylase was mostly composed of. the fraction of 0.05M phosphate buffer solution of pH 6.0 while the dextrinogenic amylase was perseted in fraction of 0.5M phosphate buffer solution of pH 6.0 4. It was found that the optimum pH of this saccharogenic amylase was within the range of from 4.5 to 5.5, stable pH was within the range of from 4.0 to 9.0 and optimum temperature was $60-65^{\circ}C$. This amylase was stable at $70^{\circ}C$ for ten minutes but completely inactivated $80^{\circ}C$ above.

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Studies on Heat Sensitivity of Egg Albumen I. Effects of Heating Time and Temperature, pH and NaCl Concentration on Heat Sensitivity of Egg Albumen (난백 의 열감수성 에 관한 연구 I. 가열온도와 시간, pH 및 NaCl농도가 난백의 열감수성에 미치는 영향)

  • 유익종
    • Korean Journal of Poultry Science
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    • v.15 no.1
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    • pp.39-44
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    • 1988
  • This study was undertaken to find out the effect of heating time and temperature, pH and NaCl concentration on heat sensitivity of egg albumen during heat treatment. Sharp increase of the turbidity and rapid decrease of the foaming power were observed when egg albumen was heated at above $60^{\circ}C$. Egg albumen became opaque when it was heated at $60^{\circ}C$ for above 13 minutes or at $65^{\circ}C$ for above 5 minutes. The turbidity was markedly increased at below pH 7 and the foaming power was largely decreased at around pH 4.0 by the heat treatment ($60^{\circ}C$, 5 min). The foam stability was slightly decreased at alkaline pH range by the heat treatment (60t, 5 min). The addition of NaCl up to 0.3M decreased the turbidity. There was no effect of NaCl addition on the foaming power, but the foam stability was decreased by the addition of NaCl at above 0.2M before and after the heat treatment ($60^{\circ}C$, 5 min).

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Studies on the Hydrolysis of Milk Fat by Microbial Lipases (미생물에서 추출된 Lipase의 유지방 분해)

  • Park, Jong-Hack;Lee, Young-Chun
    • Korean Journal of Food Science and Technology
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    • v.17 no.2
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    • pp.60-64
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    • 1985
  • To utilize microbial lipases for hydrolysis of milk fat, optimum reaction conditions and characteristics of enzymatic reactions of lipases originated from Rhizopus delemar, Mucor sp., and Candida cylindracea were investigated. Optimum pH and temperature were pH 5.6 and $45^{\circ}C$ for Rhizopus delemar lipase, pH7.5 and $35^{\circ}C$ for Mucor sp. lipase, and pH7.5 and $35^{\circ}C$ for Candida cylindracea lipase. Optimum lipase concentration and optimum substrate concentration were $600{\sim}800\;units/ml$ and 20% milk fat, regardless of their origin. Km values were 6.06% milk fat for Rhizopus delemar lipase, 7.69% for Mucor sp. lipase and 7.99% for Candida cylindracea lipase. Rate of lipid hydrolysis was Rhizopus delemar lipase>Mucor sp. lipase>Candida cylindracea lipase. As the reaction time was extended, liberation of short chain fatty acids was increased. After 8 hours reaction, capric acid content significantly increased with Candida cylindracea lipase, palmitic acid with Mucor sp. lipase and butyric acid with Rhizopus delemar lipase.

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THE INFLUENCE OF pH ON REMINERALIZATION OF ARTIFICIAL DENTAL CARIES (법랑질 인공우식의 재광화에 미치는 pH의 영향에 관한 연구)

  • Kim, Min-Kyung;Kum, Kee-Yeon;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.193-208
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    • 1997
  • Much evidence now exists from both in vivo and in vitro studies to support the claim that small caries lesions can 'heal'. But, there are still different views on the mechanism of remineralization. So in order to find the best condition for the remineralization of incipient dental caries in maximum efficient way, the author conducted the experiment which reveals the effect of pH on remineralization. 40 specimens of sound permanent teeth without demineralization or crack, $100{\mu}m$ in thickness, were immersed in lactic acid buffered demineralization solution for 4 days. Dental caries with surface zone and subsurface lesion were artificially produced. All specimens were immersed in lactic acid buffered remineralization solution of pH 4.0, 4.5, 5.0, 5.5 containg fluoride ion for 10 days. The results were obtaind by observing the specimens for every 10 days under polarized microscopy at x25. 1. Remineralization did not occur in entire depth of body of lesion at given degree of saturation and concentration of fluoride ion. 2. The pattern of remineralization has increased according to increase of pH. So it can be concluded that supersaturated solution with fluoride ion can be affected by pH in remineralization of enamel, and pH 5.5 seems to be very effective in remineralization of deep and surface zone of dental caries. However, more complex factors exist in achieving complete remineralization and further continuous researches are needed to clarify the factors.

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