• Title/Summary/Keyword: pH stability

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Enhanced Biodegradation of Lindane Using Oil-in-Water Bio-Microemulsion Stabilized by Biosurfactant Produced by a New Yeast Strain, Pseudozyma VITJzN01

  • Abdul Salam, Jaseetha;Das, Nilanjana
    • Journal of Microbiology and Biotechnology
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    • v.23 no.11
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    • pp.1598-1609
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    • 2013
  • Organochlorine pesticide residues continue to remain as a major environmental threat worldwide. Lindane is an organochlorine pesticide widely used as an acaricide in medicine and agriculture. In the present study, a new lindane-degrading yeast strain, Pseudozyma VITJzN01, was identified as a copious producer of glycolipid biosurfactant. The glycolipid structure and type were elucidated by FTIR, NMR spectroscopy, and GC-MS analysis. The surface activity and stability of the glycolipid was analyzed. The glycolipids, characterized as mannosylerythritol lipids (MELs), exhibited excellent surface active properties and the surface tension of water was reduced to 29 mN/m. The glycolipid was stable over a wide range of pH, temperature, and salinity, showing a very low CMC of 25 mg/l. Bio-microemulsion of olive oil-in-water (O/W) was prepared using the purified biosurfactant without addition of any synthetic cosurfactants, for lindane solubilization and enhanced degradation assay in liquid and soil slurry. The O/W bio-microemulsions enhanced the solubility of lindane up to 40-folds. Degradation of lindane (700 mg/l) by VITJzN01 in liquid medium amended with bio-microemulsions was found to be enhanced by 36% in 2 days, compared with degradation in 12 days in the absence of bio-microemulsions. Lindane-spiked soil slurry incubated with bio-microemulsions also showed 20-40% enhanced degradation compared with the treatment with glycolipids or yeast alone. This is the first report on lindane degradation by Pseudozyma sp., and application of bio-microemulsions for enhanced lindane degradation. MEL-stabilized bio-microemulsions can serve as a potential tool for enhanced remediation of diverse lindane-contaminated environments.

An Improved Active Damping Method with Capacitor Current Feedback

  • Geng, Yi-Wen;Qi, Ya-Wen;Liu, Hai-Wei;Guo, Fei;Zheng, Peng-Fei;Li, Yong-Gang;Dong, Wen-Ming
    • Journal of Power Electronics
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    • v.18 no.2
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    • pp.511-521
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    • 2018
  • Proportional capacitor current feedback active damping (CCFAD) has a limited valid damping region in the discrete time domain as (0, $f_s/6$. However, the resonance frequency ($f_r$) of an LCL-type filter is usually designed to be less than half the sampling frequency ($f_s$) with the symmetry regular sampling method. Therefore, ($f_s/6$, $f_s/2$) becomes an invalid damping region. This paper proposes an improved CCFAD method to extend the valid damping region from (0, $f_s/6$ to (0, $f_s/2$), which covers all of the possible resonance frequencies in the design procedure. The full-valid damping region is obtained and the stability margin of the system is analyzed in the discrete time domain with the Nyquist criterion. Results show that the system can operate stably with the proposed CCFAD method when the resonance frequency is in the region (0, $f_s/2$). The performances at the steady and dynamic state are enhanced by the selected feedback coefficient H and controller gain $K_p$. Finally, the feasibility and effectiveness of the proposed CCFAD method are verified by simulation and experimental results.

Dispersion Characteristics of Natural Crystalline Graphite Powders by Surface Modification (표면개질에 의한 인상흑연 분체의 분산특성 연구)

  • Kim, Byeong-Gon;Choe, Sang-Geun;Jeong, Heon-Saeng;Han, Sang-Geun;Lee, Jae-Jang
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.679-684
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    • 2001
  • The surface of natural graphite has not only good electrical conductivities and lubrication properties but also has strong hydrophobicity. There are no functional groups and chemical properties on it. It is difficult to join with any other ions and to disperse in aqueous system. In order to increase dispersion ability throughout modification of surface property, it is necessary to let graphite have some function on its surface by the adsorption of surfactant molecules. In this study, using zeta potential adsorbed surfactant molecules(ABDM) on graphite surface and its surface Properties turn hydrophobic into hydrophilic. The dispersing mechanism of graphite particles in aqueous system has been explained using the DLVO theory, It is concluded that the high dispersable graphite suspension of which dispersing stability$(T_{1/2})$ is 44.5 hours at pH 10 and 22.5mV zeta potential can be produced.

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Manufacture of magnetite (Fe3O4) electrode and its electrochemical properties (마그네타이트 (Fe3O4) 전극의 제조와 전기화학 특성)

  • Kim, Myong-Jin;Kim, Dong Jin;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.14 no.1
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    • pp.19-24
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    • 2015
  • Flow Accelerated Corrosion (FAC) causes unexpected accidents in a secondary side of a nuclear power plant. The secondary side pipes are mainly carbon steel tubes that have a protective magnetite ($Fe_3O_4$) layer on the inner surface. The stability of the protective magnetite layer depends on the parameters related to the FAC phenomena such as pH, temperature, flow rate, surface roughness etc. The dissolution of magnetite is basically the electrochemical reaction, but the most of the experiments of magnetite dissolution were carried out thermodynamically to determine the solubility of magnetite. The knowledge of the electrochemical properties of magnetite is required to understand the dissolution process of magnetite. This paper reviews the manufacture of the magnetite ($Fe_3O_4$) electrode, and summaries the electrochemical properties of the magnetite.

The Modified Electrode by PEDOP with MWCNTs-Palladium Nanoparticles for the Determination of hydroquinone and Catechol

  • Naranchimeg, Orogzodmaa;Kim, Seul-Ki;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2771-2775
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    • 2011
  • Poly-ethylenedioxypyrrole (PEDOP) coated thiolated multiwall carbon nanotubes palladium nanoparticles (MWCNTs-Pd) modified glassy carbon electrode (GCE) [PEDOP/MWCNTs-Pd/GCE] for the determination of hydroquinone (HQ) and it’s isomer catechol (CA) were synthesized and compared with bare GCE and thiolated multiwall carbon nanotubes (MWCNTs-SH/GCE). The modification could be made by simple processes on a GCE with MWCNTs-Pd covered by PEDOP in a 0.05 M tetrabutylammonium perchlorate (TBAP)/MeCN solution system. A well-defined peak potential evaluation of the oxidation of hydroquinone to quinone at 0.05 V (vs. Ag/AgCl), and electrochemical reduction back to hydroquinone were found by cyclic voltammetry (CV) in phosphate buffered saline (PBS) at pH 7.4. Peak current values increased linearly with increasing hydroquinone contents. The peak separation between the anodic and cathodic peaks at the PEDOP/MWCNTs-Pd/GCE was ${\Delta}Ep$ = 40 mV for HQ and ${\Delta}Ep$ = 70 mV for CA, resulting in a higher electron transfer rate. Moreover, good reproducibility, excellent storage stability, a wide linear range (0.1 ${\mu}M$ - 5 mM for HQ and 0.01 ${\mu}M$ - 6 mM for CA), and low detection limits ($2.9{\times}10^{-8}$ M for HQ and $2.6{\times}10^{-8}$ M for CA; S/N = 3) were determined using differential pulse voltammetry (DPV) and amperometric responses; this makes it a promising candidate as a sensor for determination of HQ and CA.

PREPARATION AND CHARACTERIZATION OF MULTIFERROIC 0.8 $BiFeO_3$-0.2 $BaTiO_3$ THIN FIMLS BY PULSED LASER DEPOSITION

  • Kim, K.M.;Yang, P.;Zhu, J.S.;Lee, H.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.313-313
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    • 2010
  • $BiFeO_3$ (BFO), when forming a solid solution with $BaTiO_3$ (BTO), shows structural transformations over the entire compositional range, which not only gives a way to increase structural stability and electrical resistivity but also applies a means to have better ferromagnetic ordering. In this respect, we have prepared and studied 0.8 BFO-0.2 BTO thin films on Pt(111)/$TiO_2/SiO_2$/Si substrates by pulsed laser deposition. Various deposition parameters, such as deposition temperature and oxygen pressure, have been optimized to get better quality films. Based on the X-ray diffraction results, thin films were successfully deposited at the temperature of $700^{\circ}C$ and an oxygen partial pressure of 10mTorr and 330mTorr. The dielectric, ferroelectric, and magnetic properties have then been characterized. It was found that the films deposited under lower and higher oxygen pressure corresponded to lower leakage current. Magnetism measurement showed an induced ferromagnetism. The microstructures associated with the magnetic and dielectric properties of this mixed-perovskite solid solutions were observed by transmission electron microscopy, which revealed the existence of complicated ferroelectric domains, suggested that the weak spontaneous magnetization was closely associated with the decrease in the extent of rhombohedral distortion by a partial substitution of $BaTiO_3$ for $BiFeO_3$.

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Preparation of Semi-Dried Jellyfish and Its Stability during Storage (해파리 반건품의 제조와 저장안정성)

  • 양승택
    • Journal of Life Science
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    • v.12 no.5
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    • pp.535-543
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    • 2002
  • To investigate the possibility of processing semi-dried jellyfish and to examine its keeping quality, the factors such as moisture content, pH, volatile basic nitrogen (VBN), viable cell counts, color value and texture were analyzed. For processing of the semi-dried product, optimum conditions of drying temperature and drying time were $25^{\circ}C$ and 90min, respectively, under 60 $\pm$ 5% of relative humidity and 2 m/sec of air blast speed. The shelf-life of the products, vacuum-packing method in nylon/polyethylene/linear low density polyethylene (0.015/0.045/0.040 mm) laminated film bag was at least 6 weeks during storage at 4$^{\circ}C$, while that of air packaged one was at least 4 weeks. In case of 2$0^{\circ}C$ storage the shelf-life of the products was at least 3 weeks in both air and vacuum packaged ones.

Combined Effect of Kimchi Powder and Onion Peel Extract on Quality Characteristics of Emulsion Sausages Prepared with Irradiated Pork

  • Lee, Soo-Yoen;Kim, Hyun-Wook;Hwang, Ko-Eun;Song, Dong-Heon;Choi, Min-Sung;Ham, Youn-Kyung;Choi, Yun-Sang;Lee, Ju-Woon;Lee, Si-Kyung;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.35 no.3
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    • pp.277-285
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    • 2015
  • This study was conducted to investigate the effects of kimchi powder and onion peel extract on the quality characteristics of emulsion sausage manufactured with irradiated pork. The emulsion sausages were formulated with 2% kimchi powder and/or 0.05% onion peel extract. The changes in pH value of all treatments were similar, depending on storage periods. The addition of kimchi powder increased the redness and yellowness of the emulsion sausage. The addition of onion peel extract decreased the thiobarbituric acid reactive substances value of the emulsion sausages prepared with irradiated pork. The volatile basic nitrogen value of the emulsion sausage prepared with kimchi powder was the highest, whereas that of the emulsion sausage prepared with onion peel extract was the lowest. The treatment without kimchi powder or onion peel extract and the treatments prepared with onion peel extract showed lower microbial populations than the other treatment. Sensory evaluations indicated that a higher acceptability was attained when kimchi powder was added to the emulsion sausages manufactured with irradiated pork. In conclusion, our results suggest that combined use of kimchi powder and onion peel extract could improve quality characteristics and shelf stability of the emulsion sausage formulated with irradiated pork during chilled storage.

Effects of Lemon Balm on the Oxidative Stability and the Quality Properties of Hamburger Patties during Refrigerated Storage

  • Lee, Hyun-Joo;Choi, You-Jung;Choi, Yang-Il;Lee, Jae-Joon
    • Food Science of Animal Resources
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    • v.34 no.4
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    • pp.533-542
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    • 2014
  • This study was performed to investigate the effects of lemon balm (Melissa officinalis L.) on various quality and antioxidant activity of hamburger patties. Lemon balm extract (LBE) showed the highest amount of total polyphenol (801.00 mg TAE/g DW) and flavonoids (65.05 mg RA/g DW). The $IC_{50}$ value of DPPH hydroxyl scavenging of LBE was $132{\mu}g/mL$. The hamburger patties were prepared by 0% (N), 0.1% (L1), 0.5% (L2), and 1.0% (L3) of the lemon balm powder. The addition of lemon balm powder increased the chewiness value, but did not affect the hardness, cohesiveness, and springiness values. Lemon balm powder had positive effects on sensory evaluation of patties. The pH of all patties decreased with longer storage period. 2-Thiobarbituric acid value, volatile basic nitrogen content, and the total microbial counts of hamburger patties in the L3 group were lower, compared to those of the normal (N group). In conclusion, the L3 group had significantly delayed lipid peroxidation compared to other treatment groups. However, the addition of lemon balm powder into patties showed no significantly influence on proximate composition, calorie contents, water holding capacity and cooking loss of patties. Therefore, lemon balm might be a useful natural antioxidant additive in meat products.

Development of Revegetation Technique for Water Attacking Point Using Waterlogged Prevention Frame Revetment (침수방틀을 이용한 자연형 하천의 수충부 녹화공법 개발)

  • Moon, Seok Ki;Lee, Eun Yeob;Han, Sung Sik;Lee, Ki Joon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.1
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    • pp.98-109
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    • 2001
  • This study aimed to investigate the effect of revegetation technique for water attacking point using waterlogged prevention frame revetment. In this study, we evaluate frame revetment stability, water quality, plant growth and ecological and envirnomental changes in Mooshim streamside landscape. The results are as follows; 1) The waterlogged prevention frame revetment appeared to be stable despite of two big floods. The materials used for the revetment were not eroded on the water attacking point. Thus, we confirmed the effect of scour prevention of the frame work. 2) The effects of the frame revetment on the water quality appeared to be good for the surrounding environment. Dissolved Oxygen(DO) was higher about $0.4{\sim}0.6mg/{\ell}$ at the frame revetment than that of the main stream flow. pH value was lower about 0.4~0.5. Electric Conductivity(EC) showed lower about $0.8{\sim}1.1{\mu}s/cm$. at submersion prevent frame than the low-flow of the stream. Turbidity was lower about $0.6{\sim}1.2mg/{\ell}$. 3) As the effects on ecological and environmental conditions, we discovered a number of carassius auratus and Zacco platypus in the frame revetment area. Also, sympetrum balteata, coenagrionidae was observed frequently. 4) The plant growth did not appear to tumble or wither despite of two big floods. The visual rating of plant growth was evaluated as medium (around 5 point) 5) The landscape analysis derived four factors(i.e. the harmony, the variation, the flexibility and the provincial characteristics) from the factor analysis.

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