• 제목/요약/키워드: pH sensing

검색결과 248건 처리시간 0.028초

Na2CO3-CaCO3 보조상을 사용한 후막형 Co2 센서의 특성연구 (Characteristics of thick film Co2 sensors attached with Na2CO3-CaCO3 auxiliary phases)

  • 심한별;최정운;강주현;유광수
    • 센서학회지
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    • 제15권3호
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    • pp.168-172
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    • 2006
  • Potentiometric $CO_{2}$ sensors were fabricated using a NASICON ($Na_{1+x}Zr_{2}Si_{X}P_{3-X}O_{12}$, 1.8 < x < 2.4) thick film and auxiliary layers. The powder of a precursor of NASICON with high purity was synthesized by a sol-gel method. By using the NASICON paste, an electrolyte was prepared on the alumina substrate by screen printing and then sintered at $1000^{\circ}C$ for 4 h. A series of $Na_{2}CO_{3}-CaCO_{3}$ auxiliary phases were deposited on the Pt sensing electrode. The electromotive force (emf) values were linearly dependent on the logarithm of $CO_{2}$ concentration in the range between 1,000 and 10,000 ppm. The device attached with $Na_{2}CO_{3}-CaCO_{3}$ (1:2 in mol.%) showed good sensing properties in the low temperatures.

이중 편파 Sentinel-1 SAR 영상의 편파 지표를 활용한 인공지능 기반 선박 탐지 (Exploitation of Dual-polarimetric Index of Sentinel-1 SAR Data in Vessel Detection Utilizing Machine Learning)

  • 송주영;김덕진;김준우;이성뢰
    • 대한원격탐사학회지
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    • 제38권5_2호
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    • pp.737-746
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    • 2022
  • 전천후 자료 취득이 가능한 SAR 영상을 기반으로 한 선박 탐지와 인공지능 기반 탐지 알고리즘과 함께 사용하는 것은 안정적인 선박 모니터링에 효과적이다. 기존의 SAR 영상에서는 인공지능 기반 선박 탐지 알고리즘에 진폭 영상만을 주로 사용하였으며, 물체의 산란 특성을 구분할 수 있는 다중 편파 SAR 영상의 편파 지표는 사용되지 않았다. 이에, 본 연구에서는 이중 편파 Sentinel-1 SAR 영상으로부터 고유값 분해를 통해 취득한 4개의 편파 지표인 H, p1, DoP, DPRVI와 방사 보정을 통해 취득한 2개 편파의 산란계수인 γ0, VV, γ0, VH를 이용하여 총 6개의 밴드를 가진 SAR 영상 52장의 데이터베이스를 구축하고, 이와 상응하는 시간에 취득한 선박의 실시간 위치 및 속도 정보인 AIS 자료를 사용하여 학습자료를 추출하였다. 구축된 밴드 조합에 대해 선박탐지 정확도를 평가한 결과, 이중 편파 지표를 진폭과 함께 사용한 경우 진폭 값만을 사용했을 때에 비해 개선된 탐지 정확도를 보였다.

SAW 가스센서의 제작 및 특성 (Fabrication and Characteristics of SAW Gas Sensor)

  • 전춘배;박효덕;최동한;이덕동
    • 센서학회지
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    • 제3권1호
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    • pp.40-45
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    • 1994
  • SAW 가스센서의 기판으로 $112^{\circ}$ rot. x-cut $LiTaO_{3}$ 기판을 사용하였고, 사진식각법으로 reference delay line과 sensing delay line으로 구성된 dual delay line SAW소자를 제작하였다. 각각의 IDT는 전극의 폭이 $10{\mu}m$이고, 10 개의 전극쌍을 갖는다. 각각 두개의 delay line 중에서 reference delay line은 감지막을 증착시키지 않고, sensing delay line은 유기물 반도체의 일종인 Pb-프탈로시아닌을 shadow mask로써 $10^{-5}$torr의 진공하에서 선택적으로 증착시켰다. 제작된 SAW소자로 rf amp.와 AGC(Auto Gain Control)를 사용하여 dual delay line oscillator를 만들었다. 이때 발진주파수는 $87{\sim}$89 MHz였다. 온도와 $NO_{2}$ 가스농도의 변화에 따른 발진주파수의 변화를 조사하였다.

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NH4OH 수용액 하에서 Cu 호일의 산화를 통해 합성한 CuO 나노벽의 가스센싱 특성 (Gas sensing properties of CuO nanowalls synthesized via oxidation of Cu foil in aqueous NH4OH)

  • 슈엔하이엔뷔엔;팜티엔헝;풍딘호앗;이시홍;이상욱;이준형;김정주;허영우
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.141-141
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    • 2018
  • Copper is one of the most abundant metals on earth. Its oxide (CuO) is an intrinsically p-type metal-oxide semiconductor with a bandgap ($E_g$) of 1.2-2.0 eV 1. Copper oxide nanomaterials are considered as promising materials for a wide range of applications e.g., lithium ion batteries, dye-sensitized solar cells, photocatalytic hydrogen production, photodetectors, and biogas sensors 2-7. Recently, high-density and uniform CuO nanostructures have been grown on Cu foils in alkaline solutions 3. In 2011, T. Soejima et al. proposed a facile process for the oxidation synthesis of CuO nanobelt arrays using $NH_3-H_2O_2$ aqueous solution 8. In 2017, G. Kaur et al. synthesized CuO nanostructures by treating Cu foils in $NH_4OH$ at room temperature for different treatment times 9. The surface treatment of Cu in alkaline aqueous solutions is a potential method for the mass fabrication of CuO nanostructures with high uniformity and density. It is interesting to compare the gas sensing properties among CuO nanomaterials synthesized by this approach and by others. Nevertheless, none of above studies investigated the gas sensing properties of as-synthesized CuO nanomaterials. In this study, CuO nanowalls versus nanoparticles were synthesized via the oxidation process of Cu foil in NH4OH solution at $50-70^{\circ}C$. The gas sensing properties of the as-prepared CuO nanoplates were examined with $C_2H_5OH$, $CH_3COCH_3$, and $NH_3$ at $200-360^{\circ}C$.

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A case study of red tide detection around Korean waters using satellite remote sensing

  • Suh, Y.S.;Lee, N.K.;Jang, L.H.;Kim, H.G.;Hwang, J.D.
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.654-655
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    • 2003
  • Korea has experienced 10 a Cochlodinium polykrikoides red tide outbreaks during the last 10 years (1993-2002). The monitoring activities at National Fisheries Research and Development Institute (NFRDI) in Korea have been extended to all the coastal waters after the worst of fish killing by C. polykrikoides blooms in 1995. NFRDI is looking forward to finding out the feasibility of red tide detection around Korean waters using satellite remote sensing of NOAA/AVHRR, Orbview-2/SeaWiFS, IRS-P4/OCM and Terra/MODIS on real time base. In this study, we used several alternative methods including climatological analysis, spectral and optical methods which may offer a potential detection of the major species of red tide in Korean waters. The relationship between the distribution of SST and C. polykrikoides bloom areas was studied. In climatological analysis, NOAA, SeaWiFS, OCM satellite data in 20th and 26th August 2001 were chosen using the known C. polykrikoides red tide bloom area mapped by helicopter reconnaissance and ground observation. The 26th August, 2001 SeaWiFS chlorophyll a anomaly imageries against the imageries of non-occurring red tide for August 20, 2001 showed the areas C. polykrikoides occurred. The anomalies of chlorophyll a concentration from satellite data between before and after red tide outbreaks showed the similar distribution of C. polykrikoides red tide in 26th August, 2001. The distribution of the difference in SST between daytime and nighttime also showed the possibility of red tide detection. We used corrected vegetation index (CVI) to detect floating vegetation and submerged vegetation containing algal blooms. The simple result of optical absorption from C. polykrikoides showed that if we use the optical characteristics of each red tide we will be able to get the feasibility of the red tide detection.

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Sodium Salicylate Activates p38MAPK Though a Specific-Sensing Mechanism, Distinct from Pathways Used by Oxidative Stress, Heat Shock, and Hyperosmotic Stress

  • Kim, Jung-Mo;Oh, Su-Young;Kim, Min-Young;Seo, Myoung-Suk;Kang, Chi-Duk;Park, Hye-Gyeong;Kang, Ho-Sung
    • 대한의생명과학회지
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    • 제9권4호
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    • pp.241-248
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    • 2003
  • Sodium salicylate, a plant stress hormone that plays an important role(s) in defenses against pathogenic microbial and herbivore attack, has been shown to induce a variety of cell responses such as anti-inflammation, cell cycle arrest and apoptosis in animal cells. p38MAPK plays a critical role(s) in the cell regulation by sodium salicylate. However, the signal pathway for sodium salicylate-induced p38MAPK activation is yet unclear. In this study, we show that although sodium salicylate enhances reactive oxygen species (ROS) production, N-acetyl-L-cysteine, a general ROS scavenger, did not prevent sodium salicylate-induced p38MAPK, indicating ROS-independent activation of p38MAPK by sodium salicylate. Sodium salicylate-activated p38MAPK appeared to be very rapidly down-regulated 2 min after removal of sodium salicylate. Interestingly, sodium salicylate-pretreated cells remained fully responsive to re-induction of p38MAPK activity by a second sodium salicylate stimulation or by other stresses, $H_2O$$_2$ and methyl jasmonate (MeJA), thereby indicating that sodium salicylate does not exhibit both homologous and heterologous desensitization. In contrast, pre-exposure to MeJA, $H_2O$$_2$, heat shock, or hyperosmotic stress reduced the responsiveness to subsequent homologous stimulation. Sodium salicylate was able to activate p38MAPK in cells desensitized by other heterologous p38MAPK activators. These results indicate that there is a sensing mechanism highly specific to sodium salicylate for activation of p38MAPK, distinct trom pathways used by other stressors such as MeJA, $H_2O$$_2$ heat shock, and hyperosmotic stress.

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P형 4H-SiC 기판에 형성된 ZnO 박막/나노선 가스 센서의 300℃에서 CO 가스 감지 특성 (CO Gas Sensing Characteristic of ZnO Thin Film/Nanowire Based on p-type 4H-SiC Substrate at 300℃)

  • 김익주;오병훈;이정호;구상모
    • 한국전기전자재료학회논문지
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    • 제25권2호
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    • pp.91-95
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    • 2012
  • ZnO thin films were deposited on p-type 4H-SiC substrate by pulsed laser deposition. ZnO nanowires were formed on p-type 4H-SiC substrate by furnace. Ti/Au electrodes were deposited on ZnO thin film/SiC and ZnO nanowire/SiC structures, respectively. Structural and crystallographical properties of the fabricated ZnO thin film/SiC and ZnO nanowire/SiC structures were investigated by field emission scanning electron microscope and X-ray diffraction. In this work, resistance and sensitivity of ZnO thin film/SiC gas sensor and ZnO nanowire/SiC gas sensor were measured at $300^{\circ}C$ with various CO gas concentrations (0%, 90%, 70%, and 50%). Resistance of gas sensor decreases at CO gas atmosphere. Sensitivity of ZnO nanowire/SiC gas sensor is twice as big as sensitivity of ZnO thin film/SiC gas sensor.

PVA-SbQ 고분자 물질을 이용한 ISFET 尿素센서 (ISFET Urea Sensor Using PVA-SbQ Polymer)

  • 최성문;김창수;남동현;손병기;김의락
    • 대한화학회지
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    • 제36권4호
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    • pp.496-503
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    • 1992
  • 반도체 수소이온센서인 pH-ISFET를 제조 하고, 이를 ISFET 요소 센서로 이용하기 위하여 pH-ISFET의 Si$_3$$N_4$ 막 위에 요소 분해효소인 urease를 감광성 고분자 물질인 PVA-SbQ를 이용하여 고정화하였다. 제조된 센서는 빠른 응답특성과 우수한 재현성을 보였으며, 약 1∼50 mg/dl의 요소농도를 정량할 수 있었다. 또한 그 임상적용을 위한 기초연구로서 혈액 중에 존재하는 여러 가지 물질들이 센서의 출력에 미치는 영향을 조사하였으며, 혈장의 요소농도를 측정하여 현재 실용되고 있는 분광광도법의 결과와 비교하였다.

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다채널 LAPS 제작 및 이를 이용한 pH 변화량 검출 시스템 구현 (Implementation of Multichannel LAPS and Measurement System for Detection of the pH Variation Using an Implemented Device.)

  • 배상곤;박일용;박영식;장수원;이승하;강신원;조진호
    • 센서학회지
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    • 제10권4호
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    • pp.239-249
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    • 2001
  • 본 논문은 pH감도와 교류 광전류의 바이어스 포텐셜 의존성을 이용한 다채널 센서인 LAPS의 실제 제작과, 동기 검파 및 다중화 방법을 이용하여 제작된 센서의 신호를 효과적으로 측정하기 위한 시스템 구현에 관한 것이다. 제작된 LAPS소자는 여러 종류의 물질을 동시에 측정하기 위하여 다채널 감지면으로 구성하였으며, 제작된 소자에 적합한 측정 시스템은 높은 S/N를 유지하면서 다채널 pH농도 측정이 가능하도록 하나의 전치 증폭단을 이용한 시분할 측정과 이에 적합한 제어 시스템을 포함한다. 전체 시스템 하드웨어는 전치 증폭부, 디지털 및 센서부로 구성되었으며, 소프트웨어는 디지털 제어용 시스템 프로그램과 PC프로그램으로 구성된다. 구현된 시스템의 성능을 평가한 결과 양호한 감도, 선형성으로 LAPS에 의한 다채널 측정이 가능함을 보였다.

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p-CuO/n-ZnO 이종접합 박막 구조의 수소 가스 특성 평가 (Hydrogen Gas Sensor Performance of a p-CuO/n-ZnO Thin-film Heterojunction)

  • 양이준;맹보희;정동건;이준엽;김영삼;안희경;정대웅
    • 센서학회지
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    • 제31권5호
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    • pp.337-342
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    • 2022
  • Hydrogen (H2) gas is widely preferred for use as a renewable energy source owing to its characteristics such as environmental friendliness and a high energy density. However, H2 can easily reverse or explode due to minor external factors. Therefore, H2 gas monitoring is crucial, especially when the H2 concentration is close to the lower explosive limit. In this study, metal oxide materials and their p-n heterojunctions were synthesized by a hydrothermal-assisted dip-coating method. The synthesized thin films were used as sensing materials for H2 gas. When the H2 concentration was varied, all metal oxide materials exhibited different gas sensitivities. The performance of the metal oxide gas sensor was analyzed to identify parameters that could improve the performance, such as the choice of the metal oxide material, effect of the p-n heterojunctions, and operating temperature conditions of the gas sensor. The experimental results demonstrated that a CuO/ZnO gas sensor with a p-n heterojunction exhibited a high sensitivity and fast response time (134.9% and 8 s, respectively) to 5% H2 gas at an operating temperature of 300℃.