• 제목/요약/키워드: pH of drainage

검색결과 286건 처리시간 0.028초

인회석을 이용한 도금폐수 내 중금속 제거효율 실내실험

  • 최정찬;라원진;강두현
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.172-174
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    • 2004
  • 본 논문은 광산산성배수(AMD)에서 철 및 알루미늄 제거 효과가 입증되고 ARD(Acid Rock Drainage)에서의 비소제거 효과가 확인된 인회석을 침전제로 사용하여 철, 알루미늄 및 비소가 아닌 다른 중긍속의 제거효율을 알아보기 위해 도금폐수를 이용하여 실내실험을 실시하였다. 실험결과, 도금폐수의 수질분석결과에 의하면 '수질환경보존법 오염물질 배출허용기준' <가>지역 방출수 기준을 초과하는 것은 pH, Zn, Fe, Cu, Cr 및 P였다. 실험 결과 인회석 40번체 통과분-100번체 잔류분을 사용하는 것이 가장 적절할 것으로 생각되며 유속은 1kg의 인회석에 11의 도금폐수를 3시간 동안 반응시키면 경제적, 시간적 측면에서 가장 적절한 것으로 사료된다. 이 경우 pH는 1.98에서 5.30으로 증가하고 Cr, Fe, Cu 및 Zn은 각각 77.10%, 99.58%, 99.39% 및 40.77% 제거되는 것으로 나타났다. 용해율은 0.3619 g/min/kg으로 계산되었다. 그러나 3시간의 반응시간으로는 크롬 및 아연을 기준치 이하로 제거하지 못하므로 인회석 반응조를 다단계로 하는 실험을 수행해 그 결과를 평가해야 할 것이다.

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비굴착 지하배수암거 형태별 지하배수 성능 비교분석 (Comparative Study on the Subsurface Drainage Discharge Performance by the Type of Non-Excavation Subsurface Drainage Culvert)

  • 김현태;유전용;정기열;서동욱
    • 한국농공학회논문집
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    • 제60권6호
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    • pp.73-81
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    • 2018
  • In this study, subsurface discharge performance has been studied through theoretical seepage analysis on four types of culverts that can be installed under the condition of non-excavation, such as (a)perforated pipe(${\Phi}50mm$), (b)perforated pipe+horizontal mat (B50cm) (c)perforated pipe+horizontal mat+vertical gravel(B<10cm), (d)perforated pipe+vertical gravel(B<10cm), and existing typical type (e)perforated pipe with gravel (B40, h=40cm) which can be installed by excavation. The analysis results were as follows. i) Subsurface discharge performance per unit (m) was (a)type 56%, (b) 91%, (c) 96%, (d) 76%, respectively, lower than the value of (e)culvert. ii) However, considering that non-excavation culvert can be installed at a spacing of 5m with the installation cost of the existing excavation culvert at the interval of 10m, it was analyzed that unit subsurface discharge(q) of (a)20.2mm/day(110%), (b)32.8(178%), (c)34.6(188%) (d)27.5(149%) in the four types of non-excavation culvert installed at intervals of 5m under the condition of $ k=10^{-4}cm/s$ was much larger than the amount of (e)type 18.5(100%), existing excavation culvert installed at 10m interval. iii) Through the test construction, peak subsurface drainage discharge($q_p$) was 38.4mm/day, which is larger than the value of design criteria and confirmed that it satisfies the analysis results as well. iv) In particular, it was evaluated that (b)perforated pipe+horizontal mat(B50cm) are low cost, high efficiency subsurface drainage culvert type with sufficient drainage performance(178%).

오존산화를 이용한 폐광산배수 내 용존 중금속 제거에 관한 연구 (Removal of Dissolved Heavy Metals in Abandoned Mine Drainage by Ozone Oxidation System)

  • 서석호;안광호;이정규;김건중;주경훈;라영현;고광백
    • 한국물환경학회지
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    • 제26권5호
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    • pp.725-731
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    • 2010
  • This study was to evaluate the ozone oxidation of dissolved Fe, Mn, $SO{_4}^{2-}$ ions and color in abandoned mining drainage by conducting a bench-scale operation at various reaction times in an ozone reactor. The influent was collected from an abandoned mine drainage (AMD) near the J Mine in Jungsungun, Kangwon Province. The ozone reactor was operated at ozone reaction times of 10, 20 and 30 min with ozone doses of 0.0 and $2.4g\;O_3/hr$. Samples from each effluent from subsequent sand filtration were regularly collected and analyzed for pH, Fe, Mn, Al, Cr, Hg, $SO{_4}^{2-}$, alkalinity, color, ORP, TDS and EC. The effluent concentrations of Fe and Mn from the sand filter were less than 0.1 mg/L, which were below the concentrations on Korean drinking water quality standards (Fe, Mn < 0.30 mg/L). The influent $SO{_4}^{2-}$, concentrations were not noticeably changed during this ozone oxidation. Cr and Hg in the raw wastewater from the abandoned mining drainage were not detected in this study. The experimental result shows that the ozone oxidation of dissolved heavy metals and subsequent sand filtration of metal precipitates are desirable alternative for removing heavy metals in AMD.

잠재 산성황산염토양의 개량에 관한 연구 (Study on the Improvement of Potential Acid Sulfate Soil)

  • 한강완;전재철;조재영;김금희;안열
    • 한국토양비료학회지
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    • 제29권3호
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    • pp.249-254
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    • 1996
  • 잠재성 산성황산여토양의 개량을 위해 표면배수실험, 배수실험, 토양간혼용, 매몰효과를 실험한 결과는 다음과 같다. 1. 잠재 산성황산염토양의 물관리방법에 있어 표면 배수효과는 없었으며, 배수효과는 1일 이상 배수처리구들 보다 1일 간격 배수 처리시 토양 pH가 다소 높게 유지되었으며 벼 생육상태도 양호하였다. 2. 산화된 잠재성 산성황산염토양을 개량하는데 있어 숙답토와의 동비율 혼합구 및 숙답토 30cm 복토구에서는 수도생육피해가 없어 물리적 개량법으로 이용할 수 있었다. 3. 잠재 산성황산염토양을 파낸 후 효과적인 처리방안으로는 숙답토로 30cm이상 복토한 구 및 숙답토 50%이상 혼합토양구에서 수도피해가 없었으므로 숙답에 성토하는 경우 30cm이상 복토처리가 요구된다.

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건설현장 절취사면의 산성배수 발생특성과 잠재적 산발생능력 평가 (Generation Characteristics and Prediction of Acid Rock Drainage(ARD) of Road Cut Slopes)

  • 이규호;김재곤;이진수;전철민;박삼규
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.491-498
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    • 2005
  • Acid Rock Drainage(ARD) is the product formed by the atmospheric(i.e. by water, oxygen and carbon dioxide) oxidation of the relatively common iron-sulphur minerals pyrite($FeS_2$). ARD causes the acidification and heavy metal contamination of water and soil and the reduction of slope stability. In this study the generation characteristics and the prediction of ARD of various road cut slopes were studied. An attempt to classify the rocks into several groups according to their acid generation potentials was made. Acid Base Accounting(ABA) tests, commonly used as a screening tool in ARD predictions, were performed. Sixteen rock samples were classified into PAF(potentially acid forming) group and four rock samples into NAF(non-acid forming) group. The chemical analysis of water samples strongly suggested that ARD with high content of heavy metals and low pH could pollute the ground water and/or stream water.

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배양액의 농도가 배액의 pH와 딸기 '설향' 뿌리의 활성에 미치는 영향 (Effect of Nutrient Solution Strength on pH of Drainage Solution and Root Activity of Strawberry 'Sulhyang' in Hydroponics)

  • 전하준;변미순;류습생;장미순
    • 원예과학기술지
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    • 제29권1호
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    • pp.23-28
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    • 2011
  • 딸기에 적합한 수경재배기술을 개발하기 위하여, 배양액 농도와 뿌리의 활성과의 상관관계를 조사함으로써 딸기에 적정한 배양액의 농도를 구명하고자 하였다. '설향(雪香)' 딸기를 재료로 하여 야마자키 조성 딸기 전용배양액을 0.5, 1.0, $2.0dS{\cdot}m^{-1}$ 농도로 처리하였다. 그리고 투명 플라스틱 포트에 코코피트를 충진하고 처리별로 5주씩 정식하여 딸기의 지상부 및 뿌리의 발달을 관찰하였다. 뿌리의 활력은 TTC(Triphenyl-tetrazoliumchloride)법으로 조사하였다. 엽병장은 EC $1.0dS{\cdot}m^{-1}$ 처리구에서 가장 길었으며, 그 다음 EC 2.0, $0.5dS{\cdot}m^{-1}$ 순으로 나타났다. 엽폭은 EC $1.0dS{\cdot}m^{-1}$ 처리구에서 가장 넓었으며, EC 0.5, $2.0dS{\cdot}m^{-1}$ 순으로 나타났다. 과장, 과경, 과중 및 수량은 EC 0.5와 $1.0dS{\cdot}m^{-1}$ 처리구에서 EC $2.0dS{\cdot}m^{-1}$ 처리구 보다 통계적으로 유의하게 높게 나타났다. 그러나, 당도는 처리 간에 유의한 차이를 나타내지 않았다. 지상부 건물중은 EC $1.0dS{\cdot}m^{-1}$ 처리구에서 가장 높았으며 다음이 $0.5dS{\cdot}m^{-1}$ 처리구, $2.0dS{\cdot}m^{-1}$ 처리구 순으로 나타났다. 지하부의 건물중은 배양액의 농도가 0.5와 $1.0dS{\cdot}m^{-1}$에서 높게 나타났으며, $2.0dS{\cdot}m^{-1}$에서는 현저하게 낮았다. 배액의 산도 변화는 EC $1.0dS{\cdot}m^{-1}$ 처리구는 공급배양액의 pH와 비슷한 경향을 나타내었으나, EC 0.5 처리구에서는 상승하는 경향을 보였고 EC 2.0 처리구에서는 현저하게 낮아지는 경향을 보였다. Formazan의 농도는 EC $1.0dS{\cdot}m^{-1}$ 처리구에서 전 생육기간 동안 가장 높게 나타났으며, EC $2.0dS{\cdot}m^{-1}$ 처리구에서는 현저하게 낮은 경향을 보였다. 이상의 결과에서 '설향'딸기에 가장 적합한 배양액 농도는 EC $1.0dS{\cdot}m^{-1}$에 가까운 것으로 생각되었다. 또한, 배액의 pH는 뿌리의 활성과 직접적인 상관이 있어서, 배액의 pH가 높은 것은 뿌리의 활성이 양호한 것을 시사하고, 배액의 pH가 낮은 것은 뿌리의 활성이 낮은 것을 나타내는 지표가 될 수 있다는 것을 확인하였다. 이러한 결과는 딸기 수경재배에서 생육진단의 지표로 유용하게 활용될 수 있을 것으로 생각된다.

농흉의 임상적 고찰: 59례 보 (Clinical evaluation of thoracic empyema: review of 59 cases)

  • 김현순
    • Journal of Chest Surgery
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    • 제15권3호
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    • pp.274-277
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    • 1982
  • A Clinical analysis of 59 patients of thoracic empyema was done who were received surgical intervention at dept. of thoracic surgery of the C.A.F.G.H. in the period of 2.5 years from January 1979 to June 1982. Occurrence ratio of Left and Right side pleural cavity of empyema was 1: 1.4. The predisposing factors of empyema were pulmonary Tbc. [49%], Chest pain [25%], Cough [8%], in order. B.P.F. was associated with empyema in 5 cases. The pleural cavity empyema was treated with several surgical procedures and conservative measures. Among of the 59 cases, the 30 cases [50%] were treated with decortication, 12 cases [20%] with closed thoractomy drainage, 9 cases with frequent thoracenteses, 5 cases with partial decortication and thoracoplasty and 3 cases with open thoracostomy tube drainage. Among of the 59 cases thoracic empyema, the full recovery were in 32 cases [54%], partial recovery in 20 cases [34%], not improved in 3 cases [5%] and 3 cases were died. The mortality rate was 5% and the recovery rate was 89%.

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산성 광산 배수의 처리를 위한 철(Fe) 성분의 플럭 형성 특성 (The Characteristics of Iron(Fe) Floc Formation for Treatment of Acid Mine Drainage)

  • 송근호;이광래
    • 산업기술연구
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    • 제33권A호
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    • pp.89-92
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    • 2013
  • The characteristics of floc formation of the iron(Fe) ions was studied for developing the process treating the acid mine drainage. The metal ions in aqueous solution oxidized with oxygen in air, which generated hydrogen ion and lowered the pH of the aqueous solution. The iron(Fe) ions were formed into flocs by the acid-base reaction with the added $Ca(OH)_2$ for the neutralizing the solution. There were several variables affecting the formation, size and color of floc; whether air was present or not, air feeding rate, oxidizing time, concentration of $Ca(OH)_2$, the acid-base reaction time of the $iron(Fe)-Ca(OH)_2$. For proper formation of the $iron(Fe)-Ca(OH)_2$ flocs and developing the floc treating system, the control variables mentioned above should be considered.

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Development of Silica Based Microgels and Evaluation of Their Performance in Microparticle Retention System

  • Kim, Tae-Young;Lee, Hak-Lae
    • 펄프종이기술
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    • 제32권1호
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    • pp.33-40
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    • 2000
  • The effectiveness of silica-based microgels prepared through the reaction of sulfuric acid and sodium silicate as a component of Compozil system has been evaluated . Silica based microgels with better performance in retention and drainage than a commercial colloidal silica sol have been successfully prepared. Silica gels with the highest charge density were obtained when product pH was controlled to 9. And highly charged silica-based microgels showed greater retention and freeness performance than a commerical product. In particular the difference in retention, turbidity , and freeness between these microgels and a commercial product was eminent at low addition rate. The effects of reaction conditions including reaction temperature, process water quality and feeing rate on product efficiency in improving retention and drainage were also investigated and discussed.

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Management of Mining-related Damages in Abandoned Underground Coal Mine Areas using GIS

  • Kim Y. S.;Kim J. P.;Kim J. A.;Kim W. K.;Yoon S. H.;Choi J. K.
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2004년도 Proceedings of ISRS 2004
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    • pp.253-255
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    • 2004
  • The mining-related damages such as ground subsidence, acid mine drainage(AMD), and deforestation in the abandoned underground coal mine areas become an object of public concern. Therefore, the system to manage the miningrelated damages is needed for the effective drive of rehabilitation activities. The management system for Abandoned Underground Coal Mine using GIS includes the database about mining record and information associated with the mining-related damages and application programs to support mine damage prevention business. Also, this system would support decision-making policy for rehabilitation and provide basic geological data for regional construction works in abandoned underground coal mine areas.

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