• Title/Summary/Keyword: pH Adjustment

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Effect of pH Adjustment by Adding Sulphuric Acid on Chemical Properties in Aerobic Liquefying Process of Co-Digestate of Swine Manure and Apple Pomace (돈분과 사과착즙박의 혼합 혐기소화액의 황산첨가 pH 조절이 호기성 액비화과정에서의 화학적 특성 변화)

  • Ryoo, Jong-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.3
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    • pp.5-14
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    • 2020
  • This study aims to survey the effect of sulphuric acid (H2SO4) treatment for pH adjustment with 6.5 and 7.0 regarding ammonia volatilization on chemical content change in the aerobic liquefying process of co-digesate swine manure and apple pomace. The digestates of swine manure was aerated with 0.3 ㎥ air/㎥·min for 60 days. The untreated digestate showed the increased pH and decreased contents of electrical conductivity (EC) and total nitrogen (T-N). The untreated digestate had a high concentration of NH3 with 172.6 mg/L, but, ammonia (NH3) concentration of H2SO4-treated digestate was significantly lower than that of untreated digestate. The H2SO4-untreated digestate for retaining aeration showed a decreased concentration of 47.2% of ammonium nitrogen. While, the H2SO4-treated digestate had a high concentration of ammonium nitrogen compared to the untreated digestate. Also, the H2SO4 treatment affected to increase the contents of nitrogen and phosphoric acid content. Therefore, the pH adjustment with H2SO4 might be a useful method for the decreased ammonia concentration and nitrogen maintenance in the aerobic liquefying process of swine manure digesate.

The Effects of pH and Alkalinity Adjustment on Internal Corrosion Control and Water Quality in Drinking Water Pipelines (정수의 pH 및 알칼리도 동시 조절이 상수도관의 내부부식 제어 및 수질에 미치는 영향)

  • Lee, Hyun-Dong;Jung, Hae-Ryong;Kwak, Phill-Jae;Chung, Won-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.661-669
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    • 2000
  • This research was carried out to evaluate effect of metallic release and change of water corrosive indices by the pH and alkalinity adjustment using the SDLS (Simulated Distribution Loop System) which consist of six types of pipe loop with DCIP, PVC, PE, STS304, CP, GSP, respectively, and its effects on water quality changes which were microbes quality(SPC), residual chlorine. THMs and other parameters. And it was to propose optimal criteria of water quality control for the field application. According to the results, water control system by pH and alkalinity adjustment showed the changing of corrosive water and reducing of metallic release rate and it was not affects of THMs formation, microbes regrowth and variation of other parameters. Water quality stability and corrosion control were due to calcium carbonate precipitation film formation of pipe inner by water quality control. Therefore, corrosive water control system by pH and alkalinity adjustment can be attributed to effective water quality management in water distribution system according to water quality stability of pH and TIC(Total Inorganic Carbonate concentration) that affect the precipitation and dissolution of solids.

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Thermal Decomposition of A New Insecticide KH-502 [O, O-Diethyl O-(1-phenyl -3-trifluoromethy-5-pyrazoyl) thiophosphoric acid ester] (신규(新規) 살충제(殺蟲劑)인 O, O, O-Diethyl-O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl) thiophosphoric acid ester의 열(熱)에 의한 분해성(分解性))

  • Cho, Boo-Yeon;Han, Dae-Sung
    • Korean Journal of Environmental Agriculture
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    • v.11 no.3
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    • pp.225-234
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    • 1992
  • Thermal decomposition was conducted to investigate the influence of the various factors on stability of a new insecticide, [O, O-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl) thiophosphoric acid ester : KH-502], in view of those informations applicable for industrial exploitation. In the thermal decomposition experiment, KH-502 was, after mixing with Fe, Cu and adjustment of moisture and pH conditions, subjected to three temperatures, 25, 50, and $100^{\circ}C$. Results for stability, and degradation pattern of KH-502 from the above experiment can be summarized as follows: 1. Main products of the thermal decomposition when this was conducted in the closed system were identified as following five compounds:O, O, O-Triethylthiophosphoric acid(TEPA), 1-Phenyl-3-trifluoromethyl-5-ethoxypyrazole(PTMEP), 1-Phenyl-2-ethyl-3-trifluoromethyl-5-hydroxypyrazole(PETMHP), O, O-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl)phosphoric acid ester(KH-502 oxo form), O, S-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl)phospho rothiolate(S-ethyl KH-502). However, compounds such as oxo form and S-ethyl KH-502 were not identified when the thermal decomposition was proceeded in the open system. 2. KH-502 was stable at 25 and 50$^{\circ}C$, but it was decomposed at 100$^{\circ}C$ following the first-order kinetics at the early stages of decomposition. 3. Rate constants for the thermal decomposition of KH-502 at 100$^{\circ}C$ were in the orders of Cu powder addition 0.344>Cu plate addition 0.21>moisture addition 0.05>closed system=open system=iron addition=pH 5.5 adjustment 0.04>pH 8.5 adjustment 0.027 day$^{-1}$, representing KH-502 was decomposed fast at Cu powder treatment and slow at pH 8.5 adjustment. 4. Half-life for the thermal decomposition of KH-502 at 100$^{\circ}C$ was in the orders of Cu powder addition 2.02

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Continuous Decomposition of Ammonia by a Multi Cell-Stacked Electrolyzer with a Self-pH Adjustment Function (자체 pH 조정 기능을 갖는 다단 전해조에 의한 암모니아의 연속식 분해)

  • Kim, Kwang-Wook;Kim, Young-Jun;Kim, In-Tae;Park, Geun-Il;Lee, Eil-Hee
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.352-359
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    • 2005
  • This work has studied the changes of pH in both of anodic and cathodic chambers of a divided cell due to the electrolytic split of water during the ammonia decomposition to nitrogen, and has studied the continuous decomposition characteristics of ammonia in a multi-cell stacked electrolyzer. The electrolytic decomposition of ammonia was much affected by the change of pH of ammonia solution which was caused by the water split reactions. The water split reaction occurred at pH of less than 8 in the anodic chamber with producing proton ions, and occurred at pH of more than 11 in the cathodic chamber with producing hydroxyl ions. The pH of the anodic chamber using an anion exchange membrane was sustained to be higher than that using a cation exchange membrane, which resulted in the higher decomposition of ammonia in the anodic chamber. By using the electrolytic characteristics of the divided cell, a continuous electrolyzer with a self-pH adjustment function was newly devised, where a portion of the ammonia solution from a pHadjustment tank was circulated through the cathodic chambers of the electrolyzer. It enhanced the pH of the ammonia solution fed from the pH-adjustment tank into the anodic chambers of the electrolyzer, which caused a higher decomposition yield of ammonia. And then, based on the electrolyzer, a salt-free ammonia decomposition process was suggested. In that process, ammonia solution could be continuously decomposed into the environmentally-harmless nitrogen gas up to 83%, when chloride ion was added into the ammonia solution.

Quality Characteristics of Chicken Breast Surimi as Affected by Water Washing Time and pH Adjustment

  • Jin, Sang-Keun;Kim, Il-Suk;Choi, Yeung-Joon;Park, Gu-Boo;Yang, Han-Sul
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.3
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    • pp.449-455
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    • 2008
  • This study was carried out to compare the quality properties of chicken breast surimi manufactured by four different procedures/methods. Surimi was made from chicken breast by washing two (T1) or four times (T2) with water as well as by pH adjustments at 3.0 (T3) or 11.0 (T4). The contents of moisture and crude fat were significantly higher in the surimi manufactured from pH-adjusted material than after washing. Again, collagen and yield were significantly higher in chicken breast surimi manufactured from washed than pH-adjusted samples, whereas crude protein was higher in the pH-adjusted than washed surimi samples. There was no significant difference in myofibrillar protein content among the surimi manufactured after different washing times and differences following pH adjustments were found. T4 showed highest myofibrillar protein content rating among the surimi samples. All physical characteristics were higher in pH-adjusted chicken breast surimi than in T1 and T2 washed surimi samples. The pH-adjusted surimi had higher hardness, gumminess and chewiness than washed surimi samples (p<0.05). The chicken breast surimi made by pH adjustments had higher lightness (L*) than when made by washing times, whereas pH 3.0-adjusted surimi samples had lower whiteness (W) then the other surimi samples. Myoglobin content was significantly higher in the surimi manufactured from pH-adjusted chicken breast samples.

Corrosion Control in Water Distribution System using Lime and Carbon Dioxide(I) - Determination of Optimum Operational Conditions in Lime Adding Process (소석회와 CO2를 이용한 상수관로의 부식제어(I) - 소석회 주입공정의 최적 운전인자 도출)

  • Sohn, Byung-Young;Byun, Kyu-Sik;Kim, Young-Il;Lee, Doo-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.373-378
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    • 2008
  • The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to determine the optimum operational condition in lime adding process in water treatment plant(WTP). The mixing time at dissolution tank and sedimentation time at saturator for maintaining optimal turbidity condition of lime supernatant were 60~75 minutes and 75~95 minutes, respectively. There was no difference according to $CO_2$ adding methods such as $CO_2$ saturated water or $CO_2$ gas. But, $CO_2$ saturated water could be convenience at WTP in terms of pH control and quantitative dosing. To minimize generation of calcium carbonate products, the short time interval between adding of lime and $CO_2$ is most important. The lime should be added below 32 mg/l for preventing pH rising and generation of calcium carbonate products at the heating condition.

Effects of Organic Acid Addition on Fruiting Productivity and Primordium Formation in Grifola frondosa (유기산을 이용한 pH 조절 처리가 잎새버섯 자실체 발이 및 생산성에 미치는 영향)

  • Kim, Jeong-Han;Jang, Myoung-Jun
    • The Korean Journal of Mycology
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    • v.47 no.3
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    • pp.233-240
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    • 2019
  • This study was performed to develop a useful method for substrate pH adjustment in bottle cultivation of Grifola frondosa. Four types of organic acid solution-citric acid, malic acid, tartaric acid, and succinic acid-were added at 0.5% to 3.0% (w/v) into the substrate. The pH after the organic acid treatments ranged from 3.8 to 4.8 for the mycelial growth of G. frondosa after sterilization. Supplementation with succinic acid at 0.5% resulted in a shorter cultivation period and higher consistent yields compared to other organic acid treatments. These results indicate that the technique we developed is beneficial for higher production of G. frondosa using bottle cultivation.

Optimization of 4H-SiC DMOSFETs by Adjustment of the Dimensions and Level of the p-base Region (P형 우물 영역의 도핑 농도와 면적에 따른 4H-SiC 기반 DMOSFET 소자 구조의 최적화)

  • Ahn, Jung-Joon;Bahng, Wook;Kim, Sang-Chul;Kim, Nam-Kyun;Jung, Hong-Bae;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.7
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    • pp.513-516
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    • 2010
  • In this work, a study is presented of the static characteristics of 4H-SiC DMOSFETs obtained by adjustment of the p-base region. The structure of this MOSFET was designed by the use of a device simulator (ATLAS, Silvaco.). The static characteristics of SiC DMOSFETs such as the blocking voltages, threshold voltages, on-resistances, and figures of merit were obtained as a function of variations in p-base doping concentration from $1\;{\times}\;10^{17}\;cm^{-3}$ to $5\;{\times}\;10^{17}\;cm^{-3}$ and doping depth from $0.5\;{\mu}m$ to $1.0\;{\mu}m$. It was found that the doping concentration and the depth of P-base region have a close relation with the blocking and threshold voltages. For that reason, silicon carbide DMOSFET structures with highly intensified blocking voltages with good figures of merit can be achieved by adjustment of the p-base depth and doping concentration.

Effects of pH and Gamma Irradiation on the Physicochemical Properties of Corn Starch

  • Kang, Il-Jun;Chung, Cha-Kwon;Sohn, Jeong-In
    • Preventive Nutrition and Food Science
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    • v.4 no.3
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    • pp.175-179
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    • 1999
  • To develop a production method for modified starches with less pollution, pH adjustment and gamma irradiation were applied to commerical corn starch. Blue values were significantly decreased , while alkali number, optical transmittance and solubility markedly increased when gamma irradiation was applied to pH 2 adjusted corn starch. Water binding capacity and swelling power at pH 5 were the highest among the samples. Gelatinization viscosity was considerably affected by gamma irradiation and pH of the starch. Gamma irradiation of pH 2 adjusted starch showed the lowest peak viscosity and the best cooling stability among the tested samples . Therefore, the production of modified starch with low viscosity as well as with sufficient viscosity stability seems feasible by controlling the pH of the starch and gamma irrdiation.

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Electron Microscopical Characteristics of Transglutaminase-treated Raw Skim Milk After pH Adjustment (pH조정후 트랜스글루타미나제로 처리한 탈지 원유의 전자현미경적 특성)

  • Moon, Jeong-Han;Hong, Youn-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.10
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    • pp.1638-1641
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    • 2005
  • In order to develop novel food products or additives using transglutaminase (TGase), some physicochemical and morphological understandings are needed. Raw skim milk was adjusted to pH 5.5, 7.0, and 8.5, and each was treated with microbial TGase for 0, 1, 2, 4, and 8 hours, for the protein structure observation using scanning electron microscope (SEM), The particles of untreated raw skim milk were small and evenly associated. After adjustment of pH to 5.5 and treatment of TGase for 1-hour, the protein particles aggregated widely in a bigger form than that of control. Under the same condition for 2 hours, the particles associated and clustered. The particles gathered widely and became a number of small spherical forms after 4 hours. After 8 hours, they made larger forms than the result of 1-hour treatment, and the aggregation broadened. Under the pH 7.0 and 8.5 conditions with TGase-treatment, the protein Particles fractionated and associated into the bigger masses at 1 hour point, but each piece slowly became smaller and more fractionated until treated time reached 4 hours. After 8 hours, the fragmented protein particles aggregated into larger forms as those on the pH 5.5 condition. In general, the electron microscopical forms of the samples adjusted to pH 5.5 showed smaller than those of pH 7.0 or pH 8.5, It is suggested that the protein particles and textural behavior were influenced by pH, TGase, and reaction time.