• Title/Summary/Keyword: pH 조정

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Evaluation of COD Solubilization and Reduction of Waste Activated Sludge by pH Control (pH 조절을 통한 폐활성 슬러지의 COD 가용화 및 감량화 평가)

  • Kim, Youn Kwon;Moon, Yong Taik;Kim, Ji Yeon;Seo, In Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.5
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    • pp.551-558
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    • 2007
  • From the view point of biological wastewater treatment, C/N ratio is one of the most important factor in biological nutrient removal process. However, municipal sewage in Korea is characterized by extremely low content of carbon source and relatively higher portion of N source. Accordingly, it is necessary to dose external carbon source in order to obtain higher degree of carbon source within the process. In this study, the effects of pH pretreatment as an alternative plan for increasing carbon source on the cell disruption and COD solubility of waste activated sludge were conducted under well defined experimental conditions. During 5 hours, the value of COD solubilization rate ($S_R$) at pH 11.5 is approximately 4.4 times higher than the value of $S_R$ at pH 9.5. It is expected that the level of SCOD increased due to the result from cell disruption. However, VSS/TSS ratio was not significantly changed after 5 hours. As Alkalinity changes gradually from less than 15, 30 and 60 meq NaOH/L, average RBCOD/SCOD fraction showed 34, 36 and 45%,respectively.

Management of nutrient solution based on $NH_4H_2PO_$ concentration in deep flow culture of cherry tomato (방울토마토 담액수경재배시 $NH_4H_2PO_$ 농도에 기초한 배양액 조절)

  • 이문정;김성은;김영식
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1995.10a
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    • pp.89-92
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    • 1995
  • 순환식 수경재배에서 배양액의 조성이나 농도를 정해놓고 일정기간 공급하면 배양액의 pH와 EC의 변화가 생긴다. 보통 배양액의 공급은 재배개시시에 다량 공급하고 그 이후에는 부족한 양만큼을 공급하게 되는데, 시작배양액과 추가배양액의 조성은 같아도 이온의 총량은 다르다. 때문에 재배기간중에 pH의 변화양상이 다르게 나타나는 것이다. 이러한 현상을 피하기 위하여 이온의 총량을 기초로 하여 추가배양액의 이온조성을 조정하여 공급하므로써 배양액의 pH를 안정하게 유지할 수 있을 것으로 추측한다. (중략)

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Effect of pH Adjuster on Adhesion Strength between electroless copper film and Ta diffusion barrier (반도체 배선용 무전해 구리 도금액의 pH 조정제가 접합력에 미치는 영향)

  • Lee, Chang-Myeon;Lee, Hong-Gi;Heo, Jin-Yeong;Song, Dong-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.186-186
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    • 2013
  • 반도체 배선용 무전해 구리 도금에서 pH조정제가 구리피막과 Ta 확산방지막 사이의 접합력에 미치는 영향에 대하여 연구하였다. TMAH로 pH가 조절된 경우 NaOH 사용시에 비하여 높은 접합력을 나타내었다. 면간거리 및 밀도 측정결과 TMAH를 사용한 경우 구리피막이 보다 치밀한 구조임을 확인할 수 있었다. TMAH 사용시의 높은 접합력은 NaOH을 사용 한 경우에 비하여 무전해 구리피막이 보다 낮은 내부응력을 갖기 때문으로 판단되었다. pH조정제에 따른 내부응력의 변화를 결정구조의 관점에서 자세히 고찰하였다.

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The Optimum Levels of Alkaline Hydrogen Peroxide Treatment of Rice Straw for Feed (볏짚 사료가치 증진을 위한 알카리성 과산화수소의 적정 처리수준)

  • Choi, Yoon-Hee;Kim, Myeong-Sook;Hong, Jai-Sik
    • Applied Biological Chemistry
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    • v.37 no.5
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    • pp.320-325
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    • 1994
  • These studies were conducted to investigate the chemical composition changes in in vitro digestibility for the improvement of nutritive value of rice straw by alkaline hydrogen peroxide. The content of neutral detergent fiber (NDF), acid detergent fiber (ADF), hemicellulose, cellulose and lignin in rice straw was decreased with higher level of $H_2O_2\;(pH 11.5)$. The content of ADF, cellulose and ash of the rice straw washed after $H_2O_2\;(pH 11.5)$ treatment tended to be increased but NDF, hemicellulose and lignin were decreased with higher concentration of $H_2O_2\;(pH 11.5)$. In the rice straw washed after alkaline hydrogen peroxide treatment the decomposition of cellulose and lignin was effective in $pH\;11.5{\sim}12.5$, in smaller cutting size and $55^{\circ}C$. The in vitro organic matter digestibility was increased with higher $H_2O_2$ concentration and smaller cutting size of rice straw.

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Determination of Sulfur Requirement to Adjust pH of Alkaline Soil by Buffer Curve Method (알칼리성 토양 pH 교정시 완충곡선법을 이용한 황 시용량 결정)

  • Lee, In-Bog;Lim, Jae-Hyun;Yiem, Myoung-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.405-415
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    • 2000
  • To determine application rate of elemental sulfur to adjust pH of alkaline soil, buffer curve method was investigated. The elemental sulfur required to control pH 8.3 to pH 6.3 by buffer curve calculation was treated in two soils of silty loam and sandy loam, and the sulfur-mixed soils were moistened with 50% of water holding capacity during incubation of 6 weeks at $30^{\circ}C$. Soil pH was lowered with incubation and reached to target point after 4 weeks of incubation, and elemental sulfur was oxidised entirely to sulfate. This means that buffer curve has the accuracy to determine sulfur application rate in alkaline soil. However it is estimated that application rate of sulfur should be carefully determined in the field scale. Excess application of elemental sulfur resulted in extremely low soil pH and caused the hinderance of lettuce growth by nutritional imbalance and ion toxicity. To simplify the determination procedure of sulfur requirement, buffer curve method by addition of 0.1N-HCl solution as unit of mL was developed, it was compared with theroutine methods which diluted $H_2SO_4$ solution and $Ca(OH)_2$ are added as cmolc per kg soil to adjust each pH step. Buffer capacities, cmolc kg $soil^{-1}$ $pH^{-1}$, calculated from two buffer curves were not significantly different. The result indicates that buffer curve method by 0.1N-HCl can be used to adjust high pH of alkaline soil.

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1,3-Propanediol Fermentation using the by-Products from Fat Industry (글리세롤을 함유한 유지산업 부산물의 1,3-propanediol 발효)

  • 김철호;김승환;김세정;박건규;이상기
    • KSBB Journal
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    • v.17 no.3
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    • pp.255-260
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    • 2002
  • 1,3-Propanediol as a bifunctional organic compound could be used in polymerization reactions producing polyesters and polyurethanes. Byproduct containing high concentration of glycerol from fat industry was used to produce 1,3-propanediol in lower production cost as well as waste treatment. In this study, various attempts were made to increase 1,3-propanediol production under different conditions using Klebsiella pneumoniae ATCC 15380. The conversion yield and byproduct formation were influenced significantly by the fermentation pH and temperature. The optimal glycerol and nitrogen concentration for 1,3-propanediol production were found to be 25 a/L and 1%(w/v), respectively. The formation of 1,3-propanediol was optimal at pH 6.0 and temperature $35^{\circ}C$. 1,3-Propanediol production from byproduct from 2.5% glycerol was lower than that of 2.5% commercial glycerol and amounted only to 9.84 a/L from byproduct, while to 12.13 a/L from commercial glycerol.

Browning Pattern and Pigment of Glucose/Glycine Model Systems (글루코스-글리신 혼합용액의 갈색화 패턴 및 색소)

  • Nam, Sang-Sook;Lee, Mie-Soon
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.218-222
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    • 1984
  • Browning pattern was developed in aqueous solutions of glucose/glycine mixture under controlled conditions. Browning pattern was definitely influenced by pH of medium and concentration of reactants. Filter paper disks were immersed in diluted solutions of glucose/glycine system and fried in cooking oil. Concentrations of reactants only affected browning pattern of fried filter paper disks and pH effect was obscured at high temperatures. Amorphous brown precipitate was obtained from the lowest pH medium of glucose/glycine system. An attempt was made to characterize the brown pigment produced in the present model system.

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Studies on the Solubility Phenomenon and Activities of Silk Cocoon Sericin through the Filature Water Conditions. (제사용수의 수질이 견층세리신의 용해에 미치는 거동구명에 관한 연구)

  • 김병호
    • Journal of Sericultural and Entomological Science
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    • v.16 no.2
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    • pp.77-98
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    • 1974
  • This study was carried out ill an attempt to investigate the properties and activities of sericin obtained from silk cocoon shells in silk reeling water through various instrumental analyses. In addition, the effects of the characteristics in sericin solubility on the reeling process and silk qualities were also studied on the basis of tile above conditions. The results obtained are as follows: I. The sericin properties and activities through various analytical instruments. 1. The water solubility of each amino acid such as serine, glycine. glutamic and aspartic acids against the pH modified water by using automatic amino acid analyzer, showed the lowest solubility at PH 5, but it increased according to drifting toward the alkalinity. 2. When the obtained sericin particles by water pH variation were observed with the electronic microscope, it was found for the sericin Particles to expand in the alkaline regions. 3. The IR spectrum results showed the differences among the pH modified sericin solutions at the range of 2,100cm-1 and 1.890cm-1 of wave number. 4. The existence of sericin with in silk fabrics made differences in the X-ray interference intencity, that is, the non-degummed fabrics had the interference peak at 2$\theta$=14$^{\circ}$, 17$^{\circ}$, 24$^{\circ}$, and the degummed ones had it at 2$\theta$=17$^{\circ}$, 18$^{\circ}$, 20$^{\circ}$, 23$^{\circ}$, 26$^{\circ}$. II. The results of sericin solubility for silk reeling process. 1. The sericin solubility and swelling had a tendency to increase up with high M-alkalinity and pH value of water. But in case of acidity. water hardness and concentration of ethylene glycol were high, the sericin solubility and swelling were decreased. 2. With the filature experiments, the best conditions of filature orator are summarized as fellows ; a. pH; 6.9${\pm}$0.2 d. acidity; below10ppm b. total hardness; 55:5ppm e. Fe ion; none c. M-alkalinity; 40${\pm}$10ppm

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Antimicrobial Activity of Citral against Salmonella Typhimurium and Staphylococcus aureus (살모넬라와 황색포도상구균에 대한 시트랄의 항균효과)

  • Kim, Jung-Jee;In, Ye-Won;Oh, Se-Wook
    • Korean Journal of Food Science and Technology
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    • v.43 no.6
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    • pp.791-794
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    • 2011
  • The aim of this study was to investigate the antimicrobial characteristics of citral against Salmonella Typhimurium and Staphylococcus aureus. Antimicrobial activities were determined according to the citral concentration and initial pH. The tested citral concentrations were 0-1,000 ppm in tryptic soy broth (TSB) and 0-5,000 ppm in Angelica keiskei juice (NokJeup). The initial pHs tested were 4-7. Antimicrobial activities increased as citral concentration increased. S. aureus was more susceptible than S. Typhimurium during culture in TSB. But S. aureus was less susceptible to pH changes. Citral caused about 1-2 log reduction of S. aureus and 2-5 log reduction of S. Typhimurium after 10 min exposure at different pHs. As the citral concentration in the Algelica keiskei juice increased, S. aureus was easily inactivated but S. Typhimurium was not inactivated.