• Title/Summary/Keyword: ozone-chlorine

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A Study on the Refrigerant Characteristics of the HFC-l52a, and Azeotrope Mixed with $CF_3 I$ (HFC-152a와 HFC-1523에 $CF_3 I$를 혼합한 공비혼합냉매 특성에 관한 연구)

  • 이종인;하옥남;김재열;이연신;권일욱
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.6
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    • pp.102-108
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    • 2001
  • To prevent green house effect and destruction of an ozone layer, an ozone destruction potential(OBP) must be zero and a refrigerant for low global warming potential(GWP) is needed. HFC-l34a, in which hydrogen is mixed instead of chlorine is a refrigerant used for automobile conditioners and its destruction potential is ecologically zero. However, it is not consid- ered as a perfect substitutive refrigerant as its GWP is high. It is studied refrigerant mixtures in which HFC-l52a and $CF_3 I$ in HFC-l52a with low GWP and zero ODP are mixed by experimentally and concluded as follows: 1) With the variation of speed of compressor outside temperature and flow rate, 7he heat of evaporator and compressor and coefficient of perfor- mance was varied, and influenced the air conditioner. 2) The pressure of evaporator was decreased with increasing the speed of compressor and the pressure of evaporator with the refrigerant HFC-l52a was higher 24% than that of azotrope refrigerant mixed with $CF_3 I$

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Formation Mechanism of Chlorate ($ClO_3\;^-$) by Electrochemical Process (전기화학적 공정에 의한 클로레이트의 생성메커니즘)

  • Baek, Ko-Woon;Jung, Yeon-Jung;Kang, Joon-Wun;Oh, Byung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.627-634
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    • 2009
  • This study was done to find out the formation mechanism of chlorate by electrochemical process using chloride ion ($Cl^-$) as an electrolyte. Firstly, the effective factors such as pH and initial chloride concentration were figured out to see the formation property of chlorate during electrolysis. And the relation of free chlorine, and mixed oxidants such as OH radical and ozone with chlorate were estimated to concretize the formation mechanism. As a result, it was found that the major reaction of chlorate formation would be electrochemical reaction with free chlorine, and also the direct oxidation of chloride ion and the reaction by OH radical were participated in the formation of chlorate. Moreover, it was observed that formed chlorate was oxidized to perchlorate. Lastly, the optimum condition was recommended by comparing free chlorine with chlorate concentration during the electrochemical process with the different electrode separation.

Leaching of Ruthenium by Electro-generated Chlorine Gas by Electrochemical Method (전기화학법(電氣化學法)에 의해 생성(生成)된 전해생성(電解生成) 염소(鹽素)를 이용한 루테늄의 침출(浸出))

  • Ahn, Jong-Gwan;Lee, Ah-Rum;Kim, Min-Seuk;Ahn, Jae-Woo;Lee, Jae-Ryeoung
    • Resources Recycling
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    • v.22 no.6
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    • pp.55-63
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    • 2013
  • In this study, a electrochemical-chemical combined dissolution technology was conducted by electro-generated chlorine to obtain ruthenium solution from ruthenium metal. To find out the optimum leaching conditions of ruthenium in chloride solution, this leaching process was carried out on the variation of pH, reaction time, temperature and applied voltage at the electro-generated chlorine system in the reaction bath. Also, ozone generator was used to obtain ruthenium(III) chloride solution to increase the leaching rate. The optimum condition was observed at pH 10.0, $40^{\circ}C$ within 1 hr of reaction time that more than 88% of ruthenium(III) chloride dissolved.

The Removal of Natural Organic Matter and Disinfection By-Product Precursor by Ozone (오존처리에 의한 천연유기물질 변화 및 염소 소독부산물 전구물질 제어)

  • Son, Hee-Jong;Roh, Jae-Soon;Kim, Sang-Goo;Kang, Lim-Seok;Lee, Yong-Doo
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1099-1107
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    • 2005
  • The purpose of this study was to find the transformation of organic matter as well as chlorine by product formation potential with ozone dosage. The removal percents of $UV_{254}$ and DOC were $23%{\sim}65%$ and $2%{\sim}15%$ and THMFP and HAAFP were $17%{\sim}52%$ and $9%{\sim}29%$ respectively at $0.5{\sim}3\;mgO_3/mgDOC$ ozone dosage. The hydrophobic and transphobic organic matter were reduced to $37%{\sim}68%$ and $35%{\sim}64%$, on the other hand the hydrophilir organic matter was increased to $40%{\sim}49%$ at $0.5{\sim}3\;mgO_3/mgDOC$ ozone dosage. The produced THMFP and HAAFP from the hydrophobic and transphilic organic matter were decreased greatly with increasing ozone dosage but these by products were increased in the hydrophilic matter. The produced THMFP and HAAFP per unit DOC were decreased and reactivity was reduced greatly with increasing crone dosage. The removal rate of THMFP per unit DOC was much higher than HAAFP by ozone treatment. The Br-THMFP per unit DOC was much more removed than chloroformFP per unit DOC with increasing ozone dosage. and The removal rate of TCAAFP per unit DOC was increased with increasing ozone dosage but TCAAFP was not affected by ozone treatment. Br-HAAFP was decreased at $1\;mgO_3/mgDOC$ ozone dosage but was not more removed above $1\;mgO_3/mgDOC$ ozone dosage. Br-HAAFP had lower removal effect than Br-THMFP by ozone treatment. The optimal ozone dosage can be determined about $1\;mgO_3/mgDOC$ by considering both disinfection by product formation and economical efficiency.

Effect of Chlorine Dioxide, Cold Plasma Gas Sterilization and MAP Treatment on the Quality and Microbiological Changes of Paprika During Storage (이산화염소 및 저온 플라즈마 가스 살균 및 MAP 처리가 파프리카의 저장 중 품질과 미생물학적 변화에 미치는 영향)

  • In-Lee, Choi;Joo Hwan, Lee;Yong Beom, Kwon;Yoo Han, Roh;Ho-Min, Kang
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.3
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    • pp.223-229
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    • 2022
  • This study was conducted to investigate the effect of packaging methods and sterilization treatment on storability and microbial control in paprika fruits. When treated with chlorine dioxide gas for 3, 6, and 12 hours and cold plasma gas for 1, 3, and 6 hours, and then packed in a carton box and stored in a 8 ± 1℃ chamber for 7 days, chlorine dioxide treated 12 hours and plasma treated 6 hours was prevented the development of E·coli and YM(yeast and mold). Accordingly, the control was treated with chlorine dioxide for 12 hours and plasma for 6 hours, packed using a carton box and 40,000 cc·m-2·day-1·atm-1 OTR film (MAP), and stored in a 8 ± 1℃ chamber for 20 days. Fresh weight loss rate during storage was less than 1% in the MAP treatments, and the visual quality of the MAP treatments was above the marketability limit until the end of storage. There was no difference in the contents of oxygen, carbon dioxide, and ethylene in the film. In the case of firmness, the chlorine dioxide treatments was low, and the Hunter a* value, which showed chromaticity, was highest in the Plasma 6h MAP treatment. Off-odor was investigated in the MAP treatments, but it was very low. The rate of mold growth on the fruit stalk of paprika was the fastest and highest in the chlorine dioxide treated box packaging treatments, and the lowest in the chlorine dioxide treated MAP treatments at the end of storage. The aerobic count in the pulp on the storage end date was the lowest in the plasma treated box packaging treatments, the lowest number of E·coli in the chlorine dioxide treated MAP treatments, and the lowest yeast & mold in the chlorine dioxide treated box packaging treatments. As a result, for the inhibition of microorganisms during paprika storage, it is considered appropriate to treat plasma for 6 hours before storage regardless of the packaging method.

The Review on the Washing System of Herb medicine (한약재 세척 방법에 관한 연구)

  • Hyun, Ja-Kyoung;Seo, Young-Bae
    • Journal of Haehwa Medicine
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    • v.20 no.1
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    • pp.161-174
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    • 2011
  • Objectives : This paper researched methods of washing Herb medicine through research papers of washing Crops Materials and Methods : We collected research papers on Washing crops. Then we analysed them according to washing methods. Results : The following results were obtained in this study. 1. Herbal fruit, wash using a conveyor belt. 2. Leafy herbs, soak in a chlorine solution or ozone solution and rinse it. sometimes using micro bubble system. 3. Radix, wash with high pressure sprinkling water. 4. Cortex, wash under running water by hand washing. Conclusion : Herb medicines need a washing methods for each region. so Herbs should be washed in a suitable methods for each region.

Effect of Ozone, Ultraviolet light and Chlorine on Lettuce Growth and Nutrient Solution Sterilizing in Hydroponics (오존, 자외선 및 염소처리가 수경재배 상추의 생육 및 배양액의 살균효과에 미치는 영향)

  • 이중환;정종도;서동환;최경배;전하준
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 2002.11a
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    • pp.241-245
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    • 2002
  • 최근 시설재배에서는 염류 집적 및 토양전염성 병해충 등으로 인한 연작장해를 회피하기 위하여 수경재배로 전환하는 농가가 급속히 증가하고 있다. 우리나라의 수경재배면적은 '98년 23 ha에서 2000년 1,000 ha로 급속히 증가하고 있는데, 이중 약 12%는 담액수경이나 박막수경의 순수 수경재배 방식이 차지하고 있으나 대부분이 고형배지를 이용한 비순환방식이다. 배양액의 비순환방식은 토양이나 지하수의 오염이 염려되지만, 순환방식의 경우에는 배양액 성분의 조정이나 배양액의 소독 등재처리가 필요하여 농가에서는 기피하고 있는 실정이다. (중략)

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Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry

  • Park, Jong-Ho;Ivanov, Andrey V.;Molina, Mario J.
    • Mass Spectrometry Letters
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    • v.3 no.4
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    • pp.108-111
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    • 2012
  • An experimental study on the nascent product of the OH heterogeneous reaction with NaCl was performed under dry and wet conditions using a bead-filled flow tube system coupled to a high-pressure chemical ionization mass spectrometer. The ozone concentration in the flow tube for the atomic hydrogen removal was varied in order to control the conversion reaction of molecular chlorine into HCl for the identification of the nascent product. The mass spectrometric observation was that the $O_3$ introduction reduced the concentration HCl, while it increased the concentration of $Cl_2$ and ClO. Based on the experimental results, we suggest that the nascent product of the titled reaction is gaseous $Cl_2$, which is followed by fast conversion into HCl in presence of H. No significant difference in the concentration profile between under dry and wet (RH = 2%) conditions was observed.

The Effect of Porosity of Seiving Particles on the Romoval Efficiency of Organic Substances via Biofilter in the Fixed Bed

  • Park Young Gyu
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.31-37
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    • 2002
  • This paper was investigated to clarify the possibility of a biodegradation of materials adsorbed on different porous granular-activated carbons (GACs) such as coal-& coconut-based GAC. Total organic carbon, humic substance and ammonia were used to compare their removal efficiencies. The objective of this study is to determine the adsorption capacity of bioregenerated GAC. When raw water reacted with chloride, the yield of THMs increased as a function of the input amount of chloride. The formation of trihalomethanes (THMs) was investigated in water treated with chlorine when humic acid was used as THM precursor. As the input amount of chloride in raw water increased by two or five-fold to remove the $NH_3$, the chloroform of the THMs significantly increased also five or ten-fold. It was found that the chloroform was significantly removed by the treatment of biological activated carbon (BAG) in comparison with the ozone treatment, and the removal efficiency of THMs in coal-typed GAC was $10-30\%$ better than coconut-typed GAC due to the biological degradation on the surface of the activated carbons.

Reinforcing Performance of Networked Silicas in Silica-filled Chloroprene Rubber Compounds

  • Ryu, Changseok;Yang, Jae-Kyoung;Park, Wonhyeong;Kim, Sun Jung;Kim, Doil;Seo, Gon;Kim, Wook-Soo;Ahn, Ki Woong;Kim, Beak Hwan
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.40-53
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    • 2019
  • The physical properties of chloroprene rubber (CR) compounds reinforced with networked silicas were investigated by comparing them to those reinforced with conventional silica to observe the effect of the organic connection bonds combining silica particles on their cure, tensile, and aging performance. The introduction of networked silica to CR increase in silica content to 80 phr in rubber, while the content of conventional silica was limited to 60 phr. The CR compounds reinforced with networked silica showed higher resistance to combustion. The gradual increases in delta torque, Mooney viscosity, and modulus of silica-filled CR compounds with silica content were mainly attributed to the specific interaction between the chlorine atoms of CR and the hydroxyl groups of silica. The CR compounds reinforced with networked silica showed low compression set and heat build-up and maintained their high modulus even after thermal, oil, and ozone aging.