• 제목/요약/키워드: ozone water

검색결과 583건 처리시간 0.02초

Application of ozone treatment in cooling water systems for energy and chemical conservation

  • Ataei, Abtin;Mirsaeed, Morteza Ghazi;Choi, Jun-Ki;Lashkarboluki, Reza
    • Advances in environmental research
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    • 제4권3호
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    • pp.155-172
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    • 2015
  • In this study, a complete set of recirculating cooling water system and the required instruments were built in a semi-industrial-scale and a 50 g/h ozone generation plant and a chlorine system were designed for cooling water treatment. Both chlorination and ozonation treatment methods were studied and the results were analyzed during two 45-days periods. The concentrations of ozone and chlorine in recirculating water were constant at 0.1 mg/lit and 0.6 mg/lit, respectively. In ozone treatment, by increasing the concentration cycle to 33%, the total water consumption decreased by 26% while 11.5% higher energy efficiency achieved thanks to a better elimination of bio-films. In case of Carbon Steel, the corrosion rate reached to 0.012 mm/yr and 0.025 mm/yr for the ozonation and chlorination processes, respectively. Furthermore, consumptions of the anti-corrosion and anti-sedimentation materials in the ozone cooling water treatment were reduced about 60% without using any oxidant and non-oxidant biocides. No significant changes in sediment load were seen in ozonation compared to chlorination. The Chemical Oxygen Demand of the blow-down in ozonation method decreased to one-sixth of that in the chlorination method. Moreover, the soluble iron and water turbidity in the ozonation method were reduced by 97.5% and 70%, respectively. Although no anaerobic bacteria were seen in the cooling water at the proper concentration range of ozone and chlorine, the aerobic bacteria in chlorine and ozone treatment methods were 900 and 200 CFU/ml, respectively. The results showed that the payback time for the ozone treatment is about 2.6 years.

Design Optimization of an Ozone Contactor Using Ozone Contactor Model (OCM) Software

  • Kim, Doo-Il;Lee, Chae-Young;Joe, Woo-Hyeun;Lee, Seock-Heon
    • Environmental Engineering Research
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    • 제14권4호
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    • pp.244-249
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    • 2009
  • Designing an ozone contactor is complicated because the residual ozone, log C. parvum inactivation, and bromate formation should be optimized with fluctuating water quality. OCM software was developed to assist a plant designer or an operator to fulfill the sophisticated optimization required in the design or operation of a new or an existing plant. In this article, numerical simulations were carried out using the OCM software for the design of a new ozone contactor under diverse design factors (i.e., three pHs, three temperatures, low and high dispersion numbers, and four and ten cells with complete mixing) with kinetic parameters obtained from the sand-filter effluent of a water treatment plant treating water from the Paldang impoundment. The results of the simulation suggested that a high residual ozone concentration at low pH and low temperature would be challenging, and PFR-like hydrodynamics could lower the residual ozone concentration. The inactivation of C. parvum oocysts increased at a lower pH. A lower dispersion number and more cell division increased the inactivation efficiency. Bromate was instantaneously formed during the initial ozonation stage. The effluent concentration was much lower than the regulatory levels imposed by the USEPA because of the low bromide level in raw water.

BAC탑(塔)에서의 BDOC 분해특성(分解特性) (Characteristics on the decomposition of BDOC in the BAC tower)

  • 김동윤;이상봉
    • 상하수도학회지
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    • 제12권3호
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    • pp.21-29
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    • 1998
  • The ozone/GAC process, sometimes termed BAC(Biological Activated Carbon) appeared to be effective for the removal of soluble organic matters in the drinking water Chabrol is a simple model for the simulation like as the variation of HPC and BDOC in the BAC tower. This study were carried out to calibrate of HPC and BDOC and to evaluate $H_1$ and $H_2$ of ozone-treated water with Chabrol model. BDOC values of the ozone-treated water and BAC effluent are analyzed using method of Levi and Joret. As the ozone-treated water and BAC Effluent are incubated, the HPC are increased up to 0.24 mgC/l and 0.09 mgC/l respectively. $H_1$ and $H_2$ of the ozone-treated water is 0.3 mgC/l and 0.349 mgC/l respectively and Chabrol model for BAC tower can be calibrated.

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식품 가공 공정에서의 오존수 관리 동향, 사용 실태 및 활용 방안 (Application, Utilization and Management of Ozone Water in Food Manufacturing)

  • 김용수;박인숙;김애영;전경민;서유미;최성희;이영자;최현철;전대훈;김형일;하상도
    • 한국식품위생안전성학회지
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    • 제23권2호
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    • pp.98-107
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    • 2008
  • 오존은 불소 다음으로 강력한 산화력을 가지고 있으며 넓은 범위의 살균 스펙트럼을 가진 성분이다. 식품산업을 포함한 다양한 분야에서 오존이 가진 장점을 이용하기 위한 연구가 진행되었고 지금도 효율적인 이용을 위한 많은 연구들이 이루어지고 있다. 오존은 미국, 호주 및 일본 등에서는 이미 식품첨가물로 허가되어 사용되고, 국내에서도 2007년 11월에 오존수를 식품첨가물로 허가하면서 국내 식품산업계에서 오존수 이용에 대한 관심이 증가되고 있다. 오존을 이용한 살균방법은 다른 방법들과 비교해보면 초기 설비비에 비해 유지관리비가 저렴하고, 사용 후 부산물이 거의 없다는 장점을 가지고 있으며, 최근의 식품안전 요구증대와 맞물려 그 수요가 증가될 전망이다. 국내에서 오존수는 과일, 채소, 식육 등 식품의 원재료 처리하는 살균용제로서 주로 사용되고 있으나 실태조사의 결과에 따르면 이용사례는 극히 제한적이었다. 그러나 오존수 생성 기계장치의 국내 시장이 급속도로 확대되면서, 단체급식을 중심으로 점차 사용이 증가되고 있는 추세이다. 오존수는 오존을 좀 더 편리하게 이용할 수 있도록 물에 용존 시킨 상태를 말한다. 따라서 오존수는 오존의 용존량과 용존된 오존의 지속시간 등에 대하여 철저히 관리되어야 하며, 안전한 사용을 위해서는 배오존 농도 관리도 필요하다. 상기 관리항목들은 대부분이 기계장치의 자체성능과 직결되는 것이기 때문에 오존수 제조장치의 성능기준을 새롭게 정립할 필요가 있다.

CFD에 의한 수직형 정수처리 실증시설 내 압력식 오존접촉조 성능개선에 관한 연구 (Study on performance improved design of pressure-type ozone contactor in multistorey water treatment plant by CFD)

  • 최종웅;김성수;김정현;김관엽
    • 상하수도학회지
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    • 제28권4호
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    • pp.431-440
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    • 2014
  • The ozonation process has been widely used for drinking water disinfection around the world. Recently, the pressurized ozone contactor, in which the side stream typed ozone injection method is installed, has been applied to water treatment system. In this study, numerical calculations were conducted to compare prototype and screw-type ozone contactors based on hydraulic effectiveness in more details. The prototype ozone contactor was already installed and operated in domestic water treatment plant, and the screw-type is the suggested one for improving ozone contact efficiency installing the screw plate to the prototype. Screw turn numbers of screw plate were changed as 3, 5, 7 and 9, respectively for numerical simulation. The CT(concentration of disinfectant in mg/L times time in minutes) value was considered as one of the options for evaluating disinfection ability. From the results, it could be concluded that the performance of the screw-type is higher than that of the protype contactor by controlling the variable T as the tracer time. Also, Morill index of the screw-type(turn numbers = 5 ) appeared to be lower than the other.

낙동강 상수원수의 오존처리 효과 - II. 회분식 오존처리에 의한 휘발성유기화합물 및 조류제거 효과 - (Effect of Ozone Treatment for Nakdong River Raw Water - II. Removal of VOCs and Algae in Raw Water by Conducting Batch Test of Ozonation Experiments -)

  • 임영성;이홍재;이도진;허종수;손보균;조주식
    • 한국환경과학회지
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    • 제11권12호
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    • pp.1267-1274
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    • 2002
  • This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation process. For raw water, Nakdong River was used. By conducting batch test of ozonation, the following results were obtained. When ozone dosage of $5 mg/{\ell}$ was used, ozone transfer and utilization efficiencies of the ozonation were 94 to 92%, respectively. Removal efficiencies of single VOC compound or mixed VOC compounds in the raw water were 80% to 90% by the ozonation with $2 mg/{\ell}$ dosage and 10 minutes contact time. Removal efficiencies of ABS by the ozonation with $1 mg/{\ell}$, $3 mg/{\ell}$ dosage and 20 minutes contact time were 83% to 96%, respectively. Almost 67% of chlorophyll-a at the concentration of $38.4\mu\textrm{g}/{\ell}$ was removed by ozonation at ozone dosage of $1 mg/{\ell}$ for 20 min. Considering the efficiency of ozone utilization and water treatment, the most effective ozonation could be obtained with high ozone dosage and short contact time.

전오존과 중공사형 한외여과막을 이용한 간이정수처리시스템에 관한 연구 (A Study on the Potable Water Purification System with Pre-Ozone and Ultra Filtration Membrane of Hollow Fiber Type)

  • 김민국;전양근
    • 한국물환경학회지
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    • 제21권2호
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    • pp.196-204
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    • 2005
  • The objective of this study is to evaluate the possibility to apply pre-ozone and membrane system for drinking water. This system is improved in fouling control by pre-ozone system. It is composed of ultrafiltration hollow fiber type membrane and ozone reactor. The result of this study is that the flux is increased about 10.7% and decreased in TMP by the pre-ozone. Also, backwashing pressure decreased about 18%. The optimum concentration of residual ozone is 0.3~0.5 ppm. During the period, the recovery ratio of this system was turned out to be 90% as the flowrate of effluent is $67.1m^3/day$. When the TMP and backwashing pressure was $0.85kg/cm^2$ and $1.10kg/cm^2$, this system was stable without sudden fouling. Finally, the quality of effluent is satisfied the guidelines for potable water quality such as turbidity, color, E.coli, Mn, Al, Fe and so on.

Effect of nanobubbles (oxygen, ozone) on the Pacific white shrimp (Penaeus vannamei), Vibrio parahaemolyticus and water quality under lab conditions

  • Nguyen, Huu Nghia;Nguyen, Thi Nguyen;Phan, Trong Binh;Le, Thi May;Tong, Tran Huy;Pham, Thai Giang;St-Hilaire, Sophie;Phan, Thi Van
    • Fisheries and Aquatic Sciences
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    • 제25권8호
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    • pp.429-440
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    • 2022
  • This study assessed the effects of oxygen and ozone nanobubbles on gill morphology, weight gain, and mortality of Pacific white shrimp (Penaeus vannamei), as well as the level of Vibrio parahaemolyticus and water quality of shrimp culture tanks under lab conditions. Two experiments were carried out with oxygen macrobubble, ozone macrobubble, oxygen nanobubble, ozone nanobubble, and control treatments (air-stone macrobubble). Experiments were done in triplicate in 100 L tanks with 15‰ saline water, and 20 shrimp per tank. Tanks in Experiment 1 were not inoculated with bacteria; tanks in Experiment 2 were inoculated with V. parahaemolyticus at a concentration of 106 CFU/mL. The results revealed that short treatments with ozone nanobubbles had minimal impact on shrimp gills, mortality, and growth rates, reduced V. parahaemolyticus concentration in water compared to the other groups, and improve water quality. These laboratory results indicate that ozone nanobubble treatment may be useful for controlling V. parahaemolyticus. More work is needed to find the best protocol to apply the technology on a commercial scale.

수중 미량 잔류항생물질 Ciprofloxacin, Trimethoprim, Enrofloxacin의 오존산화제거 (Removal of Residual Antibiotics-Ciprofloxacin, Trimethoprim and Enrofloxacin-from Water by Ozone Oxidation)

  • 한민수;최연우;송준혁;왕창근
    • 한국물환경학회지
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    • 제34권2호
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    • pp.149-156
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    • 2018
  • Oxidation of Ciprofloxacin, Trimethoprim, and Enrofloxacin by ozone was experimentally investigated to observe the effects of background water quality (such as ultrapure water, humic acid, and biologically treated wastewater) and water temperature on the removal rate of these antibiotics, and, thereby, to be able to provide design information when the ozone treatment process is adopted. Initial concentrations of the antibiotics spiked to $10{\mu}g/L$, and the ozone dose was 1, 2, 3, 5, and 8 mg/L. While the removal rate of Ciprofloxacin under ultrapure water background by ozone oxidation was over 99%, the removal rate under humic acid and biologically treated wastewater background was markedly lower, in the range of 49.3% ~ 99% and 19.8 % ~ 99 %, respectively. When water temperature is decreased from $20^{\circ}C$ to $4^{\circ}C$, the removal rate is reduced from the range of 19.8% ~ 99 % to the range of 7.5 % ~ 99 % under a biologically treated wastewater background. The effects of background and temperature on the removal rate of Trimethoprim and Enrofloxacin were similar to that of Ciprofloxacin, but the degree was different. Therefore, it is concluded that the background of water to be treated, as well as water temperature, should be taken into consideration when the design factor, such as ozone dose, is determined, so that the treatment objective of the ozone treatment process can be most effectively met.

수중 미량 잔류항생물질 Erythromycin, Sulfamethazine, Sulfathiazole의 오존산화제거 (Removal of Residual Antibiotics - Erythromycin, Sulfamethazine and Sulfathiazole - from water by Ozone Oxidation)

  • 최연우;한민수;송준혁;왕창근
    • 상하수도학회지
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    • 제31권4호
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    • pp.347-356
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    • 2017
  • Oxidation of erythromycin, sulfamethazine and sulfathiazole by ozone was experimentally investigated to see the effects of background water quality such as ultrapure water, humic acid and biologically treated wastewater and water temperature on the removal rate, consequently to provide design information when the ozone treatment process is adopted. Initial concentration of the antibiotics was spiked to $10{\mu}g/l$ and ozone dose was 1, 2, 3, 5, 8 mg/l. While the removal rate of erythromycin under ultrapure water background by ozone oxidation was over 99%, that under humic acid and biologically treated wastewater background was markedly reduced to the range of 59.8%~99% and 17.0%~99%, respectively. When water temperature is decreased from $20^{\circ}C$ to $4^{\circ}C$, the removal rate is reduced from the range of 17.0%~99% to the range of 9.4%~97.4% under biologically treated wastewater background. The effects of background and temperature on the removal rate of sulfamethazine and sulfathiazole were similar to erythromycin, but the degree was different. Therefore, it is concluded that the background of water to be treated as well as water temperature should be taken into consideration when the design factor such as ozone dose is determined to meet the treatment objective in the ozone treatment process.