• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1625-1627
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• 1994

A potential to effective ozone generation for 4 kinds of gap, a hole-to-plate gap, a hole-to-hole gap, a hole-to-rod gap and a plate-to-plate gap in tap water has been investigated. It is found that the hole gaps indicated higher ozone generation compared to that of the plate-to-plate gap. As a result, the hole gaps could be an effective means to generate ozone in water by utilizing both of one generation mechanisms of the discharge and the electrolysis.

• Environmental Engineering Research
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• v.11 no.6
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• pp.293-302
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• 2006

The reaction of ozone with NOM (Natural Organic Matter) can occur by two different pathways: that involving molecular ozone and by way of reactions with hydroxyl radicals which are produced from the decomposition of molecular ozone. As such, the formation of ketoacids and Assimilable Organic Carbon (AOC) can be controlled by controlling the pathway by which ozone reacts with NOM. The ratios of $[OH{\cdot}]/[O_3]$ ($R_{CT}$ values) were determined under the various ozonation conditions. The $R_{CT}$ values increased with increasing initial ozone concentration. The $R_{CT}$ values (ranges from 10 to $35^{\circ}C$) increased linearly as temperature increased (within the range from 10 to $35^{\circ}C$). However, $R_{CT}$ was independent of hydraulic retention time (HRT). Operational conditions were found to affect the formation of AOC. The conditions where the molecular ozone reaction predominated resulted in an increase in the formation of AOC.

• Journal of environmental and Sanitary engineering
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• v.6 no.1
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• pp.103-108
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• 1991

Visibility studies are conducted in oxidizing organic compounds with ozone to investigate the oxidation in the waste and sewage water. While the ozone has been used as one of the major oxidation of the waste and sewage water, it is not effective to distroy the polluted organic compounds with the practical concentration in waste water treatment. The result are shown follows ; 1. Upon oxidizing organic compound with ozone, the former is much oxidized under three meters and the latter under the ABS waste water. 2. In case of being oxidized organics waste water with ozone codis, much removed under medicine and chemical waste water than anothers of primary treatment process. 3. The final treated waste water of oxidizing organics is higher than that of filtered water or sedimented water. Specially in organics waste water the colority after oxidizing decrease from 95% to 99.9% this suggests that any organic compounds produced during ozonation night be dissdved in the final treated waste water.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.50 no.7
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• pp.334-339
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• 2001

A silent type ozone generator using water surface has been studied and improved its ozone generation characteristics by the controlling the height of Taylor cone by installing a mesh electrode, a dielectric bed of glass beads in the just under th surface of the water. The current-voltage characteristics and characteristics of ozone generation quantity of the test system were investigated and discharge current oscillograms of the each cases of the mesh electrode and the beds were observed and compared each other to analyze the discharge conditions. The Taylor cone height could be the cause of the discharge bridge to decrease the ozone generation on the discharge spacing. In this study, the hight of Taylor cone could be reduced greatly by installing the mesh and the glass beads bed just under the water surface. Therefore a higher ozone generation also could be obtained.

• Journal of Korean Society on Water Environment
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• v.28 no.5
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• pp.704-716
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• 2012

This paper provides a detailed account of pilot testing conducted at South Lake Tahoe (California), the Ddukdo (Seoul) water treatment plant (WTP) and the Bokjung (Seongnam) WTP between February, 2010, and February, 2012. The objectives were first, to characterize the reactions of ozone with hydrogen peroxide (Peroxone) for Han River water following sand filtration, second to determine empirical ozone and hydrogen peroxide doses to remove a taste-and-odor surrogate 2-methylisoborneol (MIB) using an advanced oxidation process (AOP) configuration and third, to determine the optimum dosing configuration to reduce residual ozone to a safe level at the exit of the process. The testing was performed in a real-time plant environment at both low- and high seasonal water temperatures. Experimental results including ozone decomposition rates were dependent on temperature and pH, consistent with data reported by other researchers. MIB in post-sand-filtration water was spiked to 40-50 ng/L, and in all cases, it was reduced to below the specified target level (7 ng/liter) and typically non-detect (ND). It was demonstrated that Peroxone could achieve both MIB removal and low effluent ozone residual at ozone+hydrogen peroxide doses less than those for ozone alone. An empirical predictive model, suitable for use by design engineers and operating personnel and for incorporation in plant control systems was developed. Due to a significant reduction in the ozone reaction/decomposition at low winter temperatures, results demonstrate the hydrogen peroxide can be "pre-conditioned" in order to increase initial reaction rates and achieve lower ozone residuals. Results also indicate the method, location and composition of hydrogen peroxide injection is critical to successful implementation of Peroxone without using excessive chemicals or degrading performance.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.4
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• pp.68-75
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• 2018

The introduction of advanced water treatment facilities has increased as the conventional purification method cannot remove the substance clearly. However, the internal waterproofing and Anticorrosion materials of the advanced water treatment facility using ozone deteriorate due to the oxidation power of ozone and affects the concrete, which causes a decrease in durability. This study is to evaluate the ozone resistance according to the type of spray metal and the surface treatment method of the coating, and the bond strength after ozone treatment in order to develope a finishing method to prevent deterioration of concrete structure of water treatment facility using metal spraying method as a way to construct metal panel with excellent ozone resistance and chemical resistance by an easier way than the previous. The Experimental results show that spray metal Ti has superior ozone resistance even after spraying. It is considered to be the most suitable method for ozone resistance and bond performance by finishing using Teflon sealing as surface treatment method.

• Journal of Korean Society of Water and Wastewater
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• v.10 no.4
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• pp.55-63
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• 1996

This research was based on comparing ozonation with combined ozone/ultraviolet oxidation through the methods of reducing THM produced during water treatment. The results were as follows ; 1. The decline of THM concentration was appeared according as ozone dosage increases with ozonation and combined ozone/ultraviolet oxidation. The more effective method was the treatment of irradiating UV then ozonation. In the beginning of reaction the decline rate of THM formation potential was low, I thought it was because that the reaction of ozone and humic acid needed times to be steady state, or that THM formation potential existed according to humic acid. 2. The effect of combined ozone/ultraviolet oxidation when ozone dosage was 4.2mg/L min was almost the same that of ozonation when ozone dosage was 8.6mg/L min. 3. In experiment of TOC decline through ozonation and combined ozone/ultraviolet oxidation, TOC concentration was also dropped according to increasing ozone dosage and the more effective results were showed in treatment of irradiating UV than ozonation. But the similar TOC remove rates were showed in experiment of changing with ozone dosage during combined ozone/ultraviolet oxidation TOC remove rates were low in proportion to the remove rates of THM formation potential, it was considered that humic acid was made low molecule itself though ozonation and ozone/ultraviolet oxidation. Moreover, the high degree of remove efficiency will be get though the treatment of activated carbon of GAC treatment after combined ozone/ultravilet oxidation.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2004.11a
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• pp.339-342
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• 2004

It is research about special quality of ozone gas concentration and dissolved ozone concentration that show according to change of flow rate when liquefied ozone gas in water. If increase flow rate of ozone gas, ozone concentration increases being proportional and amount to fixed flow rate, dissolved ozone concentration was measured low. When ozone concentration How rate 1000 [ppm], dissolved ozone concentration smelted to flow rate 1.5[Q] for 28 [min] is $0.1740{\sim}0.8020[mg/l]$. Could know that half-life is most short by 3 minutes 8 seconds in flow rate 1.5 [Q]. And ozone smelted 20 minutes later after half-life measurement became disjointing all.

• Journal of Life Science
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• v.9 no.5
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• pp.590-595
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• 1999

The objectives of this research were to estimate variation characteristics of TOC, UV-254 and NH4+-N, etc, if odorous generated algaes flowed into water treatment plant and they contacted with ozone known as typical advanced treatment. It was estimated that pH decreased from initial 7.4 to 2.1 after ozone contact 100min. pH declined to early 10min. suddenly and then pH drop did almost occur. TOC and UV-254 continued to decrease with passed time of ozone contact. NO3--N concentration was much higher than NH4+-N and NO2--N for whole test period. Because ozone oxidized organic matters as various kinds of ion material and ion intensity of sample was extended, conductivity showed high as passed time of ozone contact. Owing to ozone oxidation of algae, color did almost disappear after ozone contact 20min.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.111-114
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• 2003

A new monitoring system has been developed for in-situ and realtime measurement of ozone transport in unsaturated porous media using a fiber optic sensor. The calibration of the fiber optic transflection dip probe (FOTDP) system was successfully carried out at various ozone concentrations using a column with length of 30 cm and diameter of 5 cm packed with glass beads, which don't react with gaseous ozone. The breakthrough curves (BTCs) of ozone was obtained by converting the normalized intensity into ozone concentration. The FOTDP system reflected the ideal transport phenomena of gas phase ozone at various flow rates. The FOTDP system worked well for in-situ monitoring of gas phase ozone at various water saturations and in presence of SOM. However, the FOTDP system did not measure the ozone concentration at more than 70% water saturation.