• Title/Summary/Keyword: ozone treatments

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A Study on the Decomposition Rate of Phenol in the Batch Type Ozonation (회분식 오존 공정에서 페놀의 분해 속도에 관한 연구)

  • 안재동;강동수
    • Journal of Environmental Health Sciences
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    • v.23 no.4
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    • pp.127-132
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    • 1997
  • The characteristics of the ozone treatments of phenol were studied in a laboratory scale wastewater treatment system. The ozone treatment of wastewater was carried out in a batch-type reactor. The initial pH of wastewater(7-10), volumetric flow rate(1-2l/min) and ozone concentration(20~30 mg/l) of aerating gas were considereal as experimental variables in the ozone treatment. Phenol was decomposed easily by the ozone in a batch treatment, where the rate determining step was the COD removal that is decomposition of intermediates formed by the ozonation of phenol. Phenol decomposition and COD removal could be expressed by the first order reaction for the phenol concentration and COD, respectively. Rate constants of phenol decomposition and COD removal increased with the initial pH, volumetric flow rate and ozone concentration of aeration gas. Under the present experimental condition, their relationships could be given by for the phenol decomposition $k'=4.46\times 10^{-9}[pH]_o ^{3.94}[O_3]^{1.42}Q_{O3}^{1.57}$ for the COD removal $k=2.46\times 10^{-10}[pH]_o ^{5.19}[O_3]^{1.15}Q_{O3}^{1.19}$

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Ozone Effects on the Mushrooms Yields (버섯 수량성에 미치는 오존의 영향)

  • Chang, Hyun-You
    • Journal of Practical Agriculture & Fisheries Research
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    • v.4 no.1
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    • pp.65-69
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    • 2002
  • The objective of this study was to determine mushrooms yields using ozone. The results of this study showed as follows; 1. According to ozone treatment on the Pleurotus ostreatus growth length of stipe became short, diameter of stipe and pileus yields of fruiting body increase 7% than the control treatments. 2. According to ozone treatment on the Agaricus bisporus growth, length of stipe became short, diameter of stipe and pileus became large, yields of fruiting body had increase 4% than the contol treatment. 3. According to ozone treatment on the Flamulina velutipes growth, day required for primordial formation after inoculation(DPI) became late for 2 days.

Ozone Sensitivity of Physiological Indicators for Stress Evaluation in Four Families of Quercus aliena Blume (갈참나무 4가계에서 스트레스 평가용 생리 지표들의 오존 민감성)

  • Kim, Du-Hyun;Han, Sim-Hee;Lee, Jae-Cheon
    • Journal of Korean Society of Forest Science
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    • v.99 no.6
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    • pp.878-884
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    • 2010
  • Ozone sensitivity of physiological indicators and the difference of ozone tolerance on 4 families of Quercus aliena seedlings were investigated on the basis of the standardized physiological indicators. Photosynthetic parameters, photosynthetic pigment and malondialdehyde (MDA) content, and antioxidative enzyme activities were measured or analyzed from the leaves of Q. aliena seedlings at the end of ozone fumigation, and ozone tolerance indices among 4 families were calculated with the standardized physiological parameters. After ozone treatment, the reduction of carboxylation efficiency was observed in the leaves of four families, and their reduction were ranged from -24.1% to -56.9% of control seedlings. Photosynthetic pigment content differed significantly among 4 families and treatments. The reduction of total chlorophyll content showed the highest in family SU4 (-40.6%) and the lowest family US2 (-18.8%). Ascorbate-peroxidase (APX) activity showed significant difference among families and treatments, and increased as compared with control in three families, except for family US2. On the basis of the physiological indices, ozone tolerance of four families was ranked in the order of US1 > SU4 > US2 > SU1. In conclusion, photosynthetic parameters, pigment content and APX activity were recommended as appropriate indicators to assess the tolerance against ozone stress of Q. aliena.

Prediction of Cryptosporidium parvum Inactivation in Advanced Ozone Drinking Water Treatment with Lab Scale Experiments (실험실 규모 크립토스포리디움의 불활성화 실험을 통한 오존 고도정수처리 정수장에서 소독 효과 예측)

  • Cho, Min;Chung, Hyenmi;Kim, Reeho;Shon, Jinsik;Park, Sangjung;Yoon, Jeyong
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.7-13
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    • 2005
  • With the appearance of pathogenic microorganisms, which were resistant to free chlorine, the significant attention to the necessity of powerful alternative disinfection methods such as ozone, chlorine dioxide, LTV irradiation to inactivating pathogens has been increased in water treatment. Among these alternative disinfection methods, ozone is well known as strong biocidal method and the usage of ozone is also increasing in Korea. However, in Korea, there has been no report on the quantitative study of Cryptosporidium parvum with ozone and its evaluation in advanced drinking water treatments. This study reports on the methodology for predicting the ozone inactivation of Cryptosporidium parvum by ozone disinfection in advanced drinking water treatment. The method is based on the fact that a specific inactivation level of microorganisms is achieved at a unique value of ozone exposures, independent of ozone dose and type of water, and quantitatively described by a delayed Chick-Watson model. The required values ${\bar{C}}T$ for 2 log inactivation of Cryptosporidium parvum was $6.0mg/L{\cdot}min$ and $15.5mg/L{\cdot}min$ at $20^{\circ}C$ and $5^{\circ}C$, respectively. From this obtained Cryptosporidium parvum inactivation curves and calculated ${\bar{C}}T$ values of advanced drinking water treatment water in Korea with FIA (Flow injection alaysis), we can predict that water treatment plant can achieve a 1.1~1.8 log inactivation and 0~0.4 log inactivation at $20^{\circ}C$ and $5^{\circ}C$, respectively. This methodology will be useful for drinking water treatment plants which intend to evaluate the disinfection efficiencies of their ozonation process without full scale test and direct experiments with Cryptosporidium parvum.

Microbiological Quality Enhancement of Minimally-Processed Enoki Mushrooms Using Ozone and Organic Acids

  • Park, Shin-Young;Yoo, Mi-Young;Choi, Jae-Ho;Ha, Sang-Do;Moon, Kwang-Deok;Oh, Deog-Hwan
    • Food Science and Biotechnology
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    • v.14 no.6
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    • pp.803-807
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    • 2005
  • This study examined the effects of ozone exposure alone (1, 3, and 5 ppm) as well as in combination with 1% acetic acid, citric acid, or lactic acid on the growth of indigenous microorganisms in enoki mushrooms. Populations of mesophilic bacteria, yeasts and molds in enoki mushrooms appeared to be decreased by stepwise increases in concentration (1 to 5 ppm) or exposure time (0.5 to 5 min) to ozone. Compared to untreated (control) enoki mushrooms, there were reductions of 1.03 to $2.61\;\log_{10}\;CFU/g$ in mesophilic bacteria and of 1.21 to $2.7\;\log_{10}\;CFU/g$ in yeasts and molds in all ozone- treated enoki mushrooms. Combination of 3 ppm ozone and 1% citric acid (p<0.05) synergistically brought about significant reductions in both mesophilic bacteria ($3.52\;\log_{10}\;CFU/g$) and fungi (yeasts and molds) ($2.77\;\log_{10}\;CFU/g$) from enoki mushrooms. The results of this study show that low concentrations of ozone inhibit indigenous microflora populations in enoki mushrooms. Combination treatments of 3 ppm ozone with 1% citric acid showed greater antimicrobial effectiveness than either 3 ppm ozone or 1% citric acid alone.

Sensitivities of Salmonella typhimurium and Staphylococcus aureus to Ozonation in the Presence of Soluble Starch and Metal Ion Complex

  • Kim, Kee-Il;Kang, Suk-Nam;Lee, Ok-Hwan;Park, Jeong-Hyun
    • Food Science and Biotechnology
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    • v.17 no.4
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    • pp.842-845
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    • 2008
  • This study was carried out to investigate the bactericidal efficacy of concentration (0.1, 0.2, and 0.4 ppm) and exposure time (10 and 30 min) of ozone on bacterial reduction rate of Salmonella typhimurium KCTC 2541 and Staphylococcus aureus ATCC 13515 in the distilled water (DW), and DW supplemented with 0.2% soluble starch (SS), and metal ion (MC) using argentums (Ag) and copper (Cu). The significant bactericidal differences of S. aureus were showed in the treatments of DW and SS, respectively, at the concentration of ozone above 0.1 ppm for 10 min, comparing the respective initial bacterial counts. The bacterial reduction of S. aureus was more sensitive than that of S. typhimurum at the same concentration of ozone. The bacterial reduction rate of SS treatment was slightly lower than that of DW treatment at the same concentration of ozone (p<0.05), however, the bacterial reduction rate of strains improved in the MC treatment compared to the DW treatment at the same concentration of ozone.

Effects of Ionizing Energy and Ozone Treatments on the Microbial Decontamination and Physicochemical Properties of Aloe Powders and Bee Pollen

  • Yook, Hong-Sun;Chung, Young-Jin;Kim, Jung-Ok;Kwon, Oh-Jin;Kim, Sung;Byun, Myung-Woo
    • Preventive Nutrition and Food Science
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    • v.2 no.2
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    • pp.89-95
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    • 1997
  • The comparative effects of gamma irradiation an ozone treatment on the microbiological and physicochemical qualities were investigated for the improvement of hygienic quality of aloe powder and bee pollen. Gamma irradiation at 7.5~10kGy could reduce total aerobic bacteria, molds and coliforms below detection levels, but ozone treatment up to 18 ppm for 8hr was not sufficient to eliminate the microorganisms from aloe powder and bee pollen. The physicochemical properties such as fatty acid an amino acid compositions, mineral content, TBA value, barbaloin and pigment contents were not significantly changed by gamma irradiation, whereas ozone treatment caused significant changes in fatty acid composition, lipid oxidation and destruction of barbaloin and natural pigments.

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Stomatal and Photosynthetic Responses of Betula Species Exposed to Ozone (오존에 노출된 자작나무류의 기공개폐와 광합성 반응)

  • 이재천;김장수;한심희;김판기
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.6 no.1
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    • pp.11-17
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    • 2004
  • This study was conducted to determine the relationship of stomatal responses, photosynthesis, and intercellular $CO_2$ concentration( $C_{i}$) of Betula Species to ozone exposure. Five Betula Species(B. costata, B. davurica, B. schmidtii, B. platyphylla var, iaponica and B, ermani) were grown in the greenhouse. One-year-old potted seedlings of the five Betula Species were exposed to ozone(100 pub) for 8 hours da $y^{-1}$ for 5 weeks in a fumigation chamber. Net photosynthesis was significantly different among species and treatments from early in the period of the fumigation. Stomatal conductance and transpiration rate differences among species and treatments became significant after three weeks of fumigation. $C_{i}$ was significantly different only among treatments; $C_{i}$ of four species, except for B. davurica, was higher than that of control plants. Carboxylation efficiency and photo-respiration rate were significantly different among species or treatments; carboxylation efficiency and photo-respiration rate of the five Betula Species were decreased by ozone treatment. It was concluded that stomatal closure of Betula Species may be the result of the reduction of photosynthesis and rubisco activity and the resulting increase of $C_{i}$. The higher $C_{i}$ likely resulted from reduced photosynthesis because of physiological processes.ocesses.

The applications of ozone-based advanced oxidation processes for wastewater treatment: A review

  • Hussain, Mujtaba;Mahtab, Mohd Salim;Farooqi, Izharul Haq
    • Advances in environmental research
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    • v.9 no.3
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    • pp.191-214
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    • 2020
  • The rise in population and industrialization accounts for the generation of a huge amount of wastewaters. The treatment of this wastewater is obligatory to safeguard the environment and various life forms. Conventional methods for high strength wastewater treatment coming out to be ineffective. Advanced oxidation processes (AOPs) for such wastewater treatment proved to be very effective particularly for the removal of various refractory compounds present in the wastewater. Ozone based AOPs with its high oxidizing power and excellent disinfectant properties is considered to be an attractive choice for the elimination of a large spectrum of refractory compounds. Furthermore, it enhances the biodegradability of wastewaters after treatment which favors subsequent biological treatments. In this review, a detailed overview of the AOPs (like the Fenton process, photocatalysis, Electrochemical oxidation, wet air oxidation, and Supercritical water oxidation process) has been discussed explicitly focusing on ozone-based AOPs (like O3, O3/H2O2, O3/UV, Ozone/Activated carbon process, Ozone/Ultrasound process, O3/UV/H2O2 process). This review also comprises the involved mechanisms and applications of various ozone-based AOPs for effective municipal/industrial wastewaters and landfill leachate treatment. Process limitations and rough economical analysis were also introduced. The conclusive remarks with future research directions also underlined. It was found that ozonation in combination with other effective AOPs and biological methods enhances treatment efficacies. This review will serve as a reference document for the researchers working in the AOPs field particularly focusing on ozone-based AOPs for wastewater treatment and management systems.

Effects of Aqueous Ozone Combined with Organic Acids on Microflora Inactivation in the Raw Materials of Saengsik

  • Bang, Woo-Suk;Eom, Young-Ran;Eun, Jong-Bang;Oh, Deog-Hwan
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.958-962
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    • 2007
  • This study was conducted to determine the effects of microorganism inactivation using 3 ppm of aqueous ozone (AO), 1% citric acid, 1% lactic acid, and 1% acetic acid alone, as well as the combinations of AO and organic acid, for washing the raw materials of saengsik (carrot, cabbage, glutinous rice, barley) with or without agitation. The combination of AO and 1% of each organic acid significantly inactivated spoilage bacteria in both the vegetables and the grains (p<0.05). However, in the glutinous rice, no inhibitory effects were shown for total aerobic bacteria by using water, ozone, or the combination of AO with citric acid or lactic acid, without agitation. Microbial inactivation was enhanced with agitation in the grains, whereas dipping (no agitation) treatments showed better inhibitory effects in the vegetables than in the barley, suggesting that washing processes should take into account the type of food material.