• Journal of Mechanical Science and Technology
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• v.16 no.9
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• pp.1156-1165
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• 2002

The characteristics of combustion and radiation heat transfer of an oxygen-enhanced diffusion flame was experimentally analyzed. An infrared radiation heat flux gauge was used to measure the thermal radiation of various types of flames with fuel, air and pure oxygen. And the Laser Induced Incandescence (LII) technique was applied to characterize the soot concentrations which mainly contribute to the continuum radiation from flame. The results show that an oxygen-enhanced inverse diffusion flame is very effective in increasing the thermal radiation compared to normal oxygen diffusion flame. This seems to be caused by overlapped heat release rate of double flame sheets formed in inverse flame and generation of higher intermediate soot in fuel rich zone of oxygen-fuel interface, which is desirable to increase continuum radiation. And the oxygen/methane reaction at slight fuel rich condition (ø=2) in oxygen-enhanced inverse flame was found to be more effective to generate the soot with moderate oxygen availability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.9
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• pp.1174-1184
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• 1997

Extinction characteristics of pure hydrogen-oxygen diffusion flames, at high pressures in the neighborhood of the critical pressure of oxygen, is numerically studied by employing counterflow diffusion flame as a model flame let in turbulent flames in rocket engines. The numerical results show that extinction strain rate increases almost linearly with pressure up to 100 atm, which can be explained by comparison of the chain-branching-reaction rate with the recombination-reaction rate. Since contributions of the chain-branching reactions, two-body reactions, are found to be much greater than those of the recombination reactions, three-body reactions, extinction is controlled by two-body reactions, thereby resulting in the linearity of extinction strain rate to pressure. Therefore, it is found that the chemical kinetic behaviors don't change up to 100 atm. Consideration of the pressure fall-off reactions shows a slight increase in extinction strain rate, but does not modify its linearity to pressure. The reduced kinetic mechanisms, which were verified at low pressures, are found to be still valid at high pressures and show good qualitative agreement in prediction of extinction strain rates. Effect of real gas is negligible on chemical kinetic behaviors of the flames.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.6-15
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• 2016

The oxygen fuel MILD (Moderate or Intense Low-oxygen Dilution) combustion has been considered as one of the promising combustion technology for flame stability, high thermal efficiency, low emissions and improved productivity. In this paper, the effect of oxygen and fuel injection condition on formation of MILD combustion was analyzed using lab scale oxygen fuel MILD combustion furnace. The results show that the flame mode was changed from a diffusion flame mode to a split flame mode via a MILD combustion flame mode with increasing the oxygen flow rate. A high degree of temperature uniformity was achieved using optimized combination of fuel and oxygen injection configuration without the need for external oxygen preheating. In particular, the MILD combustion flame was found to be very stable and constant flame temperature region at 7 KW heating rate and oxygen flow rate 75-80 l/min.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.3
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• pp.281-288
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• 2004

Combustion using oxygen enriched air is an energy saving technology that can increase thermal efficiency by improving the burning rate and by increasing the flame temperature. Flame figures, OH radical intensities, temperature distributions and emissions concentration were examined according to oxygen enriched concentration(OEC) in a turbulent diffusion flat flame. As long as the oxygen enriched concentration was increased, the length and volume of the flat flame was decreased while OH radical intensity was raised and the flame temperature was increased. However, RMS of the fluctuating temperature was decreased, and more homogeneous temperature field was formed. Thermal NO also was increased with increase of oxygen enriched concentration, but CO was decreased due to the increase of chemical reaction rate.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.156-159
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• 2010

Peroxide is used frequently to provide electron acceptors to aerobes for the purpose of in situ bioremediation of contaminated soil/sediment. In this study, oxygen release rate of peroxides and factors affecting on dissolution and diffusion of oxygen into pore water were evaluated. Peroxides studied in this study were magnesium peroxide ($MgO_2$), calcium peroxide ($CaO_2$), and sodium percarbonate ($Na_2CO_3{\cdot}1.5H_2O_2$). $Na_2CO_3{\cdot}1.5H_2O_2$ showed the highest oxygen release rate per unit mass and the shortest release duration time among three peroxides. A simple first-order decay model for predicting the release rate of oxygen from peroxide into pore water was presented and used to fit the experimental data. The first order oxygen release rate constants k for $MgO_2$, $CaO_2$ and $Na_2CO_3{\cdot}1.5H_2O_2$ were 0.45 /hr, 3.22 /hr and 134 /hr, respectively. If $MgO_2$ was mixed with clay, oxygen release rate was lowered significantly mainly due to limitation of contact area and diffusion, implying that oxygen can be provided to the indigenous aerobes for the extended period of time.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.187-188
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• 2023

In this study, the analysis of concrete cracks was conducted with a total of three variables: coating thickness, oxygen diffusion rate, and reinforced diameter of reinforced concrete structures. Cracks occurred after about 3, 4, and 6 years at the coating thickness of 30, 40, and 50mm when the coating thickness was used as a variable, and cracks occurred after about 4, 5, and 10 years at oxygen diffusivity of 2e-9, 2e-11, and 2e-12 (m²/s) when the oxygen diffusion rate was used as a variable. In the case of reinforcing bar diameters, cracks occurred after about 4, 3, and 2 years on the reinforcing bar diameters of D10, D19, and D25.

• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.106-114
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• 2005

This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

• Journal of the Korean Society of Combustion
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• v.8 no.3
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• pp.1-7
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• 2003

Combustion using oxygen enriched air is an energy saving technology that can increase thermal efficiency by the improvement of burning rate and by the high temperature flame. Flame figures, OH radical intensities, temperature distributions and emission concentrations were measured according to oxygen enriched concentration and swirl number in a turbulent diffusion flat flame. It appeared that flame figure became flat and NO concentration decreased with increase of swirl number, and that the flame temperature increased high with increase of oxygen enriched concentration. In particular, it was most significant between oxygen concentration $40{\sim}60%$.

• The Korean Journal of Food And Nutrition
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• v.7 no.4
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• pp.399-405
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• 1994

Some method was introduced to explain oxygen transfer from broth to cell during aerobic microbe cultivation. It is explained by 5 steps that how desolved oxygen can reach to cell. Among these steps film resistance was the most important factor to describe oxygen transfer. Lumped model and distributed model was introduced to explain oxygen diffusion rate and oxygen consumption rate which occurs in the microbe pellet.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.236-241
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• 2008

The possibility of silicon oxidation through the aerial-diffusion of active oxygen species has been evaluated. The species originate from the surface of $TiO_2$ exposed by UV. Among process parameters such as UV intensity, substrate temperature and chamber pressure with oxygen, UV intensity was a major parameter to the influence on the oxide growth rate. When 1 kW high pressure Hg lamp was used as a UV source, the growth rate of silicon oxide was 8 times as faster as that of a 60 W BLB lamp. However, as the chamber pressure increased, the growth rate was declined due to the suppression of aerial diffusion of active oxygen species. According to the results, it could be confirmed that the aerial-diffusion of active oxygen species from UV-irradiated photocatalytic surface can be applied to a new method for preparing an ultra-thin silicon oxide at the range of relatively low temperature.