• Title/Summary/Keyword: oxygen concentration

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Reduction of Oxygen Concentration in the LPCVD Polysilicon Films Deposited by $N_2$ Gas-Flow Method ($N_2$ 가스 Flow에 의한 LPCVD 방법으로 증착된 다결정 실리콘 박막의 산소농도 저하)

  • An, Seung-Jung;Jeong, Min-Ho
    • Korean Journal of Materials Research
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    • v.9 no.3
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    • pp.269-273
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    • 1999
  • Polycrystalline silicon films are generally deposited by LPCVD, utilizing the thermal decomposition of $SiH_4$ gas. When silicon wafers are loaded into the furnace in order to reduce oxygen concentration of the films, we flow 20slm N, gas from top to bottom of the furnace, and then deposit films of $1000\AA$ thickness to measure oxygen concen­tration by SIMS. As a consequence of SIMS, we obtain oxygen concentration in films lower about 30 times than that of films deposited with 20slm $N_2$ gas-flow through the short injector in the hatch of furnace. In our long injector system, we estimate a reproducibility by uniformity, particle, and Rs of the deposited films.

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Changes in Oxygen-Pulse During Treadmill Walking (Treadmill 보행시 산소맥의 변화)

  • Lee, Chang-Hoon;Chung, Kyou-Chull
    • Journal of Preventive Medicine and Public Health
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    • v.17 no.1
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    • pp.281-287
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    • 1984
  • In search for a method of evaluating the cardiopulmonary function. 74 male and 33 female volunteers ages $18{\sim}25$ were subjected to this study The subjects walked on a treadmill at speed of 2,4,6 and 8km/hr with 0,5,10,15,20 and 25% grade of inclination, respectively, for a measurement of heart rate and oxygen-pulse. Heart rate was measured every 5 seconds at resting state and during walking by telemetric method using Heart Checker 108 System (Senoh Co., Japan). Oxygen concentration was measured by Douglas bag method collecting expired air for 5 minutes at rest, and for 2 minutes at the end of each walking exercise. Oxygen concentration in an expired air was analyzed with Orzat gas analyser and expressed in terms of STPD. Oxygen-pulse was defined as an amount of oxygen consumed at every heart at a cellular level. The followings were the results obtained from this study. 1. Mean values of oxygen-pulse at resting state was $3.1{\pm}0.11ml/beat$ in male and $2.5{\pm}0.87ml/beat$ in female, respectively. 2. Mean values of oxygen-pulse during treadmill walking were increased in proportion with the load of exercise, namely, the speed and grade of inclination, from minimum of 7.1ml/beat upto maximum of 18.2ml/beat in male and from minimum of 4.2ml/beat upto maximum of 12,7ml/beat in female. 3. Both linear and logarithmic regressional relationships between oxygen-pulse and speed of walking and grade of inclination were observed in both sexes. Predicted values of oxygen-pulse by logarithmic regressional formula on speed and on grade of inclination were better coincided with the measured values than those predicted by the linear regressional formula.

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A Study on the Measurement of Explosion Range by CO2 Addition for the Process Safety Operation of Propylene (프로필렌의 공정안전 운전을 위한 CO2 첨가량에 따른 폭발범위 측정에 관한 연구)

  • Choi, Yu-Jung;Heo, Jong-Man;Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.599-606
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    • 2019
  • Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

A Study on the Measurement of Microbial Dehyrogenase Activity in Biological Treatment (생물학적 수처리에 있어서 미생물 탈수소효소 활성도 측정에 관한 연구)

  • 어경해;남상호
    • Journal of Environmental Health Sciences
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    • v.15 no.2
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    • pp.41-49
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    • 1989
  • The assay on microbial dehydrogenase activity by using TTC was investigated. The experimental results are summarized as follows: 1. The TF production was affected by dissolved oxygen. Dissolved oxygen in samples could be effectively removed by adding $Na_{2}SO_{3}$ as reductant prior to incubation. 2. The toxic effect on TF formation was observed at up to 0.1% of final TTC concentration when VSS concentration was 2.7g/l. As the VSS concentration increased the effect decreased. 3. It was clearly revealed that the TF generation rate decreased with increasing VSS concentration. The dilution of sludge could be applicable when VSS level is below 3.5g/l. 4. The TF production of endogenous phase (De) could be used as a measure for the viable fraction of sludge over various sludge ages. The additional TF production (Ds) due to extracellular substrate responded to De, not to VSS concentration.

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A Study on Dust Explosion Characteristics of Hydroxypropyl Methyl Cellulose (Hydroxypropyl Methyl Cellulose의 분진 폭발특성에 관한 연구)

  • 임우섭;목연수
    • Journal of the Korean Society of Safety
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    • v.15 no.4
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    • pp.95-100
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    • 2000
  • This study was performed in Hartmann type dust explosion apparatus in order to research the dust explosion characteristics of hydroxypropyl methyl cellulose(HPMC): minimum explosive limit, minimum ignition energy, limiting oxygen concentration, maximum explosion pressure, rate of pressure rise, etc. The samples of HPMC dust were distributed into 120-140 mesh, 170-230 mesh and 325 under, and the gap distance of the discharge electrode was setted up at 5mm. The experimental results were obtained as follows: (1) The minimum explosive limit for HPMC dust was founded at 180g/㎥. the minimum ignition energy at 9.8mJ and the limiting oxygen concentration at 12%. (2) The maximum explosion pressure of HPMC dust was $8.1kg/cm^2\;{\cdot}\;$abs at the concentration of $500g/m^3$ and the maximum rate of pressure rise was 203.98 bar/sec at the concentration of $480g/m^3$ for 325 under.

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Preliminary Study of Bioremediation in Diesel Contaminated Soil (디젤 오염토양의 생물학적 복원에 관한 기초연구)

  • 김선영;권수열;이상훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.167-170
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    • 2000
  • The purpose of study is to evaluate the effects of physical parameters on diesel biodegradation in diesel contaminated soil. The parameters applied are concentration, temperature, moisture contents, electron acceptor(O$_2$). The results of this study showed that diesel were degraded faster at high temperature and moisture contents than at low temperature and moisture content. However concentration effect study indicates that diesel were more faster degraded at low concentration than at high concentration. The results of electron acceptor test showed concentration of oxygen did not affect the biodegradation rate of diesel in oxygen condition(10, 20%) of this study.

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Method for the Measurement of Dissolved Oxygen in a Cell Culture Microchannel Using Oxygen-Sensitive Luminescence (산소 민감 발광 염료를 이용한 마이크로 채널 내에서 배양되는 세포 주변의 산소 농도 측정)

  • Lee, Seung-Youl;Jin, Song-Wan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.533-538
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    • 2012
  • In this study, we used an $O_2$-sensitive luminescent dye to measure the $O_2$ concentration of culture media around HeLa cells cultured in a microchannel. $[Ru(bpy)_3]^{2+}$, which dissolves easily in water and which has no phototoxic effect, was used as the $O_2$-sensitive dye. The ratiometric sensing method was applied by introducing calcein as the $O_2$-insensitive dye, in order to overcome the disadvantages of intensity-based sensing. By performing calibration with an amperometric $O_2$ sensor, we could calculate the exact concentration of $O_2$ in the culture media. We applied this technique to measure the $O_2$ concentration around the cultured cells in the microchannel. As expected, the $O_2$ concentration gradually decreased as the cells moved farther away from the channel. This method is expected to be applicable to the investigation of hypoxia, which occurs commonly in scaffolds.

Optimization of Air-plasma and Oxygen-plasma Process for Water Treatment Using Central Composite Design and Response Surface Methodology (중심합성설계와 반응표면분석법을 이용한 수처리용 산소-플라즈마와 공기-플라즈마 공정의 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.20 no.7
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    • pp.907-917
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    • 2011
  • This study investigated the application of experimental design methodology to optimization of conditions of air-plasma and oxygen-plasma oxidation of N, N-Dimethyl-4-nitrosoaniline (RNO). The reactions of RNO degradation were described as a function of the parameters of voltage ($X_1$), gas flow rate ($X_2$) and initial RNO concentration ($X_3$) and modeled by the use of the central composite design. In pre-test, RNO degradation of the oxygen-plasma was higher than that of the air-plasma though low voltage and gas flow rate. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the RNO removal efficiency and test variables in a coded unit: RNO removal efficiency (%) = $86.06\;+\;5.00X_1\;+\;14.19X_2\;-\;8.08X_3\;+\;3.63X_1X_2\;-\;7.66X_2^2$ (air-plasma); RNO removal efficiency (%) = $88.06\;+\;4.18X_1\;+\;2.25X_2\;-\;4.91X_3\;+\;2.35X_1X_3\;+\;2.66X_1^2\;+\;1.72X_3^2$ (oxygen-plasma). In analysis of the main effect, air flow rate and initial RNO concentration were most important factor on RNO degradation in air-plasma and oxygen-plasma, respectively. Optimized conditions under specified range were obtained for the highest desirability at voltage 152.37 V, 135.49 V voltage and 5.79 L/min, 2.82 L/min gas flow rate and 25.65 mg/L, 34.94 mg/L initial RNO concentration for air-plasma and oxygen-plasma, respectively.

Development of Oxygen Sensor for the Oxygen Concentration Measuring of Air-fuel Ratio Measuring System (공연비 측정시스템의 산소농도 측정을 위한 센서 개발)

  • Lee, Jin-Hui;Choi, Ko-Yeol;Jang, Hyang-Dong;Kim, Yang-Soo;Cho, Dong-Hoe;Park, Myon-Yong;Chung, Koo-Chun;Cho, Jin-Weon
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.472-477
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    • 1999
  • It was developed the oxygen sensor of air-fuel ratio measuring system that was controlled the needed air amounts in optimum combustion according to the analysis of oxygen concentration of exhaust gas. The oxygen sensor was prepared by using gold as cathode, which the detection range for the oxygen concentration was from 0.0% to 30.0%. Response time was observed 15 to 20 sec. rapidly and selectively. It was appeared a good result in reproducibility and stability.

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Nitrogen-Oxygen Separation Characteristics by Polyimide Membrane System for Controlled Atmosphere Storage (CA저장을 위한 폴리이미드 막 시스템의 질소-산소 분리특성)

  • 이호원;현명택;고정삼
    • Food Science and Preservation
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    • v.5 no.3
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    • pp.239-246
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    • 1998
  • Polyimide membrane system was designed for manufacturing nitrogen-enriched gas, and basic technical data was suggested for appling this system to controlled atmosphere storage. The permeability characteristics of pure oxygen and nitrogen could be explained by dual-mode sorption model. There was substantial decrease in the permeation rates of oxygen, which is the more permeable gas, through the polyimide membrane due to the presence of nitrogen in comparison with pure oxygen. However, the permeation rates of nitrogen was increased by the presence of oxygen. The ideal separation factor was in the range of 5 to 6 in the range of temperature and pressure difference studied, and the separation factor of air was lower than the ideal separation factor. The increase of ideal separation factor with increasing temperature is due to the fact that the activation energy for oxygen is larger than that for nitrogen. Nitrogen concentration decreased rapidly with increasing product recovery, and it was found that this is a major operating factor to obtain nitrogen concentration required for controlled atmosphere storage. A relation equation, by which nitrogen concentration in storehouse can be predicted, was suggested under the establishment of a hypothetical model for controlled atmosphere storage process using polyimide membrane system.

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